The dependence of the Tauc and Cody optical gaps associated with hydrogenated amorphous silicon on the film thickness: αl Experimental limitations and the impact of curvature in the Tauc and Cody plots

2007 ◽  
Vol 102 (11) ◽  
pp. 113525 ◽  
Author(s):  
Tat M. Mok ◽  
Stephen K. O’Leary
2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
F. X. Abomo Abega ◽  
A. Teyou Ngoupo ◽  
J. M. B. Ndjaka

Numerical modelling is used to confirm experimental and theoretical work. The aim of this work is to present how to simulate ultrathin hydrogenated amorphous silicon- (a-Si:H-) based solar cells with a ITO BRL in their architectures. The results obtained in this study come from SCAPS-1D software. In the first step, the comparison between the J-V characteristics of simulation and experiment of the ultrathin a-Si:H-based solar cell is in agreement. Secondly, to explore the impact of certain properties of the solar cell, investigations focus on the study of the influence of the intrinsic layer and the buffer layer/absorber interface on the electrical parameters ( J SC , V OC , FF, and η ). The increase of the intrinsic layer thickness improves performance, while the bulk defect density of the intrinsic layer and the surface defect density of the buffer layer/ i -(a-Si:H) interface, respectively, in the ranges [109 cm-3, 1015 cm-3] and [1010 cm-2, 5 × 10 13  cm-2], do not affect the performance of the ultrathin a-Si:H-based solar cell. Analysis also shows that with approximately 1 μm thickness of the intrinsic layer, the optimum conversion efficiency is 12.71% ( J SC = 18.95   mA · c m − 2 , V OC = 0.973   V , and FF = 68.95 % ). This work presents a contribution to improving the performance of a-Si-based solar cells.


1987 ◽  
Vol 150 (1) ◽  
pp. 1-9 ◽  
Author(s):  
F. Demichelis ◽  
G. Kaniadakis ◽  
E. Mezzetti ◽  
P. Mpawenayo ◽  
A. Tagliaferro ◽  
...  

2002 ◽  
Vol 80 (14) ◽  
pp. 2463-2465 ◽  
Author(s):  
P. Danesh ◽  
B. Pantchev ◽  
D. Grambole ◽  
B. Schmidt

1994 ◽  
Vol 356 ◽  
Author(s):  
Wan-Shick Hong ◽  
J. C. Delgado ◽  
O. Ruiz ◽  
V. Perez-Mendez

AbstractResidual stress in hydrogenated amorphous silicon (a-Si:H) film has been studied. Deposition on square island pattern reduced the stress when the lateral dimension of the islands became comparable to the film thickness. The overall stress was reduced by approximately 40% when the lateral dimension was decreased to 40 μm, but the adhesion was not improved much. However, substrates having a 2-dimensional array of inversed pyramids of 200 μm in lateral dimension produced overall stress 3∼4 times lower than that on the normal substrates. The inversed pyramid structure also had other advantages including minimized delamination and increased effective thickness. Computer simulation confirmed that the overall stress can be reduced by deposition on the pyramidal structure.


1990 ◽  
Vol 192 ◽  
Author(s):  
N. Maley ◽  
I. Szafranek

ABSTRACTThe validity of the Brodsky, Cardona and Cuomo (BCC) [1] and the Connell and Lewis (CL) [2] methods to analyze infrared transmission data of hydrogenated amorphous silicon (a-Si:H) was examined using computer simulations. Transmission spectra for a-Si:H films 0-5¼m thick and containing up to 30 atomic% hydrogen were simulated assuming coherent reflections in the film and incoherent reflections in the c-Si substrate. Analysis of the simulated data for the 640cm−1 Si-H wagging mode shows that the BCC and CL techniques systematically overestimate the absorption coefficeint, α, and hence hydrogen content, CH, when the film thickness, d, is less than ∼l¼m. The error is nearly independent of CH and is as large as 80% in the limit d→0. On this basis, previously reported experimental evidence for the dependence of CH on d is shown to be an analysis artifact. A simple method to correct the hydrogen content determined by the BCC or CL analysis using only the film thickness is presented.


1991 ◽  
Vol 238 ◽  
Author(s):  
N. R. Manning ◽  
Haydn Chen ◽  
J. R. Abelson ◽  
L. H. Allen

ABSTRACTSamples of crystalline (111) silicon were coated with various thicknesses of hydrogenated amorphous silicon (a-Si:H), then coated with 100 nm of palladium. These samples were then reacted to form Pd2Si in vacuum. The activation energies and reaction prefactors were determined by monitoring the film thickness using x-ray diffraction and by 4-point resistivity measurements. The crystallographic texture of the metal overlayer and suicide films were investigated before and after the reaction.


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