Several Aspects of Application of Nanodiamonds as Reinforcements for Metal Matrix Composites

After detonation synthesis, primary nanodiamond particles are around 4–6 nm in size. However, they join into agglomerates with larger parameters and weak bonds between particles. The introduction of agglomerates into a metal matrix can lead to the weakness of composites. This paper demonstrates the possibility of obtaining a non-agglomerated distribution of nanodiamonds inside a metal matrix. The fabrication method was based on mechanical alloying to create additional stresses and deformations by phase transformations during treatment in a planetary mill. According to the findings, the starting temperature of the reaction between the non-agglomerated nanodiamonds and aluminium matrix reduces to 450 °C. Furthermore, the paper shows that existing methods (annealing for the transformation of a diamond structure into graphitic material and cleaning from this graphitic material) cannot reduce the sizes of nanodiamonds in the agglomerated state. Agglomerated nanodiamonds transform into carbon onions (graphitic material) during annealing in a vacuum in the following way: the nanodiamonds located in the surface layers of the agglomerate are the first to undergo the complete transformation followed by the transformation of nanoparticles in its deeper layers. In the intermediate state, the agglomerate has a graphitic surface layer and a core from nanodiamonds: cleaning from graphite cannot reduce nanodiamond particle size.

TRIBOTECHNICAL CHARACTERISTICS OF CARBON-BEARING LUBRICANTS

The development of technology for manufacturing nanostructured substances in amounts that could suffice an interlaboratory research is a high priority task for the implementation of nanoproducts. The ultra dispersiblis clusters of synthetic carbon are used as on extra component in polymeric materials. The substances have a high dispersibility and activity of the surface. To study properties of mineral oils, modified ultra dispersiblis clusters of synthetic carbon is of interest. The present activity is devoted to the research of the modifying influence of ultra dispersiblis clusters of synthetic carbon on viscosity of the characteristic of mineral oils and their stability at various temperatures. In the preparation of diamond secondary suspensions not only statistic average sizes of particles should be taken into consideration, but also polydispersity parameters of nanodiamond particle population too.

Construction of a Nanodiamond–Tamoxifen Complex as a Breast Cancer Drug Delivery Vehicle

According to the World Health Organization, breast cancer represents 16% of all cancer cases in women and is the second most common cancer. In the past decades, the mortality among patients with metastasis breast cancer has been reduced significantly via drug delivery by means of nanodiamond therapies, which are both biocompatible and scalable. In this study, we determined a theoretical pathway for the construction of a nanodiamond–tamoxifen complex that will act as a drug delivery vehicle for targeting tumor tissues of breast cancer. The tamoxifen pharmacophore was defined and the binding zone was identified for the electrostatic interaction between tamoxifen and a functionalized site of a nanodiamond particle allowing for attachment of the payload (this drug) to the surface of the nanodiamond particle. In addition, an analysis of the intermolecular interaction between the nanodiamond and tamoxifen was conducted, showing three hydrogen bonds complying fully with Lipinski’s rule of five, which states that a compound should have five or fewer hydrogen bonds to be permeating and easily absorbed by the body (qualitative prediction). All calculations were performed using the conceptual Density Functional Theory with the M06 functional and the basis set 6-31G(d). The solvent effect has been taken into account by an implicit model, the conductor like polarizable continuum model.

Technology for Nanodiamond Electroless Composite Plating and Properties of Coating

The Ni-P-nanodiamond electroless composite plating adopting nanodiamond made dispersed acid liquid and the technology for Nanodiamond Electroless composite plating on steel plate was studied. The effect of plating factors on the properties of the coating was studied with orthogonal tests. The optimum formula of nanodiamond electroless composite plating was as follow: nanodiamond 3.0g/L, temperature 85°C，pH 4.5.Microstructure, corrosion resistance and wear resistance of coating were studied. The result show that The nanodiamond content of the composite coating can get weight 15.44%, and the cystiform microstructure is fine and the cohension between coating and base is good. The coefficient of friction of coating is about 0.8 time compared with that of pure Ni-P coating and its corrosion resistance was improved greatly due to the fine nanodiamond particle occupying in the little pit.