adjacent methylene
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Author(s):  
M. Fathimunnisa ◽  
H. Manikandan ◽  
S. Selvanayagam ◽  
B. Sridhar

In the title pyrrolizidine derivative, C33H26F2N2O2, both pyrrolidine rings of the pyrrolizidine moiety adopt an envelope conformation. The difluorophenyl group is oriented at an angle of 54.3 (1)° with respect to the oxindole moiety. The crystal packing features an N—H...O hydrogen bond, which forms anR22(8) motif, and a C—H...O interaction, which generates aC(8) chain along [010]. In addition, this chain structure is stabilized by C—H...π interactions. In one of the pyrrolidine rings, the methylene group forming the flap of an envelope and the H atoms of the adjacent methylene groups are disordered over two sets of sites, with site-occupancy factors of 0.571 (4) and 0.429 (4)


1970 ◽  
Vol 11 (40) ◽  
pp. 3459-3462 ◽  
Author(s):  
R.G. Kostyanovsky ◽  
A.A. Fomichov ◽  
Z.E. Samojlova

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