scholarly journals Vinylidene fluoride polymerization by metal-free selective activation of hydrogen peroxide: microstructure determination and mechanistic study

2021 ◽  
Vol 12 (6) ◽  
pp. 926-938
Author(s):  
Nadim Eid ◽  
Bruno Améduri ◽  
Olinda Gimello ◽  
Anthony Bonnet ◽  
Samuel Devisme
Keyword(s):  
Hydrogen Peroxide ◽  
Radical Polymerization ◽  
Dimethyl Carbonate ◽  
Vinylidene Fluoride ◽  
Mechanistic Study ◽  
Selective Activation ◽  
Metal Free ◽  
Activation Of Hydrogen Peroxide

Hydrogen peroxide-initiated radical polymerization of vinylidene fluoride (VDF) at 130 °C in dimethyl carbonate is presented.

scholarly journals Author Correction: A metal-free photocatalyst for highly efficient hydrogen peroxide photoproduction in real seawater

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Qingyao Wu ◽  
Jingjing Cao ◽  
Xiao Wang ◽  
Yan Liu ◽  
Yajie Zhao ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Metal Free ◽  
Highly Efficient

A Correction to this paper has been published: https://doi.org/10.1038/s41467-021-21490-z

Metal-free amino-controlled electrochemical intramolecular C–O and C–N couplings by site-selective activation of aryl C–N and C–O bonds

2021 ◽  
Author(s):  
Mu-Jia Luo ◽  
Gui-Fen Lv ◽  
Yang Li ◽  
Jin-Heng Li
Keyword(s):  
Free Amino ◽  
Selective Activation ◽  
Metal Free ◽  
Site Selective

Metal-free amino-assisted electrochemical intramolecular C–O or C–N couplings of amino-2-(2-aminoaryl)phenols are described.

Hydrogen Peroxide Generation with 100% Faradaic Efficiency on Metal-Free Carbon Black

ACS Catalysis ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 2454-2459
Author(s):  
Zhe Wang ◽  
Qin-Kun Li ◽  
Chenhao Zhang ◽  
Zhihua Cheng ◽  
Weiyin Chen ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Black ◽  
Free Carbon ◽  
Faradaic Efficiency ◽  
Metal Free ◽  
Hydrogen Peroxide Generation

scholarly journals Mechanistic Study on the Reaction of pinB-BMes2 with Alkynes Based on Experimental Investigation and DFT Calculations: Gradual Change of Mechanism Depending on the Substituent

2021 ◽  
Author(s):  
Linlin Wu ◽  
Chiemi Kojima ◽  
Ka Ho Lee ◽  
Shogo Morisako ◽  
Zhenyang Lin ◽  
...  
Keyword(s):  
Experimental Investigation ◽  
Transition Metal ◽  
Dft Calculations ◽  
Kinetic Analysis ◽  
Reaction Rate ◽  
Mechanistic Study ◽  
Isomer Ratio ◽  
Gradual Change ◽  
Isomeric Mixture ◽  
Metal Free

Transition-metal free direct and base-catalyzed 1,2-diborations of arylacetylenes using pinB-BMes2 provided syn/anti-isomeric mixture of diborylalkenes. The kinetic analysis showed that the reaction rate and isomer ratio were affected by reaction...

One-pot synthesis of bio-based polycarbonates from dimethyl carbonate and isosorbide under metal-free condition

2020 ◽  
Vol 22 (14) ◽  
pp. 4550-4560
Author(s):  
Wenjuan Fang ◽  
Zhencai Zhang ◽  
Zifeng Yang ◽  
Yaqin Zhang ◽  
Fei Xu ◽  
...  
Keyword(s):  
Dimethyl Carbonate ◽  
One Pot ◽  
Free Condition ◽  
Metal Free ◽  
One Pot Synthesis ◽  
Synthetic Strategy

A synthetic strategy for bio-based polycarbonate was developed via one-pot polymerization of renewable monomer isosorbide and dimethyl carbonate using eco-friendly organo-catalysts.

scholarly journals Mechanistic Study of the Conversion of Superoxide to Oxygen and Hydrogen Peroxide in Carbon Nanoparticles

2016 ◽  
Vol 8 (24) ◽  
pp. 15086-15092 ◽  
Author(s):  
Almaz S. Jalilov ◽  
Chenhao Zhang ◽  
Errol L. G. Samuel ◽  
William K. A. Sikkema ◽  
Gang Wu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Nanoparticles ◽  
Mechanistic Study
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