Activation of hydrogen peroxide by the nitrate anion in micellar media

2021 ◽  
Vol 23 (5) ◽  
pp. 1965-1971
Author(s):  
Fabian Schmidt ◽  
Bastian Zehner ◽  
Marlene Kaposi ◽  
Markus Drees ◽  
János Mink ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Nitrate Anion ◽  
Micellar Media ◽  
Catalyst Recycling ◽  
Product Separation ◽  
Surface Active ◽  
Simple Product ◽  
Epoxidation Of Olefins ◽  
Activation Of Hydrogen Peroxide

Surface-active imidazolium nitrates activate hydrogen peroxide, which enables the epoxidation of olefins. The micelles solubilise the substrate in the aqueous oxidant phase and allow for simple product separation and catalyst recycling.

scholarly journals Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate

RSC Advances ◽  
2017 ◽  
Vol 7 (22) ◽  
pp. 13467-13472 ◽  
Author(s):  
Hongchuan Xin ◽  
Shilei Yang ◽  
Baigang An ◽  
Zengjian An
Keyword(s):  
Hydrogen Peroxide ◽  
Recyclable Catalyst ◽  
Water Based ◽  
Product Separation ◽  
Simple Product

An efficient, VOC free method for the synthesis of 2,4-dichlorophenol, with simple product separation and a recyclable catalyst is developed.

Activation of Hydrogen Peroxide by Ionic Liquids: Mechanistic Studies and Application in the Epoxidation of Olefins

2013 ◽  
Vol 19 (19) ◽  
pp. 5972-5979 ◽  
Author(s):  
Iulius I. E. Markovits ◽  
Wilhelm A. Eger ◽  
Shuang Yue ◽  
Mirza Cokoja ◽  
Christian J. Münchmeyer ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Ionic Liquids ◽  
Mechanistic Studies ◽  
Epoxidation Of Olefins ◽  
Activation Of Hydrogen Peroxide

ChemInform Abstract: Iron-Catalyzed Epoxidation of Olefins Using Hydrogen Peroxide.

ChemInform ◽  
2011 ◽  
Vol 42 (37) ◽  
pp. no-no
Author(s):  
Kamrul Hasan ◽  
Nicole Brown ◽  
Christopher M. Kozak
Keyword(s):  
Hydrogen Peroxide ◽  
Epoxidation Of Olefins

Selective Cyclohexene Oxidation to Allylic Compounds over Cu-triazole Framework via Homolytic Activation of Hydrogen Peroxide

2021 ◽  
Author(s):  
Panyapat Ponchai ◽  
Kanyaporn Adpakpang ◽  
Sareeya Bureekaew
Keyword(s):  
Hydrogen Peroxide ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Porous Structures ◽  
Cyclohexene Oxidation ◽  
Catalytic Sites ◽  
P Utilization ◽  
Metal Organic ◽  
Activation Of Hydrogen Peroxide

Utilization of metal-organic frameworks as heterogeneous catalysts is crucial owing to their abundant catalytic sites and well-defined porous structures. Highly robust [Cu3(trz)3(μ3-OH)(OH)2(H2O)4]∙2H2O (trz = 1,2,4-triazole) was employed as a catalyst...

Epoxidation of olefins with hydrogen peroxide using an isocyanate as co-reactant

1970 ◽  
Vol 11 (23) ◽  
pp. 2029-2032 ◽  
Author(s):  
Naotake Matsumura ◽  
Noboru Sonoda ◽  
Shigeru Tsutsumi
Keyword(s):  
Hydrogen Peroxide ◽  
Epoxidation Of Olefins
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