scholarly journals Spray Deposition of Ag Nanowire–Graphene Oxide Hybrid Electrodes for Flexible Polymer–Dispersed Liquid Crystal Displays

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2231 ◽  
Author(s):  
Yumi Choi ◽  
Chang Kim ◽  
Sungjin Jo
Keyword(s):  
Optical Properties ◽  
Graphene Oxide ◽  
Sheet Resistance ◽  
Indium Tin Oxide ◽  
Spray Deposition ◽  
Spray Coating ◽  
Optical Transmittance ◽  
Large Area ◽  
Flexible Polymer ◽  
Polymer Dispersed

We investigated the effect of different spray-coating parameters on the electro-optical properties of Ag nanowires (NWs). Highly transparent and conductive Ag NW–graphene oxide (GO) hybrid electrodes were fabricated by using the spray-coating technique. The Ag NW percolation network was modified with GO and this led to a reduced sheet resistance of the Ag NW–GO electrode as the result of a decrease in the inter-nanowire contact resistance. Although electrical conductivity and optical transmittance of the Ag NW electrodes have a trade-off relationship, Ag NW–GO hybrid electrodes exhibited significantly improved sheet resistance and slightly decreased transmittance compared to Ag NW electrodes. Ag NW–GO hybrid electrodes were integrated into smart windows based on polymer-dispersed liquid crystals (PDLCs) for the first time. Experimental results showed that the electro-optical properties of the PDLCs based on Ag NW–GO electrodes were superior when compared to those of PDLCs based on only Ag NW electrodes. This study revealed that the hybrid Ag NW–GO electrode is a promising material for manufacturing the large-area flexible indium tin oxide (ITO)-free PDLCs.

scholarly journals Atomic Layer-Deposited Al-Doped ZnO Thin Films for Display Applications

Coatings ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 539 ◽  
Author(s):  
Dimitre Dimitrov ◽  
Che-Liang Tsai ◽  
Stefan Petrov ◽  
Vera Marinova ◽  
Dimitrina Petrova ◽  
...  
Keyword(s):  
Thin Films ◽  
Liquid Crystal ◽  
Indium Tin Oxide ◽  
Near Infrared ◽  
Atomic Layer ◽  
Optical Transmittance ◽  
Flexible Polymer ◽  
Polymer Dispersed ◽  
Infrared Spectral ◽  
Aluminum Doped Zinc Oxide

The integration of high uniformity, conformal and compact transparent conductive layers into next generation indium tin oxide (ITO)-free optoelectronics, including wearable and bendable structures, is a huge challenge. In this study, we demonstrate the transparent and conductive functionality of aluminum-doped zinc oxide (AZO) thin films deposited on glass as well as on polyethylene terephthalate (PET) flexible substrates by using an atomic layer deposition (ALD) technique. AZO thin films possess high optical transmittance at visible and near-infrared spectral range and electrical properties competitive to commercial ITO layers. AZO layers deposited on flexible PET substrates demonstrate stable sheet resistance over 1000 bending cycles. Based on the performed optical and electrical characterizations, several applications of ALD AZO as transparent conductive layers are shown—AZO/glass-supported liquid crystal (LC) display and AZO/PET-based flexible polymer-dispersed liquid crystal (PDLC) devices.

scholarly journals ALD Deposited ZnO:Al Films on Mica for Flexible PDLC Devices

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1011
Author(s):  
Dimitre Z. Dimitrov ◽  
Zih Fan Chen ◽  
Vera Marinova ◽  
Dimitrina Petrova ◽  
Chih Yao Ho ◽  
...  
Keyword(s):  
Near Infrared ◽  
Atomic Layer ◽  
Optical Transmittance ◽  
Force Microscopy ◽  
Flexible Polymer ◽  
Layer Deposition ◽  
Polymer Dispersed ◽  
Muscovite Mica ◽  
Infrared Spectral ◽  
Continuous Bending

In this work, highly conductive Al-doped ZnO (AZO) films are deposited on transparent and flexible muscovite mica substrates by using the atomic layer deposition (ALD) technique. AZO-mica structures possess high optical transmittance at visible and near-infrared spectral range and retain low electric resistivity, even after continuous bending of up to 800 cycles. Structure performances after bending tests have been supported by atomic force microscopy (AFM) analysis. Based on performed optical and electrical characterizations AZO films on mica are implemented as transparent conductive electrodes in flexible polymer dispersed liquid crystal (PDLC) devices. The measured electro-optical characteristics and response time of the proposed devices reveal the higher potential of AZO-mica for future ITO-free flexible optoelectronic applications.

scholarly journals Tunable Memristic Characteristics Based on Graphene Oxide Charge-Trap Memory

Micromachines ◽  
2019 ◽  
Vol 10 (2) ◽  
pp. 151 ◽  
Author(s):  
Lei Li
Keyword(s):  
Graphene Oxide ◽  
Electron Microscope ◽  
Indium Tin Oxide ◽  
Nonvolatile Memory ◽  
Nanocomposite Films ◽  
Large Area ◽  
Charge Trap ◽  
Nonvolatile Memory Devices ◽  
Device Applications ◽  
Sandwiched Structure

Solution-processable nonvolatile memory devices, consisted of graphene oxide (GO) embedded into an insulating polymer polymethyl methacrylate (PMMA), were manufactured. By varying the GO content in PMMA nanocomposite films, the memristic conductance behavior of the Ni/PMMA:GO/Indium tin oxide (ITO) sandwiched structure can be tuned in a controllable manner. An investigation was made on the memristic performance mechanism regarding GO charge-trap memory; these blends were further characterized by transmission electron microscope (TEM), scanning electron microscope (SEM), Fourier transform infrared spectra (FTIR), Raman spectra, thermogravimetric analysis, X-ray diffraction (XRD), ultraviolet-visible spectroscopy, and fluorescence spectra in particular. Dependent on the GO content, the resistive switching was originated from the charges trapped in GO, for which bipolar tunable memristic behaviors were observed. PMMA:GO composites possess an ideal capability for large area device applications with the benefits of superior electronic properties and easy chemical modification.

scholarly journals Pulsed Electrodeposition for Copper Nanowires

Crystals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 218 ◽  
Author(s):  
Duc-Thinh Vuong ◽  
Ha-My Hoang ◽  
Nguyen-Hung Tran ◽  
Hyun-Chul Kim
Keyword(s):  
Sheet Resistance ◽  
Indium Tin Oxide ◽  
Transparent Electrode ◽  
Pulse Frequency ◽  
Transparent Conductors ◽  
Copper Nanowires ◽  
Ambient Conditions ◽  
Smart Windows ◽  
Promising Alternative ◽  
Flexible Polymer

Copper nanowires (Cu NWs) are a promising alternative to indium tin oxide (ITO), for use as transparent conductors that exhibit comparable performance at a lower cost. Furthermore, Cu NWs are flexible, a property not possessed by ITO. However, the Cu NW-based transparent electrode has a reddish color and tends to deteriorate in ambient conditions due to the oxidation of Cu. In this paper, we propose a pulsed-current (PC) plating method to deposit nickel onto the Cu NWs in order to reduce oxidation over a 30-day period, and to minimize the sheet resistance. Additionally, the effects of the pulse current, duty cycle, and pulse frequency on the performance of the Cu–Ni (copper–nickel) NW films have also been investigated. As a result, the reddish color of the electrode was eliminated, as oxidation was completely suppressed, and the sheet resistance was reduced from 35 Ω/sq to 27 Ω/sq. However, the transmittance decreased slightly from 86% to 76% at a wavelength of 550 nm. The Cu–Ni NW electrodes also exhibited excellent long-term cycling stability after 6000 bending cycles. Our fabricated Cu–Ni electrodes were successfully applied in flexible polymer-dispersed liquid crystal smart windows.

Structural and Optical Properties of InSnO3 Sol-Gel Coatings to Use in Windows Glass Buildings

2010 ◽  
Vol 168-170 ◽  
pp. 2348-2351
Author(s):  
Lazaro De Jesus Dominguez Gallegos ◽  
Angélica Silvestre López Rodríguez ◽  
Pio Sifuentes Gallardo ◽  
Miguel Angel Hernández Rivera ◽  
María Guadalupe Garnica Romo ◽  
...  
Keyword(s):  
Optical Properties ◽  
Indium Tin Oxide ◽  
Sol Gel ◽  
Visible Region ◽  
Optical Transmittance ◽  
Indium Chloride ◽  
Glass Substrates ◽  
Tin Chloride ◽  
Ito Thin Films ◽  
Ito Films

Indium stannate (InSnO3) films doping with small amounts of copper are made highly useful as architectural window coatings. Indium-tin-oxide (ITO) has attracted intense interest due to some of its unique characteristics; it has high optical transmittance in the visible region, low electric resistivity, and chemical stability. Therefore, ITO thin films have been found to play an important role in opto-electronic applications. In this work, uniform and transparent ITO films were deposited onto glass substrates using a sol-gel process. The initial sols were prepared by mixing solutions of indium chloride prepared in anhydrous ethanol with tin chloride and mechanically stirring and refluxed 2 hours and aged 2 week, the resultant mixture until a clear and sticky coating sol was obtained. The glass substrates were spin-coated and annealed at 500 °C. Because annealing conditions affect the microstructures, the properties of the resultant ITO films can be controlled. The optical transmittance of 200 nm thick ITO film was more than 80% in the visible region. The surface morphology examined by SEM appears to be uniform over large surface areas. The structural, microstructural and optical properties of the coatings and powders made from the sols were extensively characterized by using XRD, AFM and spectrophotometer techniques

scholarly journals Using Dual Microresonant Cavity and Plasmonic Effects to Enhance the Photovoltaic Efficiency of Flexible Polymer Solar Cells

Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 944 ◽  
Author(s):  
Wenfei Shen ◽  
Guoqing Zhao ◽  
Xiaolin Zhang ◽  
Fanchen Bu ◽  
Jungheum Yun ◽  
...  
Keyword(s):  
Solar Cells ◽  
Sheet Resistance ◽  
Active Layer ◽  
Indium Tin Oxide ◽  
Light Harvesting ◽  
Polymer Solar Cells ◽  
Sio2 Nanoparticles ◽  
Flexible Polymer ◽  
Photoactive Polymers ◽  
Plasmonic Effects

Fabricating polymer solar cells (PSCs) on flexible polymer substrates, instead of on hard glass, is attractive for implementing the advantage and uniqueness of the PSCs represented by mechanically rollable and light-weight natures. However, simultaneously achieving reliable robustness and high-power conversion efficiency (PCE) in such flexible PSCs is still technically challenging due to poor light harvesting of thin photoactive polymers. In this work, we report a facile, effective strategy for improving the light-harvesting performance of flexible PSCs without sacrificing rollability. Very high transparent (93.67% in 400–800 nm) and low sheet resistance (~10 Ω sq−1) ZnO/Ag(O)/ZnO electrodes were implemented as the flexible substrates. In systematically comparison with ZnO/Ag/ZnO electrodes, small amount of oxygen induced continuous metallic films with lower thickness, which resulted in higher transmittance and lower sheet resistance. To increase the light absorption of thin active layer (maintain the high rollability of active layer), a unique platform simultaneously utilizing both a transparent electrode configuration based on an ultrathin oxygen-doped Ag, Ag(O), and film and plasmonic Ag@SiO2 nanoparticles were designed for fully leveraging the advantages of duel microresonant cavity and plasmonic effects to enhance light absorbance in photoactive polymers. A combination of the ZnO/Ag(O)/ZnO electrode and Ag@SiO2 nanoparticles significantly increased the short-current density of PSCs to 17.98 mA cm−2 with enhancing the photoluminescence of PTB7-Th film. The flexible PSC using the optimized configuration provided an average PCE of 8.04% for flexible PSCs, which was increased by 36.27% compared to that of the PSC merely using a conventional transparent indium tin oxide electrode.

scholarly journals Nanostructural Characterisation and Optical Properties of Sputter-Deposited Thick Indium Tin Oxide (ITO) Coatings

Coatings ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1127
Author(s):  
Andrius Subacius ◽  
Bill Baloukas ◽  
Etienne Bousser ◽  
Steve J. Hinder ◽  
Mark A. Baker ◽  
...  
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Nanocrystalline Structure ◽  
Optical Transmittance ◽  
Glass Substrates ◽  
Ito Thin Films ◽  
Sputter Deposited ◽  
Thick Coatings

Indium tin oxide (ITO) thin films, used in many optoelectronic applications, are typically grown to a thickness of a maximum of a few hundred nanometres. In this work, the composition, microstructure and optical/electrical properties of thick ITO coatings deposited by radio frequency magnetron sputtering from a ceramic ITO target in an Ar/O2 gas mixture (total O2 flow of 1%) on unheated glass substrates are reported for the first time. In contrast to the commonly observed (200) or (400) preferential orientations in ITO thin films, the approximately 3.3 μm thick coatings display a (622) preferential orientation. The ITO coatings exhibit a purely nanocrystalline structure and show good electrical and optical properties, such as an electrical resistivity of 1.3 × 10−1 Ω·cm, optical transmittance at 550 nm of ~60% and optical band gap of 2.9 eV. The initial results presented here are expected to provide useful information for future studies on the synthesis of high-quality thick ITO coatings.

scholarly journals Theoretical Uniformity Analysis and Improvement of Spray Deposition by Mixing Nozzles with Heating Conditions

Coatings ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 81
Author(s):  
Xuran Dong ◽  
Xiaolong Pan ◽  
Xianxian Gao ◽  
Haisheng Fang
Keyword(s):  
High Speed ◽  
Heating Temperature ◽  
Spray Deposition ◽  
Low Cost ◽  
Spray Coating ◽  
Deposition Process ◽  
Test Method ◽  
Large Area ◽  
Orthogonal Test Method ◽  
Experimental Trials

Spray coating is widely used in the manufacture of deposited layers of electronic devices due to its unique advantages of high-speed deposition over a large area. To improve the spray deposition process for further low-cost and uniform production, the uniformity of the spray deposition should be systematically investigated. The current study, however, mainly focuses on the experimental trials with few numerical directions especially for the mixing nozzle sprayers with heating conditions. In the paper, we conduct a theoretical study on the uniformity of the internal and external mixing nozzles. The influencing factors include the initial angle, the total ink flow rate, the transporting gas velocity and the distance from the nozzle to the substrate. Then, the orthogonal test method is adopted to obtain the optimal combination of the parameters. Finally, the effects of different heating modes on the uniformity have been further studied. The results show that these factors influence the uniformity with the two types of nozzles to a different degree. The evaporation of the atomized droplets can effectively improve the uniformity in a certain temperature range. The heating temperature with the highest uniformity is various depending on the heating modes, which should be carefully addressed during the actual production.

Flexible and Transparent SWCNT Electrodes for Alternating Current Electroluminescence (ACEL) Devices

2009 ◽  
Vol 1204 ◽  
Author(s):  
Christian Schrage ◽  
Stefan Kaskel
Keyword(s):  
Thin Film ◽  
Carbon Nanotube ◽  
Sheet Resistance ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Emission Intensity ◽  
Spray Coating ◽  
Alternating Current ◽  
Coating Process ◽  
Single Walled Carbon Nanotube

AbstractThe application of transparent single-walled carbon nanotube (SWCNT) electrodes in rigid and flexible alternating current electroluminescence (ACEL) devices is demonstrated. SWCNT thin film electrodes (50 – 160 nm) were made using a spray-coating process suitable for adjusting transparency and sheet resistance. The emission intensity was as high as for indium tin oxide (ITO) based ACEL devices with transparencies comparable to ITO coated polymer slides.

Electrical and Optical Properties of Indium Tin Zirconium Oxide Films at Different Annealing Treatment Temperatures

2012 ◽  
Vol 189 ◽  
pp. 110-114
Author(s):  
Jian Guo Chai ◽  
Bo Zhang
Keyword(s):  
Optical Properties ◽  
Electrical Properties ◽  
Indium Tin Oxide ◽  
Zirconium Oxide ◽  
Room Temperature ◽  
Annealing Treatment ◽  
Optical Transmittance ◽  
Electrical And Optical Properties ◽  
Glass Substrates ◽  
Lower Annealing Temperature

Indium tin oxide (ITO) and indium tin zirconium oxide (ITZO) films were deposited on glass substrates at room temperature by magnetron sputtering technology with one or two targets. Electrical and optical properties of ITO and ITZO films by air-annealing treatment were contrastively studied. ITZO films provided with the preferential crystalline orientation change from (222) to (400) plane, as well as the increase in grain size and the decrease in surface roughness. As result, zirconium -doping remarkably improved the optical-electrical properties of the films deposited at room temperature. The resistivity of ITO and ITZO films showed the trend which includes first dropping and then rising, which was closely related with the variations of carrier concentration and mobility. ITZO films had high optical transmittance of above 80% at lower annealing temperature. ITZO films prepared by co-sputtering reveal better optical-electrical properties.

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