Optimization study on wet electrostatic powder coating process to manufacture UHMWPE/LDPE towpregs

In the present study, an attempt has been made to coat the non-conductive Ultra-high Molecular Weight Polyethylene (UHMWPE) fibers with Low-Density Polyethylene (LDPE) powder. In order to enable the deposition of electrostatically charged LDPE powder onto the fiber surface, UHMWPE fibers are dipped into a surface modification bath to impart momentary conductivity. Further, Box Behnken’s experimental design is used to optimize the processing parameters for Fiber Volume Fraction (Vf) for this wet electrostatic spray coating process. An experimental multi-parametric equation is acquired through response surface methodology to ascertain the association amid the process parameters such as processing temperature (A), conveying air pressure (B), and gun nozzle angle (C) on the output response of Vf. The process parametric values for A, B, and C are varied from 225°C to 245°C, 0.2 bar to 0.4 bar, and 0° to 120° respectively. The Vf obtained is in the range of 37.02%–56.28% depending on the combination of process parametric values. Powder pick-up increases with an increase in the gun nozzle angle. An increase in conveying air pressure and temperature of the hot air oven leads to an increase in powder deposition. The values predicted from the model are observed to be in close proximity (94.59%) to the experimental results. Gun nozzle angle is the principal parameter affecting the matrix deposition on the fiber surface in comparison to other process parameters.

Effect of Polyurethane Non-Transparent Coating Process on Paint Film Performance Applied on Modified Poplar

Whether modified poplar can obtain a qualified or even excellent finishing effect on European and American furniture is worthy of deep study. To evaluate whether the conventional non-transparent coating process is suitable for modified poplar, a multi-level hybrid orthogonal experiment method was carried out to start research on how factors affect the paint film performance of the non-transparent coating process. The effect of experimental factors and levels on paint film performance is pointed out, and the optimal factors and levels are found. Parameter optimization of the polyurethane non-transparent finishing process based on modified poplar is carried out. An application basis was provided for the extensive use of modified poplar wood as a substrate in the European and American furniture markets. The conclusions are: (1) gloss of paint film can be improved by increasing the number of nitrocellulose (NC) lacquer transparent topcoats, (2) adhesion and thickness of paint film can be improved by polyurethane (PU) sealing primer, (3) the initial paint film’s abrasion is influenced efficiently by the coating process and coating sanding. PU sealing primer has an efficient influence on the later abrasion of paint film. The effect of modified poplar surface pretreatment on the mass loss of paint film tends to be stable.

Application of Surfactant Material as Anti-hygroscopicity agent for Ammonium Nitrate (NH4NO3)

Ammonium nitrate is a promising rocket propellant oxidizer. It is present as the major component in most industrial explosives. Due to the surface polarity of ammonium nitrate, the particles can easy absorb moisture. In this study, ammonium nitrate particles were coated by cetylalcohol surfactant in order to reduce the hygroscopicity. The optimized physical coating process using cetylalcohol was achieved by (L9 (34 )) Taguchi orthogonal array (TOA).The analysis of TOA revealed that the highest decline of absorption rate was 35.45% with the mass ratio of coating layer was 0.95%. Scanning electron microscopy (SEM) was used to characterize the surface of coated and uncoated ammonium nitrate. The idea and approach presented in this study can help the researchers to improving anti-hygroscopicity of ammonium nitrate.

Fabrication of Polycrystalline Cubic Boron Nitride/Metal Composite Particles by Surface Metallization Followed by Electroless Deposition Technique

Polycrystalline cBN/copper composite abrasive particles were prepared by an electroless powder coating process. Ti metallization and tin/silver metallization techniques were used to improve the coating process by depositing an autocatalytic metallic layer on the surface of the cBN particles. Metallized, as well as un-metallized, cBN particles were further coated by copper using electroless deposition. Electroless copper coating of un-metallized and metallized cBN particles by 90 wt.% of copper were achieved. The surface morphology, the composition and the crystalline phase identifications of the metallized cBN particles, as well as the 10 wt.% cBN /copper composite powders, were investigated by field emission scanning electron microscopy, an energy-dispersive spectrometer and an X-ray diffractometer. The results show that the surface of the Ti metalized and tin/Ag-metallized cBN particles were covered by the nanosized Ti or Ag layer, respectively, which enhanced the deposition of the copper during the electroless deposition bath. The results also showed that the deposited layer on the metallized cBN particles was composed mainly of metallic copper. The produced 10 wt.% cBN/copper composite particles also underwent thermo-gravimetric analysis to investigate its stability at high temperature. It was revealed that the Ti-metallized cBN/copper composite powder has higher stability at 800 °C under the environmental conditions than the tin/silver-metallized and the un-metallized cBN/copper composite particles, respectively.

Effect of Coating Process on Mechanical, Optical, and Self-Healing Properties of Waterborne Coating on Basswood Surface with MF-Coated Shellac Core Microcapsule

Self-repairing microcapsules prepared with melamine formaldehyde (MF) resin as wall material and shellac and waterborne coating as core material were added to waterborne coating to prepare a self-repairing coating. In order to explore the effect of the coating process on the performance of the waterborne coating on the basswood surface with microcapsules, the number of coating layers of primer and finish and the addition mode of the microcapsules were tested as influencing factors. The effects of different coating processes on the optical, mechanical, and liquid resistance of the basswood surface coating were investigated. The results showed that different coating processes had little effect on the color difference of the coating. When the coating process was two layers of primer and three layers of finish, and microcapsules were added to the finish, the minimum gloss of the basswood surface coating at 60° incident angle was 10.2%, and the best mechanical properties, liquid resistance, and comprehensive properties were achieved. Finally, the aging resistance and self-healing performance of the waterborne coating on the basswood surface prepared by this coating process were explored. The results showed that the waterborne coating had a certain repair effect on scratch damage. This paper lays a theoretical foundation for the practical application of self-healing microcapsules in wood-surface waterborne coatings.