Formation of reactive intermediates [ROOOOR] from the addition of superoxide ion (O2.bul.-) to carbon tetrachloride, trichlorotrifluoromethane, trichloromethylbenzene, benzoyl chloride, n-butyl bromide, and n-butyl chloride in acetonitrile

1988 ◽  
Vol 1 (1) ◽  
pp. 19-21 ◽  
Author(s):  
Shigenobu Matsumoto ◽  
Hiroshi Sugimoto ◽  
Donald T. Sawyer
1990 ◽  
Vol 55 (11) ◽  
pp. 2614-2623
Author(s):  
Jiří Mollin ◽  
Pavlína Staňková ◽  
Oldřiška Staňková

The composition of solvolysis products of butyl bromide, acetanhydride, and benzoyl chloride has been followed aqueous alcohol in alkaline and (except for butyl bromide) also in neutral regions. The results have been used as a piece of evidence of the existence of equilibrium between hydroxide and alkoxide ions and for evaluation of the possibility of calculation of the concentration ratio of hydroxide and alkoxide ions from the concentration ratios of the products as well as for evaluation of selectivities of the solvolytic reactions for mechanistic purposes.


Sign in / Sign up

Export Citation Format

Share Document