Measuring thicknesses of native oxide, crystalline-silicon, and buried oxide layers and the interface roughnesses of SOI

Author(s):  
Iris Bloomer ◽  
George G. Li ◽  
A. Rahim Forouhi ◽  
A. Auberton-Herve ◽  
Andrew Wittkower
1996 ◽  
Vol 446 ◽  
Author(s):  
G. G. Li ◽  
A. R. Forouhi ◽  
I. Bloomer ◽  
A. Auberton-Herve ◽  
A. Wittkower

AbstractA new technique, referred to as the “n&k Method”, is used to characterize the thin films comprising Silicon-on-Insulator (SOI). With the “n&k Method”, a non-destructive robust measurement of the thickness of both the crystalline silicon top-layer and the buried oxide under-layer, the spectra of refractive index (n), and extinction coefficient (k), and the smoothness of the interfaces is established. The “n&k Method” determines these quantities simultaneously and without multiple solutions for thickness. The non-destructive measurement of interface roughness between the buried oxide under-layer and the silicon substrate is associated with the presence of silicon islands. The native oxide that forms on SOI is also detected and measured. No initial user's input for thickness and optical constants are required in order to obtain these results. The spectra of optical constants are measured accurately and reliably.


ChemInform ◽  
2010 ◽  
Vol 28 (43) ◽  
pp. no-no
Author(s):  
E. SCHROER ◽  
S. HOPFE ◽  
Q. Y. TONG ◽  
U. GOESELE ◽  
W. SKORUPA

Author(s):  
K. V. Anand ◽  
P. Pang ◽  
J. B. Butcher ◽  
K. Das ◽  
E. Franks ◽  
...  

1998 ◽  
Vol 10 (4) ◽  
pp. 498-500 ◽  
Author(s):  
J. Heerlein ◽  
M. Grabherr ◽  
R. Jager ◽  
P. Unger

2004 ◽  
Vol 10 (S02) ◽  
pp. 1090-1091
Author(s):  
Marion A. Stevens-Kalceff

Extended abstract of a paper presented at Microscopy and Microanalysis 2004 in Savannah, Georgia, USA, August 1–5, 2004.


Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4093
Author(s):  
Maciej Ratynski ◽  
Bartosz Hamankiewicz ◽  
Dominika A. Buchberger ◽  
Andrzej Czerwinski

Among the many studied Li-ion active materials, silicon presents the highest specific capacity, however it suffers from a great volume change during lithiation. In this work, we present two methods for the chemical modification of silicon nanoparticles. Both methods change the materials’ electrochemical characteristics. The combined XPS and SEM results show that the properties of the generated silicon oxide layer depend on the modification procedure employed. Electrochemical characterization reveals that the formed oxide layers show different susceptibility to electro-reduction during the first lithiation. The single step oxidation procedure resulted in a thin and very stable oxide that acts as an artificial SEI layer during electrode operation. The removal of the native oxide prior to further reactions resulted in a very thick oxide layer formation. The created oxide layers (both thin and thick) greatly suppress the effect of silicon volume changes, which significantly reduces electrode degradation during cycling. Both modification techniques are relatively straightforward and scalable to an industrial level. The proposed modified materials reveal great applicability prospects in next generation Li-ion batteries due to their high specific capacity and remarkable cycling stability.


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