scholarly journals On the mechanism for plasma hydrogenation of graphene

2010 ◽  
Vol 97 (23) ◽  
pp. 233104 ◽  
Author(s):  
J. D. Jones ◽  
W. D. Hoffmann ◽  
A. V. Jesseph ◽  
C. J. Morris ◽  
G. F. Verbeck ◽  
...  
Keyword(s):  
2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Grittima Kongprawes ◽  
Doonyapong Wongsawaeng ◽  
Kanokwan Ngaosuwan ◽  
Worapon Kiatkittipong ◽  
Suttichai Assabumrungrat

AbstractPartially hydrogenated fatty acid methyl ester (H-FAME) is conventionally produced through partial hydrogenation under high pressure and elevated temperature in the presence of a catalyst. Herein, a novel green, catalyst-free, non-thermal and atmospheric pressure dielectric barrier discharge (DBD) plasma was employed instead of a conventional method to hydrogenate palm FAME. H-FAME became more saturated with the conversion of C18:2 and C18:3 of 47.4 and 100%, respectively, at 100 W input power, 1 mm gas-filled gap size and 80% H2 in the mixed gas at room temperature for 5 h, causing a reduction of the iodine value from 50.2 to 43.5. Oxidation stability increased from 12.8 to 20 h while a cloud point changed from 13.5 to 16 °C. Interestingly, DBD plasma hydrogenation resulted in no trans-fatty acid formation which provided a positive effect on the cloud point. This green DBD plasma system showed a superior performance to a conventional catalytic reaction. It is an alternative method that is safe from explosion due to the mild operating condition, as well as being highly environmentally friendly by reducing waste and energy utilization from the regeneration process required for a catalytic process. This novel green plasma hydrogenation technique could also be applied to other liquid-based processes.


2008 ◽  
Vol 516 (10) ◽  
pp. 3172-3178 ◽  
Author(s):  
Y. Abdi ◽  
P. Hashemi ◽  
S. Mohajerzadeh ◽  
M. Jamei ◽  
M.D. Robertson ◽  
...  

1996 ◽  
Vol 442 ◽  
Author(s):  
K. Leosson ◽  
H. P. Gislason

AbstractWe present investigations on the two dominating acceptor levels observed in Cu-diffused GaAs which have frequently been attributed to the two ionization levels of a double CuGa acceptor. We employed plasma hydrogenation and lithium diffusion followed by reverse-bias and zero-bias annealing to passivate and subsequently reactivate the Cu-related acceptor levels. Deep-level current-transient spectroscopy measurements reveal that the two levels are independently reactivated, strongly indicating that they arise from different defects.


1983 ◽  
Vol 78 (1) ◽  
pp. K65-K69 ◽  
Author(s):  
S. J. Pearton ◽  
J. M. Kahn
Keyword(s):  

Nanoscale ◽  
2010 ◽  
Vol 2 (4) ◽  
pp. 594 ◽  
Author(s):  
Qijin Cheng ◽  
Eugene Tam ◽  
Shuyan Xu ◽  
Kostya (Ken) Ostrikov

1997 ◽  
Vol 18 (5) ◽  
pp. 187-189 ◽  
Author(s):  
Kan-Yuan Lee ◽  
Yean-Kuen Fang ◽  
Chii-Wen Chen ◽  
K.C. Huang ◽  
Mong-Song Liang ◽  
...  

1983 ◽  
Vol 12 (6) ◽  
pp. 1003-1014 ◽  
Author(s):  
S. J. Pearton ◽  
J. M. Kahn ◽  
E. E. Haller

2020 ◽  
Vol 45 (58) ◽  
pp. 34214-34226
Author(s):  
Fuyu Dong ◽  
Yongda Liu ◽  
Yue Zhang ◽  
Weidong Li ◽  
Peter K. Liaw ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document