Performance-Based Selection of the Cathode Material for the Electrodeposition-Redox Replacement Process of Gold Recovery from Chloride Solutions

Recently, an emerging electrodeposition-redox replacement (EDRR) method was demonstrated to provide exceptionally efficient gold recovery from cyanide-free hydrometallurgical solutions. However, the effect of electrode material and its corrosion resistance in this process was overlooked, even though the EDRR process is carried out in extremely corrosive, acidic chloride solution that also contains significant amounts of strong oxidants, i.e., cupric ions. In the current study, nickel alloy C-2000, stainless steels 316L and 654SMO, and grade 2 titanium were for the first time critically evaluated as potential cathode materials for EDRR. The particular emphasis was placed on better understanding of the effect of cathode substrate on the overall efficiency of the gold recovery process. The use of a multiple attribute decision-making method of material selection allowed reaching of a well-founded compromise between the corrosion properties of the electrodes and process efficiency of gold extraction. The 654SMO steel demonstrated outstanding performance among the examined materials, as it enabled gold recovery of 28.1 pct after 3000 EDRR cycles, while its corrosion rate (CR) was only 0.02 mm/year.

Development of Pulsed TEM Equipped with Nitride Semiconductor Photocathode for High-Speed Observation and Material Nanofabrication

The development of pulsed electron sources is applied to electron microscopes or electron beam lithography and is effective in expanding the functions of such devices. The laser photocathode can generate short pulsed electrons with high emittance, and the emittance can be increased by changing the cathode substrate from a metal to compound semiconductor. Among the substrates, nitride-based semiconductors with a negative electron affinity (NEA) have good advantages in terms of vacuum environment and cathode lifetime. In the present study, we report the development of a photocathode electron gun that utilizes photoelectron emission from a NEA-InGaN substrate by pulsed laser excitation, and the purpose is to apply it to material nanofabrication and high-speed observation using a pulsed transmission electron microscope (TEM) equipped with it.

Features of Electrophoretic Deposition of a Ba-Containing Thin-Film Proton-Conducting Electrolyte on a Porous Cathode Substrate

This paper presents the study of electrophoretic deposition (EPD) of a proton-conducting electrolyte of BaCe0.89Gd0.1Cu0.01O3-δ (BCGCuO) on porous cathode substrates of LaNi0.6Fe0.4O3−δ (LNFO) and La1.7Ba0.3NiO4+δ (LBNO). EPD kinetics was studied in the process of deposition of both a LBNO sublayer on the porous LNFO substrate and a BCGCuO electrolyte layer. Addition of iodine was shown to significantly increase the deposited film weight and decrease the number of EPD cycles. During the deposition on the LNFO cathode, Ba preservation in the electrolyte layer after sintering at 1450 °C was achieved only with a film thickness greater than 20 μm. The presence of a thin LBNO sublayer (10 μm) did not have a pronounced effect on the preservation of Ba in the electrolyte layer. When using the bulk LBNO cathode substrate as a Ba source, Ba was retained in a nominal amount in the BCGCuO film with a thickness of 10 μm. The film obtained on the bulk LBNO substrate, being in composition close to the nominal composition of the BCGCuO electrolyte, possessed the highest electrical conductivity among the films deposited on the various cathode substrates. The technology developed is a base step in the adaptation of the EPD method for fabrication of cathode-supported Solid Oxide Fuel Cells (SOFCs) with dense barium-containing electrolyte films while maintaining their nominal composition and functional characteristics.

Distribution of profiles and macroparticles in coatings obtained by continuous cathodic arc using a straight magnetic concentrator

Thin films of Ti and Cu were deposited on 316 stainless steel substrates by the continuous cathodic arc technique with magnetic concentrator in a straight duct. Samples obtained at different cathode-substrate distances, for positions within the magnetic concentrator. The morphology of the surface was determined by electron scanning microscopy (SEM). The average thickness of the films was measured from the deposited mass; the profiles of the films were also studied from measurements with a Calotest in different points of the samples and with a profilometer, the coefficient of friction and wear were characterized with a tribometer; the hardness with a nanoindenter. The results showed that the average thickness increased by the action of the magnetic concentrator, although this causes the samples to have a central region of maximum thickness and that the thickness decreased up to 50% in a radius of about 1 cm. The films were rough with presence of macroparticles. The number of macroparticles, the film roughness and the deposition rate were also analyzed; the deposition rate depended on the axial position inside the duct. The number of macroparticles diminished with increasing axial position, the friction coefficient and wear rate diminished when the substrate was placed farther from the cathode, inside the magnetic duct. The hardness value measured with a nanoindenter is about the order as the reported in the literature; the lowest coefficients of friction, the least wear and the highest values of hardness were obtained in the region where the magnetic field is highest.

Влияние усиленной электрическим полем термической электронной эмиссии на температуру катода с тонкой диэлектрической пленкой в дуговом газовом разряде

A model of thermal electron emission enhanced by the electric field (thermo-field emission) from the metal cathode substrate into a thin insulating film formed on its surface is developed. A system of equations for the cathode surface temperature in the arc discharge and the electric field strength in the film, providing the required discharge current density, is formulated. It is shown that existence of the dielectric film can result in a considerable reduction of the cathode temperature in the discharge due to lower potential barrier height at the metal-insulator boundary than at the metal-discharge boundary in case of the metal cathode without the film. It is found that due to an enhancement of thermal emission of electrons into the film by the electric field generated in it, an additional decrease of the cathode temperature by about 100 K takes place.

Comparative Study of Electrophoretic Deposition of Doped BaCeO3-Based Films on La2NiO4+δ and La1.7Ba0.3NiO4+δ Cathode Substrates

This paper presents the results of a comparative study of methods to prevent the loss of barium during the formation of thin-film proton-conducting electrolyte BaCe0.89Gd0.1Cu0.01O3−δ (BCGCuO) on La2NiO4+δ-based (LNO) cathode substrates by electrophoretic deposition (EPD). Three different methods of the BCGCuO film coating were considered: the formation of the BCGCuO electrolyte film without (1) and with a protective BaCeO3 (BCO) film (2) on the LNO electrode substrate and the formation of the BCGCuO electrolyte film on a modified La1.7Ba0.3NiO4+δ (LBNO) cathode substrate (3). After the cyclic EPD in six stages, the resulting BCGCuO film (6 μm) (1) on the LNO substrate was completely dense, but the scanning electron microscope (SEM) analysis revealed the absence of barium in the film caused by its intensive diffusion into the substrate and evaporation during the sintering. The BCO layer prevented the barium loss in the BCGCuO film (2); however, the protective film possessed a porous island structure, which resulted in the deterioration of the film’s conductivity. The use of the modified LBNO cathode also effectively prevented the loss of barium in the BCGCuO film (3). A BCGCuO film whose conductivity behavior most closely resembled that of the compacts was obtained by using this method which has strong potential for practical applications in solid oxide fuel cell (SOFC) technology.