Effect of Nitrogen on Phosphine-Susceptible and -Resistant Populations of Stored Product Insects

In this study, we evaluated nitrogen treatment on phosphine-resistant field and -susceptible laboratory populations of different stored product beetles. Nine trials were conducted in commercial nitrogen chambers with the O2 level set at 1.0%. Two different temperatures—i.e., 28 and 40 °C—and three exposure intervals—i.e., 2.5, 3 and 9 d—were used in our tests. Adults of the sawtoothed grain beetle, Oryzaephilus surinamensis (L.) (Coleoptera: Silvanidae); the red flour beetle, Tribolium castaneum (Herbst) (Coleoptera: Tenebrionidae); and the rice weevil, Sitophilus oryzae (L.) (Coleoptera: Curculionidae) were used in the trials. The insects were placed in vials with different commodities per species and population, and their mortality was measured after the termination of each trial. Then, the vials were kept in incubator chambers at 25 °C and 65% relative humidity for 65 d to measure progeny production. Complete parental mortality was observed in all cases for O. surinamensis and S. oryzae, but there was some survival for T. castaneum at 28 °C and 3 d of exposure. In general, progeny production was completely (100%) suppressed, with some exceptions for all species and populations. The results indicate that low oxygen is effective for all species tested, regardless of their resistance status to phosphine, and can be further adopted as an alternative method to mitigate resistance in stored product beetles.

Amino acid content in red wines obtained from grapevine nitrogen foliar treatments: consumption during the alcoholic fermentation

Nitrogen is an important element for grapevine and winemaking which affects the development of the plant and yeast, and therefore it is important for wine quality. The aim of this work was to study the influence of foliar application to vineyard of proline, phenylalanine and urea and two commercial nitrogen fertilizers, without and with amino acids in their formulation, on the wine amino acid content and their consumption during the alcoholic fermentation. The results showed that these treatments did not affect the amino acid composition in wines. The differences observed for certain amino acids were so small that the concentration of total amino acids was not significantly different among wines. Moreover, it was observed that the higher the content of amino acids in the medium, the greater their consumption during the alcoholic fermentation.

Analysis of radioactive trace impurities with μBq-sensitivity in Borexino

BOREXINO has set new standards in the field of ultra-low background experiments. Such a success was only possible by a strict quality control program during the construction phase of the experiment. In this paper, we describe how construction materials and auxiliary systems of the BOREXINO detector were screened for their residual radioactivity with unprecedented high sensitivity. The highly sensitive assay techniques developed for this purpose were also used to validate the purity of water and nitrogen used in the experiment. Moreover, we report on the production of 222 Rn -free nitrogen and synthetic air with very low 222 Rn concentration as well as on the successful search for commercial nitrogen with a particularly low concentration of argon and krypton.

Influence of Flame Retardant on Leather Fatliquoring and Fire Resistance

Commercial nitrogen-phosphorus flame retardants (KZR-2, SC-968, FR-102), which are frequently used in textile industry, were imposed on the fatliquoring processes of leather. When 0%, 0.5%, 1.0%, 1.5%, 2.0%, 3%, 6%, 9%, 12﹪and 15﹪ amount of flame retardants was respectively added, their influence on the absorption rate of different fatliquoring agents (synthetic oil, fish oil, vegetable oil and lecithin) and on the flame retardant property were investigated. The absorption rate of fat-liquoring agents was measured by oven and dichloromethane methods. The fire resistance was studied by means of oxygen index, vertical combustion and smoke density. The results show that flame retardants (KZR-2, SC-968 and FR-102) can enhance the absorption rate of fat-liquoring agents in leather by more than 40%. Their ability for this enhancement can be listed as KZR-2>SC-968>FR-102. Among them, KZR-2 owns the best performance for the enhancing of absorption rate ( its influence on the oil is listed as synthetic oil>fish oil>lecithin>vegetable oil).

Growth, Root Formation, and Nutrient Value of Triticale Plants Fertilized with Biosolids

Biosolids are utilized as nutrient rich fertilizer. Little material is available on benefits to forage crops resulting from fertilization with biosolids. This paper aimed to compare the effects of fertilization with biosolids versus commercial nitrogen fertilizer on growth, root formation, and nutrient value of triticale plants in a greenhouse experiment. Per treatment, five pots were seeded with five triticale seeds each. Treatments included a nonfertilized control, fertilization with 100, 200, 300, 400, and 500 ml biosolids per pot, and fertilization with a commercial nitrogen fertilizer at the recommended application rate and at double that rate. Biomass production, root length, root diameter, nitrogen, phosphorus, and potassium concentration were analyzed at harvest. Fertilization with biosolids increased triticale production (P<0.001); production was similar for the 100 to 400 mL treatments. Root length, nitrogen, and phosphorus concentration increased, and potassium concentration decreased linearly with application rate. At the recommended rate, biomass production was similar between fertilization with biosolids and commercial fertilizer. However, plants fertilized with commercial fertilizer had considerably longer roots (P<0.001), higher nitrogen concentration (P<0.05), and lower potassium concentration (P<0.01) than those fertilized with biosolids. Our results indicate that at the recommended application rate, biomass production was similar between fertilization with biosolids and with commercial nitrogen fertilizer, indicating the value of biosolids fertilization as a potential alternative.

Trace metal enrichment in sugarcane soils due to the long-term application of fertilisers, North Queensland, Australia: geochemical and Pb, Sr, and U isotopic compositions

This study aimed to determine whether >80 years of fertiliser application has led to recognisable changes in the trace metal (Cd, Cu, Mo, Ni, Pb, Sr, Th, U, Zn) chemistry of topsoils (0–0.10 m) from sugarcane land, northern Queensland, Australia. The metal concentrations of commercial nitrogen (N) and potassium (K) fertilisers currently used in northern Queensland were generally lower than those of phosphate fertilisers and fertiliser blends. Composite topsoil samples (0–0.10 m depth) taken from canelands had higher median Cd, Mo, Pb, Sr, Th, U, and Zn concentrations than topsoils from forested areas of the catchment. Niobium, Ta, and Ti were confirmed as refractory immobile elements and used as reference elements for the evaluation of trace metal enrichments. Bivariate plots of trace metal/immobile element ratios verified that Cd, Mo, Pb, Sr, Th, U, and Zn are enriched in sugarcane soils compared with background forest soils. Isotopic ratios for Pb, Sr, and U highlight that fertilisers, cane soils, and forest soils have isotopically distinct compositions. Phosphate fertilisers currently used in the agricultural industry possess the most radiogenic 87Sr/86Sr, 234U/238U, 207Pb/206Pb, and 208Pb/206Pb ratios. Background forest soils have the highest 87Sr/86Sr, 207Pb/206Pb, and 208Pb/206Pb and lowest 234U/238U ratios. By contrast, cane soils exhibit 207Pb/206Pb and 208Pb/206Pb ratios that appear on a mixing line between the isotopically distinct background soils and phosphate fertilisers. Also, cane soils possess 234U/238U ratios similar to phosphate fertilisers. Thus, the application of phosphate fertilisers to canelands has resulted in higher Cd, Mo, Pb, Sr, Th, U, and Zn concentrations and more radiogenic Pb, Sr, and U isotope ratios in cane soils. Trace metal ratios and the Pb, Sr, and U isotopic composition of topsoils and fertilisers are useful tools to recognise fertiliser-derived trace metals in agricultural landscapes.