An efficient method for the synthesis of nickel phosphide nanocrystals via thermal decomposition of single-source precursors

RSC Advances ◽  
2015 ◽  
Vol 5 (16) ◽  
pp. 11952-11959 ◽  
Author(s):  
Yuan Pan ◽  
Yunqi Liu ◽  
Chenguang Liu
Keyword(s):  
Thermal Decomposition ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Efficient Method ◽  
Nickel Phosphide ◽  
Single Source ◽  
Single Source Precursors ◽  
First Time

We report an efficient method for the synthesis of nickel phosphide NCs for the first time. The size of Ni2P NCs can be controlled by changing reaction temperature and OAm quantity. The phase of nickel phosphide NCs can be controlled by increasing reaction time.

Research on Preparation, Characterization of Novel Nano-ZnO

2011 ◽  
Vol 311-313 ◽  
pp. 549-554
Author(s):  
Yan Yan Liu ◽  
Dian Mo Zheng
Keyword(s):  
Thermal Decomposition ◽  
Zinc Oxide ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Zinc Acetate ◽  
Average Particle Size ◽  
Molar Ratio ◽  
Average Particle ◽  
Acetate Solution ◽  
Nano Zno

Zinc acetate and ammonium bicarbonate are used as raw material, zinc oxide prepared by direct precipitation of new technology. This paper discusses the effection of the formation in zinc oxide from the reactant concentration of zinc acetate, HCO3-/Zn2+ molarity ratio, reaction temperature, reaction time and condition in thermal decomposition of basic zinc carbonate. Using transmission electron microscopy (TEM), thermogravimetric / differential thermal analysis (TG / DTA) and other methods, preparation of nano-ZnO are characterized. Good conditions for the better system of nano- ZnO are 0.75mol /L in the concentration of zinc acetate solution, 2.5:1 in bicarbonate of ammonia and zinc acetate molar ratio, 45 °C of reaction temperature, 1.0h of reaction time, and 350 °C in thermal decomposition temperature, 3.0h of pyrolysis time. Zinc oxide obtained average particle size is 20 ~ 80nm, for the hexagonal crystal form.

scholarly journals Synthesis of metal sulfide nanomaterials via thermal decomposition of single-source precursors

2010 ◽  
Vol 20 (32) ◽  
pp. 6612 ◽  
Author(s):  
Ilan Jen-La Plante ◽  
Tahani W. Zeid ◽  
Peidong Yang ◽  
Taleb Mokari
Keyword(s):  
Thermal Decomposition ◽  
Metal Sulfide ◽  
Single Source ◽  
Single Source Precursors

Novel single-source precursors for SiBxCyNz film deposition

2017 ◽  
Vol 41 (20) ◽  
pp. 11926-11933 ◽  
Author(s):  
Ivan S. Merenkov ◽  
Boris A. Gostevskii ◽  
Pavel O. Krasnov ◽  
Tamara V. Basova ◽  
Yuri M. Zhukov ◽  
...  
Keyword(s):  
Film Deposition ◽  
Single Source ◽  
Single Source Precursors ◽  
First Time

A novel type of single-source CVD precursor – Me3SiCCB[N(SiMe3)2]2 – has been synthesized and successfully tested for the first time in SiBCN film deposition.

scholarly journals Exothermal effects in the thermal decomposition of [IrCl6]2−-containing salts with [M(NH3)5Cl]2+ cations: [M(NH3)5Cl][IrCl6] (M = Co, Cr, Ru, Rh, Ir)

2018 ◽  
Vol 42 (3) ◽  
pp. 1762-1770 ◽  
Author(s):  
S. A. Martynova ◽  
P. E. Plyusnin ◽  
T. I. Asanova ◽  
I. P. Asanov ◽  
D. P. Pishchur ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Ligand Exchange ◽  
Endothermic Effect ◽  
Single Source ◽  
Single Source Precursors ◽  
Bimetallic Alloys

[M(NH3)5Cl][IrCl6], M = Co, Cr, Ru, Rh, and Ir, were proposed as single-source precursors for bimetallic alloys. Upon heating, compounds show endothermic effect which can be corresponded with Ir(iv) reduction and ligand exchange.

Hydrothermal Conversion of Glucose into Lactic Acid with Nickel as a Catalyst

2011 ◽  
Vol 347-353 ◽  
pp. 3873-3876
Author(s):  
Adama Yousif ◽  
Xu Zeng ◽  
Fang Ming Jin ◽  
Yan Fang
Keyword(s):  
Lactic Acid ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Efficient Method ◽  
Optimum Conditions ◽  
Hydrothermal Conditions ◽  
Hydrothermal Conversion ◽  
Acid Yield

In this paper, an efficient method for producing lactic acid from glucose with nickel as a catalyst under hydrothermal conditions has been developed. The addition of nickel can improve the lactic acid yield efficiently under alkaline hydrothermal conditions. The highest lactic acid yield of 35% was obtained under the optimum conditions, i.e., reaction temperature 300 °C, reaction time 60 s, 0.5 mmol nickel and 2.5 M NaOH.

Thermolysis Synthesis of MoS2 Microrods for Noble Metal-Free Catalytic Reduction of 4-Nitrophenol

2019 ◽  
Vol 19 (11) ◽  
pp. 7381-7386 ◽  
Author(s):  
Qiuhao Li ◽  
Zhenwei Zhang ◽  
Qiushuang Chen ◽  
Yang Li ◽  
Xiuqing Qiao
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Apparent Rate Constant ◽  
Catalytic Reduction ◽  
The Self ◽  
Single Source ◽  
Metal Free ◽  
Ultrathin Nanosheets ◽  
Metal Dichalcogenides ◽  
First Time

MoS2 microrods constructed by ultrathin nanosheets have been synthesized, for the first time, by thermal decomposition of intermediate (NH4)2MoS4 crystals, which could not only provide the single-source for both the molybdenum and sulfur atoms, but also served as the self-sacrificed template. The well-defined microstructure was characterized by XRD, SEM, TEM, XPS, BET, respectively. The results indicated that MoS2 microrods with uniform morphology were assembled by defective ultrathin nanosheets. Moreover, these MoS2 microrods exhibit superior catalytic activity with the apparent rate constant (κapp) of 0.161 min−1 for the reduction of 4-nitrophenol (4-NP) by NaBH4. Encouragingly, the MoS2 microrods still show evident activity for the reduction of 4-NP after five cycle tests, which has significant importance for the application in the reduction of 4-NP to p-aminophenol (4-AP). Also, this method can be extended to construct other kinds of metal dichalcogenides (TMDs).

Synthesis, characterisation and thermal decomposition of tin(IV) dithiocarbamate derivatives – single source precursors for tin sulfide powders

Polyhedron ◽  
2004 ◽  
Vol 23 (12) ◽  
pp. 2103-2109 ◽  
Author(s):  
D.C. Menezes ◽  
G.M. de Lima ◽  
A.O. Porto ◽  
C.L. Donnici ◽  
J.D. Ardisson ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Tin Sulfide ◽  
Single Source ◽  
Single Source Precursors ◽  
Dithiocarbamate Derivatives
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