High-Quality Polycrystalline Silicon Thin Film Prepared by a Solid Phase Crystallization Method

1994 ◽  
Vol 358 ◽  
Author(s):  
T. Baba ◽  
T. Matsuyama ◽  
T. Sawada ◽  
T. Takahama ◽  
K. Wakisaka ◽  
...  

ABSTRACTWe succeeded, for the first time, in depositing a silicon film which features 1000Å-wide single-crystalline grains embedded in a matrix of amorphous tissue. The deposition was done by plasma-enhanced CVD from silane diluted with hydrogen at a considerably high temperature (550°C). 5pm-thick undoped amorphous silicon film was deposited on the above film and was crystallized by a solid phase crystallization method. The polycrystalline silicon film which was obtained has a columnar structure and shows an extremely high electron mobility of 808 cm2/Vs.

1996 ◽  
Vol 198-200 ◽  
pp. 940-944 ◽  
Author(s):  
T. Matsuyama ◽  
N. Terada ◽  
T. Baba ◽  
T. Sawada ◽  
S. Tsuge ◽  
...  

1995 ◽  
Vol 378 ◽  
Author(s):  
Kamal K. Mishra

AbstractIron gettering in p-type CZ silicon at 600C has been investigated using deep level transient spectroscopy(DLTS), and the surface photovoltage(SPV) method. A quantitative analysis of the gettering kinetics of iron using the polycrystalline silicon film is presented for the first time. Depth profiles of iron concentration indicated a sharp gradient in the Fe concentration near the polycrystalline silicon/substrate interface. Concurrent decrease in the minority carrier diffusion length was also observed in the same region. The majority of iron gettering from the bulk silicon was found to be associated with the enhancement of the internal gettering.The presence of small oxygen precipitates/nuclei generated by prolonged heat treatment at 600C was found to prevent regeneration of FeB pairs at the room temperature. On the other hand, large precipitates formed at lOOOC do not influence the diffusion or the recombination of Fei with B to form FeB pairs.


1992 ◽  
Vol 283 ◽  
Author(s):  
T. Matsuyama ◽  
T. Baba ◽  
M. Tanaka ◽  
S. Tsuda ◽  
H. Nishiwaki ◽  
...  

ABSTRACTThe relationship between the grain size of poly-Si after SPC and the structure of a-Si before SPC was studied. The structure of a-Si was characterized by TA/TO: the Raman intensity ratio of the Transverse Acoustic (TA) like band and the Transverse Optical (TO) like band. A good positive correlation between the grain size and TS/TO was revealed for the first time. The nucleation and growth kinetics were speculated by using a thermodynamic model. The grain size could be enlarged up to 6 μ m by applying textured substrates to a-Si with a large structural disorder. This film was applied to the active layer of solar cells, and a collection efficiency of 51% at 900 nm was obtained.


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