Grain Structure Statistics in As-Patterned and Annealed Interconnects

1998 ◽  
Vol 516 ◽  
Author(s):  
W. Fayad ◽  
V. Andleigh ◽  
C. V. Thompson ◽  
H.J. Frost

AbstractWe have simulated the development of grain structures in polycrystalline films with lognormally distributed grain sizes, and carried out extensive characterization of grain cluster and bamboo cluster statistics. These statistics were characterized as a function of line-width to initial-grain-size ratios in as-patterned strips, and in strips in which we have simulated post-patterning grain structure evolution resulting from annealing. Among the important findings is that polygranular and bamboo cluster-length distributions for as-patterned lines are best fit by Weibull distribution functions instead of lognormal or exponential functions, as is often assumed. We report analytic formulae describing grain structure statistics that can be used in reliability calculations and simulations. We have carried out structure-sensitive electromigration simulations to show that the predicted failure statistics are essentially the same for grain structures generated using grain growth simulations and grain structures generated using analytic models. Analytic models provide computationally efficient means of determining the lifetime variations associated with grain-structure variations.

2013 ◽  
Vol 753 ◽  
pp. 231-234 ◽  
Author(s):  
Ning Wang ◽  
Yan Jun Li ◽  
Knut Marthinsen

In the present work an Al-Mn-(Fe-Si) model alloy has been subjected to different homogenization treatments, to achieve materials with different microchemistry states in terms of constituents, levels of Mn in solid solution (potential for concurrent precipitation) and dispersoid densities, followed by cold rolling and back-annealing. Characterization of the microchemistry state after homogenization and the evolution in dispersoid precipitation and its effects on the softening behavior after deformation has been performed. It is demonstrated that variations in microchemistry may have dramatic effects on the softening kinetics and the final grain structures, where both pre-existing fine and dense dispersoids before back annealing as well as precipitation concurrent with recovery and recrystallization strongly retard kinetics and generally lead to a coarse grain structure, while conditions with no or limited concurrent precipitation softens much faster and generally results in an even, fine and equi-axed grain structure. The different softening behaviors have been discussed in terms of Zener drag effects derived from the dispersoid evolutions.


1997 ◽  
Vol 490 ◽  
Author(s):  
S. P. Riege ◽  
V. Andleigh ◽  
C. V. Thompson ◽  
H. J. Frost

ABSTRACTWe have extended a 2D simulation of grain growth to treat the effects of precipitates on the evolution of interconnect grain structures during post-patterning processing. It is known from experiments that different annealing histories result in different precipitate sizes and locations. Precipitates capture and effectively pin grain boundaries and inhibit grain growth and evolution toward bamboo structures. We find that even a small volume fraction of precipitates prevent an interconnect strip from reaching the fully bamboo structure by retarding grain growth and lowering the average grain size. At a late stage of evolution, cluster regions are pinned by precipitates on both sides, preventing further transformation to the by far more reliable bamboo structure. The results from grain growth simulations have been used with our electromigration simulator MTT/EmSim to investigate the dependence of interconnect reliability on linewidth and precipitate distribution. We find that in lines with precipitates the bamboo structure is not reached during post-pattern annealing even if the line width is smaller than the average grain diameter. Furthermore, it is found that while Cu in solid solution improves interconnect reliability, Al2Cu precipitates can inhibit post-patterning grain structure evolution to more reliable bamboo or near-bamboo structures so much that similar lines made of pure Al would be more reliable. Linked grain structure evolution and electromigration simulations allow process optimization for maximum interconnect reliability.


2020 ◽  
Vol 989 ◽  
pp. 301-305
Author(s):  
Alexey V. Stolbovsky

Grain structures of Nb3Sn layers, formed by solid-state diffusion, have been analyzed using statistical methods. To determine parameters of grain structure from grain size distributions, a statistical model with combination of lognormal and standard distributions was used. Histograms of grain size distributions in Nb3Sn layers, formed by solid-state diffusion in different composites, appeared to have only one group of crystallites after various regimes of heat treatment. It has been established that there is strong correlation between average grain sizes and the standard deviations, and this statement is also fulfilled at the grain structure evolution under additional annealing.


Author(s):  
Ricardo Sánchez-Murillo

This study presents a hydrogeochemical analysis of spring responses (2013-2017) in the tropical mountainous region of the Central Valley of Costa Rica. The isotopic distribution of δ18O and δ2H in rainfall resulted in a highly significant meteoric water line: δ2H = 7.93×δ18O + 10.37 (r2=0.97). Rainfall isotope composition exhibited a strong dependent seasonality. The isotopic variation (δ18O) of two springs within the Barva aquifer was simulated using the FlowPC program to determine mean transit times (MTTs). Exponential-piston and dispersion distribution functions provided the best-fit to the observed isotopic composition at Flores and Sacramento springs, respectively. MTTs corresponded to 1.23±0.03 (Sacramento) and 1.42±0.04 (Flores) years. The greater MTT was represented by a homogeneous geochemical composition at Flores, whereas the smaller MTT at Sacramento is reflected in a more variable geochemical response. The results may be used to enhance modelling efforts in central Costa Rica, whereby scarcity of long-term data limits water resources management plans.


1981 ◽  
Vol 4 ◽  
Author(s):  
T. J. Stultz ◽  
J. F. Gibbons

ABSTRACTStructural and electrical characterization of laser recrystallized LPCVD silicon films on amorphous substrates using a shaped cw laser beam have been performed. In comparing the results to data obtained using a circular beam, it was found that a significant increase in grain size can be achieved and that the surface morphology of the shaped beam recrystallized material was much smoother. It was also found that whereas circular beam recrystallized material has a random grain structure, shaped beam material is highly oriented with a <100> texture. Finally the electrical characteristics of the recrystallized film were very good when measured in directions parallel to the grain boundaries.


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