Effects of Substrate Bias on the Nucleation of Diamond Films Studied by Atomic Force Microscopy

1995 ◽  
Vol 416 ◽  
Author(s):  
G. Sánchez ◽  
M. C. Polo ◽  
W. L. Wang ◽  
J. Esteve

ABSTRACTThe nucleation stage of diamond on silicon substrates was studied by atomic force microscopy. Samples were grown by hot filament chemical vapor deposition and substrate biases from -200 ν to +75 ν were investigated. The effects of the process on the substrate as well as on the morphology of the crystallites were observed using an atomic force microscope operating in tapping mode. It was observed that both the density and morphology of the diamond crystallites were greatly dependent on the applied bias values. The highest nucleation density was achieved for the -200 ν bias, when a plasma around the substrate holder was formed.

2004 ◽  
Vol 97-98 ◽  
pp. 191-194 ◽  
Author(s):  
R. Augulis ◽  
Valentinas Snitka ◽  
R. Rotomskis

Meso-tetra (4-sulfonatophenyl) porphine (TPPS4) is water-soluble tetrapyrrolic dye, which forms self assembled nanostructures – J-aggregates under appropriate conditions. It was shown, that such aggregates survive dried on the substrate. The spatial structure of TPPS4 Jaggregates formed in acidic aqueous solutions and dispersed on silicon substrates was analyzed by means of atomic force microscopy (AFM). The stripe-like structures were observed. The size of individual stripes ranged 4,5×40×(200-1000) nm (H×W×L). The width and height was almost the same for all stripes and independent upon the concentration of the solution, however the length was statistically distributed and the mean length increased with increasing concentration of initial TPPS4 solution. At higher concentrations such stripes stacked into thicker fibers containing 2-20 stripes. Such fibers branched and formed large bush-like structures sized up to several millimeters. According to experimental findings the model of mesostructures, formed by TPPS4 J-aggregates, was proposed.


2003 ◽  
Vol 94 (3) ◽  
pp. 1699-1704 ◽  
Author(s):  
G. Tanasa ◽  
O. Kurnosikov ◽  
C. F. J. Flipse ◽  
J. G. Buijnsters ◽  
W. J. P. van Enckevort

2000 ◽  
Vol 618 ◽  
Author(s):  
A.S. Bakin ◽  
D. Piester ◽  
H.-H. Wehmann ◽  
A.A. Ivanov ◽  
A. Schlachetzki ◽  
...  

ABSTRACTThree-dimensional islands of InP have been reproducibly grown in the Stranski-Krastanow growth mode on Si (001) and (111) by using metal-organic vapor phase epitaxy in order to obtain nanometer-scale quantum dots. Atomic-force microscopy was used to determine the morphology of the samples and to evaluate the dimensions of the islands. Formation of three-dimensional islands with densities as high as 2.5×1010 cm−2 and small sizes have been observed. The evolution of island morphology is explained in terms of strain-relaxing mechanisms at the first stages of InP/Si heteroepitaxy.


1999 ◽  
Vol 557 ◽  
Author(s):  
P. Brogueira ◽  
V. Chu ◽  
J.P. Conde

AbstractThe initial stages of microcrystalline silicon growth of n+ doped films prepared by rf plasma enhanced chemical vapor deposition (PECVD) and of intrinsic films prepared by hot-wire chemical vapor deposition (HW-CVD) are studied using atomic force microscopy, Raman spectroscopy and parallel dark conductivity measurements. The effect of the use of a plasma hydrogen treatment, of chamber conditioning prior to this treatment, of the type of substrate (glass or c-Si) used and the effects of a seed layer on the film properties are discussed.


2005 ◽  
Vol 83 (7) ◽  
pp. 753-759 ◽  
Author(s):  
W Chen ◽  
C Xiao ◽  
Q Yang ◽  
A Moewes ◽  
A Hirose

Electric voltages with both polarities were applied to silicon substrates in a hot-filament chemical vapour deposition device to study the biasing effects on deposition of diamond and carbon nanocones. It has been found that positive biasing greatly enhanced diamond nucleation density and improved diamond film quality. On the other hand, negative biasing promotes deposition of dense, well-aligned carbon nanocones. The orientation of the carbon nanocones appears to align with the direction of the electric field lines near the substrate surface.PACS Nos.: 81.15.Gh, 81.05.Uw, 81.07.–b


2018 ◽  
Vol 6 (1) ◽  
pp. 13
Author(s):  
Adebayo Fashina ◽  
Kenneth Adama ◽  
Lookman Abdullah ◽  
Chukwuemeka Ani ◽  
Oluwaseun Oyewole ◽  
...  

In this paper, the surface morphology of textured silicon substrates is explored. Prior to the surface morphology analysis, textured silicon substrates were obtained by KOH anisotropic texturing of polished silicon wafers. This was achieved by investigating of the dependence surface texturing on the process parameters; etchant concentration, etching time and temperature. The surface morphology of the textured silicon samples was obtained using atomic force microscopy that was operated in the tapping mode. The resulting atomic force microscopy (AFM) images were analyzed using the Nanoscope and Gwyddion software packages. The AFM analysis revealed more surface details such as the depth, roughness, section, and step height analysis. The analysis was limited to a length scale of a few micrometers, which carefully reveals the number of individualities of the initial stages of pyramid growth. The average roughness was found to be 593nm for an optimally textured silicon wafer. The implications of the study are then discussed for potential light trapping application in silicon solar cells.


1992 ◽  
Vol 60 (13) ◽  
pp. 1567-1569 ◽  
Author(s):  
V. Baranauskas ◽  
M. Fukui ◽  
C. R. Rodrigues ◽  
N. Parizotto ◽  
V. J. Trava‐Airoldi

1995 ◽  
Vol 10 (12) ◽  
pp. 3037-3040 ◽  
Author(s):  
Long Wang ◽  
John C. Angus ◽  
David Aue

Morphology of twinned diamond particles grown by chemical vapor deposition was characterized by atomic force microscopy in both contact and tapping modes. Quantitative angle measurements using a surface normal algorithm were performed on untwinned crystals, penetration twins, re-entrant corners, and fivefold dimples. Tip-sample interaction is discussed. The morphology of the penetration twins and some of the re-entrant corners can be explained by low order Σ3 twins and flat crystallographic surfaces. Abnormally shallow re-entrants with large vicinal faces are attributed to rapid nucleation of new layers at a point along the re-entrant intersection.


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