scholarly journals Exothermal effects in the thermal decomposition of [IrCl6]2−-containing salts with [M(NH3)5Cl]2+ cations: [M(NH3)5Cl][IrCl6] (M = Co, Cr, Ru, Rh, Ir)

2018 ◽  
Vol 42 (3) ◽  
pp. 1762-1770 ◽  
Author(s):  
S. A. Martynova ◽  
P. E. Plyusnin ◽  
T. I. Asanova ◽  
I. P. Asanov ◽  
D. P. Pishchur ◽  
...  

[M(NH3)5Cl][IrCl6], M = Co, Cr, Ru, Rh, and Ir, were proposed as single-source precursors for bimetallic alloys. Upon heating, compounds show endothermic effect which can be corresponded with Ir(iv) reduction and ligand exchange.

2010 ◽  
Vol 20 (32) ◽  
pp. 6612 ◽  
Author(s):  
Ilan Jen-La Plante ◽  
Tahani W. Zeid ◽  
Peidong Yang ◽  
Taleb Mokari

Polyhedron ◽  
2004 ◽  
Vol 23 (12) ◽  
pp. 2103-2109 ◽  
Author(s):  
D.C. Menezes ◽  
G.M. de Lima ◽  
A.O. Porto ◽  
C.L. Donnici ◽  
J.D. Ardisson ◽  
...  

2010 ◽  
Vol 49 (11) ◽  
pp. 4756-4758 ◽  
Author(s):  
Chivin Sun ◽  
Richard D. Westover ◽  
Kelsey R. Margulieux ◽  
Lev N. Zakharov ◽  
Andrew W. Holland ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (16) ◽  
pp. 11952-11959 ◽  
Author(s):  
Yuan Pan ◽  
Yunqi Liu ◽  
Chenguang Liu

We report an efficient method for the synthesis of nickel phosphide NCs for the first time. The size of Ni2P NCs can be controlled by changing reaction temperature and OAm quantity. The phase of nickel phosphide NCs can be controlled by increasing reaction time.


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