Surface and Bulk Oxygen Vacancy Defect States near the Fermi Level in 125 nm WO3−δ/TiO2(110) Films: A Resonant Valence Band Photoemission Spectroscopy Study

2011 ◽  
Vol 115 (33) ◽  
pp. 16411-16417 ◽  
Author(s):  
Artur Braun ◽  
Selma Erat ◽  
Xiaojun Zhang ◽  
Qianli Chen ◽  
Tzu-Wen Huang ◽  
...  
1991 ◽  
Vol 43 (18) ◽  
pp. 14581-14588 ◽  
Author(s):  
F. Proix ◽  
C. A. Sébenne ◽  
B. El Hafsi ◽  
K. Hricovini ◽  
R. Pinchaux ◽  
...  

2012 ◽  
Vol 27 (6) ◽  
pp. 065021 ◽  
Author(s):  
Olivia M Berengue ◽  
Mariana K Kanashiro ◽  
Adenilson J Chiquito ◽  
Cleocir J Dalmaschio ◽  
Edson R Leite

1985 ◽  
Vol 48 ◽  
Author(s):  
G. R. Gruzalski ◽  
D. M. Zehner ◽  
G. W. Ownby

ABSTRACTXPS was used to determine core-level binding energies and valence-band structure for TaCx over the range 0.5 ≲ × ≲ 1.0. As x decreased, the carbonls binding energy (BE) changed very little, the carbon-2s BE shifted toward the Fermi level, the position of the p-d valence-band peak shifted toward the Fermi level more, and the tantalum-4d and -4f BE's shifted toward the Fermi level even more, about 0.16 eV for a change in × of 0.1. In addition, the valence-band spectra exhibited structure between about 1 and 2 eV BE, and this structure increased as x decreased. These observations are explicable in terms of charge transfer and the formation of occupied defect states associated with carbon vacancies.


1987 ◽  
Vol 94 ◽  
Author(s):  
David W. Niles ◽  
Ming Tang ◽  
Hartmut Höchst

ABSTRACTWe have used angular resolved ultraviolet photoemission spectroscopy to study the epitaxial growth of Si on GaP(110). Surface state emission obscures the top of the valence band (TVB). The Fermi level for the clean GaP(110) surface is 1.20±0.05eV above the TVB. 1ML (monolayer) of Si pins the Fermi level position at 1.40±0.05eV above the TVB. Further deposition of Si leads to a valence band discontinuity ΔEv=1.07 ±0.10eV.


2003 ◽  
Vol 805 ◽  
Author(s):  
Esther Belin-Ferré ◽  
Zoltan Dankhazi ◽  
Marie-Françoise Fontaine ◽  
Jean Thirion ◽  
Marie-Cécile de Weerd ◽  
...  

ABSTRACTWe report here the results obtained for the valence band of four compounds from the Al-Cr-Fe system, all being approximants of the decagonal quasicrystalline phase as probed by a combination of X-ray emission and X-ray photoemission spectroscopy techniques. Salient features are d-d and p-d hybridizations at the Fermi level and in its close vicinity as well as a repulsive interaction between the d states of the two transition elements. Within about 4 eV below the Fermi level Al states are suggested to be of more localized-like character in the Al-Cr-Fe samples than in Al-Cu-Fe ones.


1987 ◽  
Vol 94 ◽  
Author(s):  
Ming Tang ◽  
David W. Niles ◽  
Isaac Hernández-Calderón ◽  
Hartmut Hóchst

ABSTRACTAngular Resolved Photoemission Spectroscopy with Synchrotron radiation has been used to study the MBE growth of α-Sn on CdTe(110). Sn grows epitaxially and the Fermi level pins at 0.72eV above the CdTe valence band maximum. Outdiffusion or segregation of Cd in the α-Sn layer is not observed. For small Sn coverages the Sn4d core spectra show a second component which may be due to the initial interfacial growth of SnTe.


1999 ◽  
Vol 86 (7) ◽  
pp. 3792-3796 ◽  
Author(s):  
Zoltán Hajnal ◽  
József Miró ◽  
Gábor Kiss ◽  
Ferenc Réti ◽  
Péter Deák ◽  
...  

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