Selective Cyclohexene Oxidation to Allylic Compounds over Cu-triazole Framework via Homolytic Activation of Hydrogen Peroxide

Utilization of metal-organic frameworks as heterogeneous catalysts is crucial owing to their abundant catalytic sites and well-defined porous structures. Highly robust [Cu3(trz)3(μ3-OH)(OH)2(H2O)4]∙2H2O (trz = 1,2,4-triazole) was employed as a catalyst...

Vinylidene fluoride polymerization by metal-free selective activation of hydrogen peroxide: microstructure determination and mechanistic study

Hydrogen peroxide-initiated radical polymerization of vinylidene fluoride (VDF) at 130 °C in dimethyl carbonate is presented.

Activation of hydrogen peroxide by the nitrate anion in micellar media

Surface-active imidazolium nitrates activate hydrogen peroxide, which enables the epoxidation of olefins. The micelles solubilise the substrate in the aqueous oxidant phase and allow for simple product separation and catalyst recycling.