homoleptic complexes
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2020 ◽  
Vol 49 (37) ◽  
pp. 13072-13082 ◽  
Author(s):  
Andreas Rösch ◽  
Simon H. F. Schreiner ◽  
Philipp Schüler ◽  
Helmar Görls ◽  
Robert Kretschmer

By dealing with various bis(amidine)s or bis(guanidine)s and different magnesium sources, we got a full house of homoleptic complexes. However, the joker card showing a heteroleptic complex is waiting to be used.


2019 ◽  
Vol 43 (45) ◽  
pp. 17756-17773
Author(s):  
Gonzalo Scalese ◽  
Ignacio Machado ◽  
Isabel Correia ◽  
Joao Costa Pessoa ◽  
Lucía Bilbao ◽  
...  

[VIVO(L-H)2] and [VVO(OCH3)(L-H)2] compounds of 8-hydroxyquinoline derivatives L showed activity against Trypanosoma cruzi and Leishmania infantum and high selectivities. Metallomics and interaction with BSA, apo-HTF and DNA were studied.


2017 ◽  
Vol 46 (44) ◽  
pp. 15330-15339 ◽  
Author(s):  
Maria Baskin ◽  
Natalia Fridman ◽  
Monica Kosa ◽  
Galia Maayan

We describe the preparation of synthetically challenging heteroleptic complexes by considering the solubility properties of their corresponding favored homoleptic complexes.


2017 ◽  
Vol 53 (37) ◽  
pp. 5186-5189 ◽  
Author(s):  
Abir Goswami ◽  
Indrajit Paul ◽  
Michael Schmittel

The fusion of two homoleptic complexes quantitatively created a novel three-component nanorotor.


2017 ◽  
Vol 53 (34) ◽  
pp. 4706-4709 ◽  
Author(s):  
Jérôme Long ◽  
Boris G. Shestakov ◽  
Dan Liu ◽  
Liviu F. Chibotaru ◽  
Yannick Guari ◽  
...  

We report the synthesis and magnetic properties of a series of new organometallic homoleptic complexes Li(DME)3[Ln(DAD)2] (Ln = Dy (1a, 1b), Tb(2), and Er(3)).


2017 ◽  
Vol 16 (4) ◽  
pp. 585-595
Author(s):  
Angelo Lanzilotto ◽  
Martin Kuss-Petermann ◽  
Oliver S. Wenger ◽  
Edwin C. Constable ◽  
Catherine E. Housecroft

The syntheses and electrochemical and photophysical properties of the homoleptic complexes [Zn(1)2][PF6], [Fe(1)2][PF6] and [Ru(1)2][PF6] where 1 is the metalloligand 7-(4-([2,2′:6′,2′′-terpyridin]-4′-yl)phenyl)-5,10,15,20-tetraphenylporphyrinatozinc(ii) are reported.


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