Activation of Hydrogen Peroxide by a Titanium Oxide-Supported Iron Catalyst: Evidence for Surface Fe(IV) and Its Selectivity

2020 ◽  
Vol 54 (23) ◽  
pp. 15424-15432
Author(s):  
Hak-Hyeon Kim ◽  
Hongshin Lee ◽  
Donghyun Lee ◽  
Young-Jin Ko ◽  
Heesoo Woo ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Titanium Oxide ◽  
Iron Catalyst ◽  
Activation Of Hydrogen Peroxide ◽  
Supported Iron

Selective Cyclohexene Oxidation to Allylic Compounds over Cu-triazole Framework via Homolytic Activation of Hydrogen Peroxide

2021 ◽  
Author(s):  
Panyapat Ponchai ◽  
Kanyaporn Adpakpang ◽  
Sareeya Bureekaew
Keyword(s):  
Hydrogen Peroxide ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Porous Structures ◽  
Cyclohexene Oxidation ◽  
Catalytic Sites ◽  
P Utilization ◽  
Metal Organic ◽  
Activation Of Hydrogen Peroxide

Utilization of metal-organic frameworks as heterogeneous catalysts is crucial owing to their abundant catalytic sites and well-defined porous structures. Highly robust [Cu3(trz)3(μ3-OH)(OH)2(H2O)4]∙2H2O (trz = 1,2,4-triazole) was employed as a catalyst...

Aldehydes as potential acylating reagents for oxidative esterification by inorganic ligand-supported iron catalysis

2019 ◽  
Vol 21 (16) ◽  
pp. 4550-4554 ◽  
Author(s):  
Han Yu ◽  
Jingjing Wang ◽  
Zhikang Wu ◽  
Qixin Zhao ◽  
Demin Dan ◽  
...  
Keyword(s):  
Iron Catalyst ◽  
Iron Catalysis ◽  
Oxidative Esterification ◽  
Inorganic Ligand ◽  
Supported Iron

An inorganic ligand-supported iron catalyst which can effectively catalyze oxidative esterification of various aldehydes and alcohols with excellent yields.

Protons Make Possible Heterolytic Activation of Hydrogen Peroxide over Zr-Based Metal–Organic Frameworks

ACS Catalysis ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 9699-9704 ◽  
Author(s):  
Nataliya V. Maksimchuk ◽  
Ji Sun Lee ◽  
Marina V. Solovyeva ◽  
Kyung Ho Cho ◽  
Aleksandr N. Shmakov ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Activation Of Hydrogen Peroxide
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