Magnesium bis(amidinate) and bis(guanidinate) complexes: impact of the ligand backbone and bridging groups on the coordination behaviour

2020 ◽  
Vol 49 (37) ◽  
pp. 13072-13082 ◽  
Author(s):  
Andreas Rösch ◽  
Simon H. F. Schreiner ◽  
Philipp Schüler ◽  
Helmar Görls ◽  
Robert Kretschmer

By dealing with various bis(amidine)s or bis(guanidine)s and different magnesium sources, we got a full house of homoleptic complexes. However, the joker card showing a heteroleptic complex is waiting to be used.

2021 ◽  
Author(s):  
Y. Kitamoto ◽  
K. Oda ◽  
K. Ogino ◽  
K. Hiyama ◽  
H. Kita ◽  
...  

An azadioxa-planar triphenylborane was synthesized for the first time and it was found that bridging groups have a critical role in changing its molecular properties.


2008 ◽  
Vol 2008 (34) ◽  
pp. 5408-5417 ◽  
Author(s):  
Olga Crespo ◽  
M. Concepción Gimeno ◽  
Peter G. Jones ◽  
Antonio Laguna ◽  
Mar Naranjo ◽  
...  

2007 ◽  
pp. 2823 ◽  
Author(s):  
Steven Kealey ◽  
Nicholas J. Long ◽  
Philip W. Miller ◽  
Andrew J. P. White ◽  
Peter B. Hitchcock ◽  
...  

2007 ◽  
Vol 2007 (30) ◽  
pp. 4770-4780 ◽  
Author(s):  
Nawal K. Al-Rasbi ◽  
Harry Adams ◽  
Lindsay P. Harding ◽  
Michael D. Ward

2011 ◽  
Vol 376 (1) ◽  
pp. 317-324 ◽  
Author(s):  
Rathinasabapathi Prabhakaran ◽  
Kalaivani Palaniappan ◽  
Rui Huang ◽  
Monica Sieger ◽  
Wolfgang Kaim ◽  
...  

Polyhedron ◽  
2008 ◽  
Vol 27 (2) ◽  
pp. 879-886 ◽  
Author(s):  
E. Viñuelas-Zahínos ◽  
M.A. Maldonado-Rogado ◽  
F. Luna-Giles ◽  
F.J. Barros-García

2017 ◽  
Vol 19 (39) ◽  
pp. 26969-26979 ◽  
Author(s):  
Qun-Yan Wu ◽  
Yu-Ting Song ◽  
Lin Ji ◽  
Cong-Zhi Wang ◽  
Zhi-Fang Chai ◽  
...  

The mechanisms of Am(iii)/Eu(iii) selectivity of three mixed N,O-donor ligands with different bridging groups were obtained and compared.


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