Heteroleptic complexesviasolubility control: examples of Cu(ii), Co(ii), Ni(ii) and Mn(ii) complexes based on the derivatives of terpyridine and hydroxyquinoline

2017 ◽  
Vol 46 (44) ◽  
pp. 15330-15339 ◽  
Author(s):  
Maria Baskin ◽  
Natalia Fridman ◽  
Monica Kosa ◽  
Galia Maayan
Keyword(s):  
Heteroleptic Complexes ◽  
Derivatives Of ◽  
Homoleptic Complexes

We describe the preparation of synthetically challenging heteroleptic complexes by considering the solubility properties of their corresponding favored homoleptic complexes.

Synthesis and characterization of two ruthenium(II) heteroleptic complexes of annelated derivatives of 2,2′-bipyridine

1998 ◽  
Vol 22 (4) ◽  
pp. 373-380 ◽  
Author(s):  
Edmond Amouyal ◽  
Florence Penaud-Berruyer ◽  
Driss Azhari ◽  
Hassan Aït-Haddou ◽  
Christophe Fontenas ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Heteroleptic Complexes ◽  
Derivatives Of

scholarly journals Phosphonate-functionalized heteroleptic ruthenium(II) bis(2,2′:6′,2″-terpyridine) complexes

2014 ◽  
Vol 92 (8) ◽  
pp. 724-730 ◽  
Author(s):  
Edwin C. Constable ◽  
Catherine E. Housecroft ◽  
Markéta Šmídková ◽  
Jennifer A. Zampese
Keyword(s):  
Crystal Structure ◽  
Methyl Ester ◽  
Single Crystal ◽  
Ester Group ◽  
Positive Potential ◽  
Small Shift ◽  
Heteroleptic Complexes ◽  
Starting Point ◽  
P Type ◽  
Derivatives Of

The heteroleptic complexes [Ru(1)(4)][PF6]2, [Ru(2)(4)][PF6]2, [Ru(Phtpy)(4)][PF6]2, and [Ru(pytpy)(4)][PF6]2 (Phtpy = 4′-phenyl-2,2′:6′,2″-terpyridine, pytpy = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine, 1 and 2 = 4-methyl ester substituted derivatives of Phtpy and pytpy, 4 = ethyl 2,2′:6′,2″-terpyridine-4′-phosphonate) have been prepared. The single crystal structure of ligand 1 (1 = methyl 4-carboxy-4′-phenyl-2,2′:6′,2″-terpyridine) is reported. The introduction of the 4-methyl ester group causes a small red shift in the MLCT band of the ruthenium(II) complexes and a small shift to a more positive potential for the Ru2+/Ru3+ couple. The new complexes should serve as a useful starting point for development of ruthenium(II) dyes suited for sensitization of p-type semiconductors.

A series of heteroleptic complexes of the type fac-[MnIIIL2]− [H2L=derivatives of N-(2-hydroxybenzyl)glycine or N-(5-nitro-2-hydroxybenzyl)sarcosine] possessing unusual Mn(III) co-ordination spheres

1999 ◽  
Vol 290 (2) ◽  
pp. 228-236 ◽  
Author(s):  
Musa S. Shongwe ◽  
Masahiro Mikuriya ◽  
Ryoji Nukada ◽  
Eric W. Ainscough ◽  
Andrew M. Brodie ◽  
...  
Keyword(s):  
Heteroleptic Complexes ◽  
Derivatives Of

Physical Properties of TCNQ Salts with N-Methyl Derivatives of Pyridine

1982 ◽  
Vol 85 (1) ◽  
pp. 257-263 ◽  
Author(s):  
A. Graja ◽  
M. Przybylski ◽  
B. Butka ◽  
R. Swietlik
Keyword(s):  
Physical Properties ◽  
Methyl Derivatives ◽  
Derivatives Of

Diorganyl Derivatives of Tellurium(IV) (σ-Telluranes of R 2 TeX 2 Type)

2002 ◽  
Vol 23 (2) ◽  
pp. 125-207 ◽  
Author(s):  
Igor D. Sadekov ◽  
Alexander V. Zakharov ◽  
Alexander A. Maksimenko
Keyword(s):  
Derivatives Of
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