scholarly journals Ultrasonic and Thermodynamic Study on Solute-Solvent Interaction. Binary Mixtures oft-Butyl Chloride,t-Butyl Bromide and 1,1,1-Trichloroethane with Carbon Tetrachloride, Benzene andp-Xylene

1971 ◽  
Vol 44 (5) ◽  
pp. 1224-1230 ◽  
Author(s):  
Osamu Kiyohara ◽  
Kiyoshi Arakawa
Keyword(s):  
Carbon Tetrachloride ◽  
Binary Mixtures ◽  
Thermodynamic Study ◽  
Butyl Chloride ◽  
Butyl Bromide ◽  
Solvent Interaction ◽  
Solute Solvent Interaction

Infrared Study of Some Organophosphorus Esters in Carbon Tetrachloride and/or Chloroform 1% Solutions

1992 ◽  
Vol 46 (10) ◽  
pp. 1564-1574 ◽  
Author(s):  
R. A. Nyquist ◽  
C. W. Puehl
Keyword(s):  
Carbon Tetrachloride ◽  
Functional Groups ◽  
Solvent System ◽  
Infrared Study ◽  
Solvent Interaction ◽  
Rotational Isomers ◽  
Solvent Systems ◽  
Solute Solvent Interaction ◽  
Organophosphorus Esters

Solvent systems such as CHCl3/CCl4 or CDCl3/CCl4 are useful in showing that organophosphorus esters do exist as rotational isomers in solution. The functional groups such as P=O and POR in organophosphorus esters are the sites of solute/solvent interaction, since their group frequencies are more affected than group frequencies arising primarily within the R group of the organophosphorus esters. This study also shows that different complexes are formed between the solute and solvent systems as well as within the solvent system as the mole % CHCl3/CCl4 or CDCl3/CCl4 increases.

Dielectric Polarisation of Pyridine

1975 ◽  
Vol 30 (7-8) ◽  
pp. 587-590
Author(s):  
V. K. Joshi
Keyword(s):  
Dipole Moment ◽  
Carbon Tetrachloride ◽  
Polar Solvents ◽  
Solvent Interaction ◽  
Solute Solvent Interaction ◽  
The Moment ◽  
Dielectric Polarisation ◽  
Influence Of Solvent

This paper deals with the study of dielectric polarisation of pyridine at 35°C in four non polar solvents namely benzene, carbon tetrachloride, dioxan and cyclohexane. The results have been discussed to understand the merits of PALIT equation. It is observed that the moment value μs obtained by this is fairly comparable with that calculated by the method of HALVERSTADT and KUMLER2. The order of apparent dipole moment has been discussed in terms of influence of solvent and solute-solvent interaction as well.

Conductance and Viscometric Studies of Some Tetraalkylammonium and Sodium Salts in Acetonitrile-Dimethyl Sulfoxide Mixtures at 35 °C

1992 ◽  
Vol 57 (10) ◽  
pp. 2078-2088 ◽  
Author(s):  
Mohinder S. Chauhan ◽  
Kishore C. Sharma ◽  
Sanjay Gupta ◽  
Suvarcha Chauhan ◽  
Vijay K. Syal
Keyword(s):  
Dimethyl Sulfoxide ◽  
Binary Mixtures ◽  
Molar Conductivity ◽  
Viscosity Data ◽  
Conductivity Data ◽  
Equation Resolution ◽  
Solvent Interaction ◽  
Sodium Salts ◽  
Ionic Components

Molar conductances and viscosities of Bu4NBPh4, NaBPh4 and R4NBr (R ethyl, propyl and butyl) at 35 °C in acetonitrile (AN), dimethylsulfoxide (DMSO) and their binary mixtures have been reported. The conductivity data has been analysed by the Shedlovsky conductance equation and viscosity data by the Jones-Dole equation. Resolution of limiting molar conductivity (Λ0) and viscosity B coefficient of electrolytes into their ionic components have been achieved by the reference salt method. Viscosity A coefficients have been compared with theoretical Aη coefficients. Derived conductance and viscosity parameters have been discussed in terms of the ion-solvent interaction.

Sign in / Sign up

Export Citation Format

Share Document