Highly selective and sensitive fluorescence optode membrane for uranyl ion based on 5-(9-anthracenylmethyl)-5-aza-2,8-dithia[9],(2,9)-1,10-phenanthrolinophane

RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92061-92070 ◽  
Author(s):  
Mojtaba Shamsipur ◽  
Moslem Mohammadi ◽  
Avat (Arman) Taherpour ◽  
Alessandra Garau ◽  
Vito Lippolis
Keyword(s):  
Fluorescence Emission ◽  
Uranyl Ion ◽  
Highly Sensitive ◽  
Optode Membrane

A highly sensitive and selective fluorimetric optode membrane based on the enhancement in fluorescence emission of 5-(9-anthracenylmethyl)-5-aza-2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) for subnanomolar detection of uranyl ion is presented.

scholarly journals A Highly Sensitive Spectrofluorometric Method for the Determination of a New Antidepressant Drug, Reboxetine, in Tablets

2006 ◽  
Vol 89 (4) ◽  
pp. 972-975 ◽  
Author(s):  
ArmaĞan Önal
Keyword(s):  
Antidepressant Drug ◽  
Fluorescence Emission ◽  
Calibration Graph ◽  
Control Analysis ◽  
Optimum Conditions ◽  
Highly Sensitive ◽  
Relative Standard ◽  
Spectrofluorometric Method ◽  
Interday Precision

Abstract A highly sensitive, selective, and rapid spectrofluorometric method has been developed for the determination of reboxetine (REB) in tablets. The method is based on derivatization with 7-chloro-4-nitrobenzofurazan. The product showed an absorption maximum at 476 nm and a fluorescence emission peak at 533 nm in ethyl acetate. The optimum conditions of the reaction were investigated, and it was found that the reaction proceeded quantitatively at pH 8.5, 70C in 5 min. The calibration graph is rectilinear over the range of 0.02-0.40 μg/mL. The relative standard deviation values for intraday and interday precision were 0.40-0.93 and 0.54-1.37%, respectively. The proposed method was applied to the assay of REB in tablets. Mean recovery of REB from the tablets ranged between 99.91-100.20%. The results were compared statistically with those obtained by a method reported in the literature. The method is sensitive, simple, and selective, and can be used for routine quality control analysis.

Highly sensitive fluorescent sensor for Mg2+ and Ca2+ based on a multi-addressable diarylethene

RSC Advances ◽  
2016 ◽  
Vol 6 (24) ◽  
pp. 19957-19963 ◽  
Author(s):  
Shiqiang Cui ◽  
Zhaoyan Tian ◽  
Shouzhi Pu ◽  
Yanfeng Dai
Keyword(s):  
Color Change ◽  
Fluorescent Sensor ◽  
Fluorescence Emission ◽  
Highly Sensitive

A new photochromic diarylethene bearing 8-aminoquinoline unit was designed and synthesized, and the multi-addressable behaviors were investigated. It was highly sensitive towards Mg2+ and Ca2+ with different fluorescence emission and color change.

scholarly journals A rapid and highly sensitive biomarker detection platform based on a temperature-responsive liposome-linked immunosorbent assay

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Runkai Hu ◽  
Keitaro Sou ◽  
Shinji Takeoka
Keyword(s):  
Immunosorbent Assay ◽  
Limit Of Detection ◽  
Specific Antigen ◽  
Fluorescence Emission ◽  
Detection Sensitivity ◽  
Sensitive Detection ◽  
Enzyme Linked Immunosorbent Assay ◽  
Temperature Responsive ◽  
Highly Sensitive ◽  
Highly Sensitive Detection

Abstract The enzyme-linked immunosorbent assay (ELISA) is widely used in various fields to detect specific biomarkers. However, ELISA tests have limited detection sensitivity (≥ 1 pM), which is insufficiently sensitive for the detection of small amounts of biomarkers in the early stages of disease or infection. Herein, a method for the rapid and highly sensitive detection of specific antigens, using temperature-responsive liposomes (TLip) containing a squaraine dye that exhibits fluorescence at the phase transition temperature of the liposomes, was developed. A proof-of-concept study using biotinylated TLip and a streptavidin-immobilized microwell plate showed that the TLip bound to the plate via specific molecular recognition could be distinguished from unbound TLip within 1 min because of the difference in the heating time required for the fluorescence emission of TLip. This system could be used to detect prostate specific antigen (PSA) based on a sandwich immunosorbent assay using detection and capture antibodies, in which the limit of detection was as low as 27.6 ag/mL in a 100-μL PSA solution, 0.97 aM in terms of molar concentration. The present temperature-responsive liposome-linked immunosorbent assay provides an advanced platform for the rapid and highly sensitive detection of biomarkers for use in diagnosis and biological inspections.

A Fluorescent g-C3N4 Nanosensor for Detection of Dichromate Ions

2020 ◽  
Vol 16 (5) ◽  
pp. 593-601 ◽  
Author(s):  
Ghasem Shiravand ◽  
Alireza Badiei ◽  
Hassan Goldooz ◽  
Mehdi Karimi ◽  
Ghodsi M. Ziarani ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Fluorescence Emission ◽  
High Sensitivity ◽  
Inner Filter Effect ◽  
Quenching Mechanism ◽  
Fluorescence Emission Spectra ◽  
Selective Determination ◽  
Hydrothermal Oxidation ◽  
Highly Sensitive ◽  
Prepared Nanostructures

Background: Dichromate (Cr2O7 2-) ion is one of the carcinogenic and toxic spices in environment which can easily contaminate the environment due to its high solubility in water. Therefore, a lot of attention has been focused on the detection of Cr2O7 2- with high sensitivity and selectivity. Methods: In present work, nitrogen-rich precursor was used for synthesizing graphitic carbon nitride (g-C3N4) nanostructures through hydrothermal oxidation of g-C3N4 nanosheets. The prepared nanostructures show two distinct fluorescence emissions centered at 368 and 450 nm which are highly sensitive toward Cr2O7 2- ions. Results: The as-prepared g-C3N4 was characterized by several techniques such as Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD) and fluorescence emission spectra. The XRD pattern of prepared nanostructures illustrated two diffraction patterns (at 13.4° and 27.6°) indicating tri-s-tri-azine-based structures. The g-C3N4 exhibited good selectivity and sensitivity toward Cr2O7 2- among other anions. According to titration test, the detection limit and stern-volmer constant (Ksv) were calculated as 40 nM and 0.13×106 M-1, respectively. The investigation of quenching mechanism shows that Cr2O7 2- may form hydrogen bonding with surface groups of g-C3N4 (such as NH2, OH and COOH) resulted in more fluorescence quenching in comparison with the pure inner filter effect. Conclusion: The g-C3N4 nanostructures were successfully synthesized through the hydrothermal oxidation. The as-prepared g-C3N4 can be used as a highly sensitive fluorescent probe for the selective determination of Cr2O7 2 ion among other anions. The quenching mechanism was experimentally studied. According to reliable responses in real sample tests, it can be proposed that g-C3N4 nanostructure is a suitable sensitive nanosensor for detection of Cr2O7 2 ions in aqueous media.

Design of novel and modified dual optode membrane based on carbon dots for both ultratrace copper(ii) and cobalt(ii): derivative spectrophotometric and central composite design study

2018 ◽  
Vol 42 (4) ◽  
pp. 2590-2604 ◽  
Author(s):  
Seyed Alireza Shahamirifard ◽  
Mehrorang Ghaedi
Keyword(s):  
Central Composite Design ◽  
Carbon Dots ◽  
Chemical Sensor ◽  
Optical Chemical Sensor ◽  
Ion Sensing ◽  
Highly Sensitive ◽  
Optode Membrane ◽  
Central Composite ◽  
Determination Of Copper

A selective, accurate and highly sensitive optical chemical sensor (optode) for the simultaneous determination of copper(ii) and cobalt(ii) without any prior separation or purification ion sensing was developed.

scholarly journals Novel Multifunctional Luminescent Electrospun Fluorescent Nanofiber Chemosensor-Filters and Their Versatile Sensing of pH, Temperature, and Metal Ions

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1259 ◽  
Author(s):  
Bo-Yu Chen ◽  
Yen-Chen Lung ◽  
Chi-Ching Kuo ◽  
Fang-Cheng Liang ◽  
Tien-Liang Tsai ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Color Change ◽  
Ethylenediaminetetraacetic Acid ◽  
Fluorescence Emission ◽  
Volume Ratio ◽  
High Sensitivity ◽  
Electrospinning Process ◽  
Solution Temperature ◽  
Highly Sensitive ◽  
Nanofibrous Membranes

Novel multifunctional fluorescent chemosensors composed of electrospun (ES) nanofibers with high sensitivity toward pH, mercury ions (Hg2+), and temperature were prepared from poly(N-Isopropylacrylamide-co-N-methylolacrylamide-co-rhodamine derivative) (poly(NIPAAm-co-NMA-co-RhBN2AM)) by employing an electrospinning process. NIPAAm and NMA moieties provide hydrophilic and thermo-responsive properties (absorption of Hg2+ in aqueous solutions), and chemical cross-linking sites (stabilization of the fibrous structure in aqueous solutions), respectively. The fluorescent probe, RhBN2AM is highly sensitive toward pH and Hg2+. The synthesis of poly(NIPAAm-co-NMA-co-RhBN2AM) with different compositions was carried on via free-radical polymerization. ES nanofibers prepared from sensory copolymers with a 71.1:28.4:0.5 NIPAAm:NMA:RhBN2AM ratio (P3 ES nanofibers) exhibited significant color change from non-fluorescent to red fluorescence while sensing pH (the λPL, max exhibited a 4.8-fold enhancement) or Hg2+ (at a constant Hg2+ concentration (10−3 M), the λPL, max of P3-fibers exhibited 4.7-fold enhancement), and high reversibility of on/off switchable fluorescence emission at least five times when Hg2+ and ethylenediaminetetraacetic acid (EDTA) were sequentially added. The P3 ES nanofibrous membranes had a higher surface-to-volume ratio to enhance their performance than did the corresponding thin films. In addition, the fluorescence emission of P3 ES nanofibrous membranes exhibited second enhancement above the lower critical solution temperature. Thus, the ES nanofibrous membranes prepared from P3 with on/off switchable capacity and thermo-responsive characteristics can be used as a multifunctional sensory device for specific heavy transition metal (HTM) in aqueous solutions.

Boron-doped and serine and histidine-functionalized graphene quantum dot with strong yellow fluorescence emission for highly sensitive detection of carbofuran in cucumber and cabbage

2021 ◽  
Author(s):  
Na Wang ◽  
Ruiyi Li ◽  
Qinsheng Wang ◽  
Yongqiang Yang ◽  
Nana Li ◽  
...  
Keyword(s):  
Quantum Dot ◽  
Graphene Quantum Dots ◽  
Fluorescence Emission ◽  
Functionalized Graphene ◽  
Yellow Fluorescence ◽  
Graphene Quantum Dot ◽  
Boron Doped ◽  
Highly Sensitive ◽  
Light Excitation ◽  
Highly Sensitive Detection

Weak fluorescence at visible light excitation limits many applications of graphene quantum dots. The paper reports synthesis of boron-doped and serine and histidine-functionalized graphene quantum dot (B-Ser-His-GQD). The resulting B-Ser-His-GQD...

scholarly journals Development of Fluorescent Reagent Based on Ligand Exchange Reaction for the Highly Sensitive and Selective Detection of Dopamine in the Serum

Sensors ◽  
2019 ◽  
Vol 19 (18) ◽  
pp. 3928 ◽  
Author(s):  
Yoshio Suzuki
Keyword(s):  
Fluorescence Intensity ◽  
Ligand Exchange ◽  
Fluorescence Emission ◽  
Molecular Probe ◽  
Free Form ◽  
Selective Detection ◽  
The Novel ◽  
Ligand Exchange Reaction ◽  
Exchange Site ◽  
Highly Sensitive

A new fluorescent probe (BDP-Fe2+) was developed for targeting dopamine, with a boron–dipyrromethenyl (BDP) group as the fluorophore and a Fe2+ complex as the ligand exchange site. The free form of BDP-Fe2+ in solution displayed weak fluorescence emission, while it showed strong fluorescence emission after interaction with dopamine due to the release of Fe2+ from BDP-Fe2+, confirming the binding of Fe2+ to dopamine. The increase in fluorescence intensity was concentration-dependent, and a good linear relationship was observed between the fluorescence intensity and dopamine concentration. The detection limit of dopamine by BDP-Fe2+ was 1.1 nM, indicating a 20-fold higher sensitivity than that of previously reported compounds. The reaction of BDP-Fe2+ with dopamine was not affected by the presence of foreign substances, allowing the highly selective detection of dopamine in the human serum sample. The results of this study indicate that the novel compound BDP-Fe2+ is a reliable fluorescent molecular probe for the detection of dopamine and can be widely employed in diverse scientific areas.

scholarly journals Novel Multifunctional Luminescent Electrospun Fluorescent Nanofiber Chemosensors-Filter and Their Versatile Sensing of pH, Temperature, and Metal Ions

2018 ◽  
Author(s):  
Bo-Yu Chen ◽  
Yen-Chen Lung ◽  
Chi-Ching Kuo ◽  
Fang-Cheng Liang ◽  
Tien-Liang Tsai ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Color Change ◽  
Ethylenediaminetetraacetic Acid ◽  
Fluorescence Emission ◽  
Volume Ratio ◽  
High Sensitivity ◽  
Electrospinning Process ◽  
Solution Temperature ◽  
Highly Sensitive ◽  
Nanofibrous Membranes

Novel multifunctional fluorescent chemosensors composed of electrospun (ES) nanofibers with high sensitivity toward pH, mercury ions (Hg2+), and temperature were prepared from poly(N-Isopropylacrylamide-co-N-methylolacrylamide-co-rhodamine derivative) (poly(NIPAAm-co-NMA-co-RhBN2AM)) by employing electrospinning process. NIPAAm and NMA moieties provide hydrophilic and thermo-responsive properties (absorption of Hg2+ in aqueous solutions), and chemical cross-linking sites (stabilization of the fibrous structure in aqueous solutions), respectively. The fluorescent probe, RhBN2AM is highly sensitive toward pH and Hg2+. Synthesis of poly(NIPAAm-co-NMA-co-RhBN2AM) with different compositions were carried on via free-radical polymerization. ES nanofibers prepared from sensory copolymers with a 71.1:28.4:0.5 NIPAAm: NMA: RhBN2AM ratio (P3 ES nanofibers) exhibited significant color change from nonfluorescent to red fluorescence while sensing pH or Hg2+, and high reversibility of on/off switchable fluorescence emission when Hg2+ and ethylenediaminetetraacetic acid (EDTA) were sequentially added. The P3 ES nanofibrous membranes had a higher surface-to-volume ratio to enhance their performance than did the corresponding thin films. In addition, the fluorescence emission of P3 ES nanofibrous membranes exhibited second enhancement above the lower critical solution temperature. Thus, the ES nanofibrous membranes prepared from P3 with on/off switchable capacity and thermo-responsive characteristics can be used as multifunctional sensory devise for specific heavy transition metal (HTM) in aqueous solutions.

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