Determination of Polyhexamethylene Biguanide Hydrochloride Using a Lactone-Rhodamine B-Based Fluorescence Optode

A new determination method for polyhexamethylene biguanide hydrochloride (PHMB) using a lactone-rhodamine B (L-RB) based fluorescence optode has been developed. The optode membrane consists of 2-nitrophenyl octyl ether as a plasticizer, L-RB, and poly (vinyl chloride). The optode responds to tetrakis (4-fluorophenyl) borate, sodium salt (NaTPBF) in the μM range. The fluorescence intensity of the L-RB film for PHMB solution containing 20 μM NaTPBF decreased linearly as the concentration of the PHMB solution increased in the concentration range from 0 to 8.0 μM, which shows that PHMB with a concentration range of 0 to 8.0 μM is determined by the L-RB film optode. The concentration of PHMB in the contact lens detergents by the proposed method was in accord with its nominal concentration.

Design of novel and modified dual optode membrane based on carbon dots for both ultratrace copper(ii) and cobalt(ii): derivative spectrophotometric and central composite design study

A selective, accurate and highly sensitive optical chemical sensor (optode) for the simultaneous determination of copper(ii) and cobalt(ii) without any prior separation or purification ion sensing was developed.

New optical sensor based on the immobilization of a triazene ligand in PVC membrane for Hg(II) ion

This paper describes the development and creation of a new sensitive optical sensor that is quite selective to Hg(II) ions in aqueous solution. The sensing element, the newly synthesized methyl 2-[3-(3-methylphenyl)-2-triazen- 1-yl]benzoate, incorporated into a plasticized poly(vinyl chloride) membrane, is able to determine Hg(II) ion with a high selectivity over a wide dynamic range from 5.0?115.1 ?g L-1 at pH 7.5 with a lower detection limit of 0.67 ?g L-1. The response of the optode membrane to Hg(II) was fully reversible and revealed a very good selectivity towards Hg(II) ion from a wide variety of other metal ions in solution. The overall performance characteristics of the sensor were evaluated and good reversibility, wide dynamic range, long life span, long-term response stability and high reproducibility were found. The proposed optical sensor gives proper results in applications including direct determination of the Hg(II) ion in real environmental samples.

High pH sensing with water-soluble porpholactone derivatives and their incorporation into a Nafion® optode membrane

The known optical high pH sensing chromophores, free base and metal complexes (M = 2H, Zn(ii), Pt(ii)) of meso-tetrakis(pentafluorophenyl)porpholactone, and the as yet untested Ga(iii) complex, were made freely water-soluble by derivatization at the aryl group with PEG chains.

Highly selective and sensitive fluorescence optode membrane for uranyl ion based on 5-(9-anthracenylmethyl)-5-aza-2,8-dithia[9],(2,9)-1,10-phenanthrolinophane

A highly sensitive and selective fluorimetric optode membrane based on the enhancement in fluorescence emission of 5-(9-anthracenylmethyl)-5-aza-2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) for subnanomolar detection of uranyl ion is presented.