Exothermal effects in the thermal decomposition of [IrCl6]2−-containing salts with [M(NH3)5Cl]2+ cations: [M(NH3)5Cl][IrCl6] (M = Co, Cr, Ru, Rh, Ir)
Keyword(s):
[M(NH3)5Cl][IrCl6], M = Co, Cr, Ru, Rh, and Ir, were proposed as single-source precursors for bimetallic alloys. Upon heating, compounds show endothermic effect which can be corresponded with Ir(iv) reduction and ligand exchange.
2010 ◽
Vol 24
(9)
◽
pp. 650-655
◽
Keyword(s):
Keyword(s):
Keyword(s):
Keyword(s):
1999 ◽
Vol 09
(PR8)
◽
pp. Pr8-943-Pr8-951
◽
Study of nanoalloys formation mechanism from single-source precursors [M(NH3)5Cl](ReO4)2, M = Rh, Ir
2007 ◽
Vol 2007
(suppl_26)
◽
pp. 283-288
◽