Optical Method of Detection of Oil Contamination on Water Surface in UV Spectral Range

2019 ◽  
pp. 88-96
Author(s):  
Michael L. Belov ◽  
Yulia I. Vsyakova ◽  
Victor A. Gorodnichev

Efficiency analysis of optical (photo and radiometric) method of oil contamination detection based on differences between reflective characteristics of clean and oil-contaminated water surfaces was conducted with sounding wave selection in UV, visible, near-infrared and medium-infrared regions of the spectrum. It is shown that, in terms of eye safety, width of thickness interval of detected oil films and atmospheric attenuation, the most promising type of sounding for monitoring of oil contamination is UV sounding at a wavelength of 0.355 µm, which allowing to detect oil films with thickness of at least 2 µm reliably with probability of correct detection exceeding 0.9 and probability of false alarms of 0.002 with relative measurement noise not exceeding 5 %.

Marine Drugs ◽  
2021 ◽  
Vol 19 (6) ◽  
pp. 325
Author(s):  
Bertalan Juhasz ◽  
Dawrin Pech-Puch ◽  
Jioji N. Tabudravu ◽  
Bastien Cautain ◽  
Fernando Reyes ◽  
...  

Three dermacozines, dermacozines N–P (1–3), were isolated from the piezotolerant Actinomycete strain Dermacoccus abyssi MT 1.1T, which was isolated from a Mariana Trench sediment in 2006. Herein, we report the elucidation of their structures using a combination of 1D/2D NMR, LC-HRESI-MSn, UV–Visible, and IR spectroscopy. Further confirmation of the structures was achieved through the analysis of data from density functional theory (DFT)–UV–Visible spectral calculations and statistical analysis such as two tailed t-test, linear regression-, and multiple linear regression analysis applied to either solely experimental or to experimental and calculated 13C-NMR chemical shift data. Dermacozine N (1) bears a novel linear pentacyclic phenoxazine framework that has never been reported as a natural product. Dermacozine O (2) is a constitutional isomer of the known dermacozine F while dermacozine P (3) is 8-benzoyl-6-carbamoylphenazine-1-carboxylic acid. Dermacozine N (1) is unique among phenoxazines due to its near infrared (NIR) absorption maxima, which would make this compound an excellent candidate for research in biosensing chemistry, photodynamic therapy (PDT), opto-electronic applications, and metabolic mapping at the cellular level. Furthermore, dermacozine N (1) possesses weak cytotoxic activity against melanoma (A2058) and hepatocellular carcinoma cells (HepG2) with IC50 values of 51 and 38 μM, respectively.


2017 ◽  
Vol 231 (11-12) ◽  
Author(s):  
Tianlin Cao ◽  
Fanyu Zhao ◽  
Zulin Da ◽  
Fengxian Qiu ◽  
Dongya Yang ◽  
...  

AbstractIn this work, an amino-functionalized graphene oxide (AFGO) was synthesized by graphene oxide (GO) and ethylene diamine. A novel amino-functionalized graphene oxide/azobenzene polyimide (AFGO/ACPI) was synthesized with AFGO, azobenzene chromophore and pyromellitic dianhydride (PMDA). The structure, mechanical and thermal property of AFGO/ACPI were characterized and measured by fourier transform infrared, UV-visible spectroscopy, near-infrared spectrum, thermogravimetric analysis and differential scanning calorimetry. To obtain the refractive index of AFGO/ACPI at different temperature and wavelength (532 nm, 650 nm and 850 nm), the attenuated total reflection (ATR) method was used to measure, and thermo optic coefficients (dn/dT) were −7.22×10


2020 ◽  
Vol 34 (14) ◽  
pp. 2050148
Author(s):  
Wei Wang ◽  
Zhaofeng Bai ◽  
Xiaoping Xie ◽  
Haiping Mei ◽  
Wei Zhao

It is hard to achieve low bit error rate (BER) and high-quality signals in free-space optical (FSO) communication systems due to atmospheric link interference. For the sake of seeking solutions, we proposed an experimental scheme of free-space laser communication based on middle-wave infrared (MWIR) and near infrared (NIR) for obtaining atmospheric transmission characteristic in 1 km turbulence path. Compared with NIR waveband, MWIR-based scheme is more suitable for atmospheric FSO communication since it owns higher anti-interference ability for atmospheric attenuation, turbulence and skylight background noise. The experimental results may offer a significant reference for FSO communication in atmosphere link.


2012 ◽  
Vol 18 (6) ◽  
pp. 1239-1245 ◽  
Author(s):  
C.M. MacRae ◽  
N.C. Wilson ◽  
A. Torpy ◽  
C.J. Davidson

AbstractThe measurement of near-infrared (NIR) cathodoluminescence (CL) with sufficient sensitivity to allow full spectral mapping has been investigated through the application of optimized grating spectrometers that allow the ultraviolet (UV), visible, and NIR CL spectra to be measured simultaneously. Two optical spectrometers have been integrated into an electron microprobe, allowing simultaneous collection of hyperspectral CL (UV-NIR), characteristic X-rays, and electron signals. Combined hyperspectral CL spectra collected from two natural apatite (Ca5[PO4]3[OH,F]) samples from Wilberforce (Ontario, Canada) and Durango (Mexico) were qualitatively analyzed to identify the emission centers and then deconvoluted pixel-by-pixel using least-squares fitting to produce a series of ion-resolved CL intensity maps. Preliminary investigation of apatite has shown strong NIR emissions associated primarily with the rare-earth element Nd. Details of growth and alteration were revealed in the NIR that were not discernable with electron-induced X-ray mapping. Intense emission centers from Nd3+ and Sm3+ were observed in the spectra from both apatites, along with minor emissions from other 3+ rare-earth elements. Quantitative electron probe microanalysis was performed on points within the mapped area of the Durango apatite to produce a calibration line relating cathodoluminescent intensity of the fitted peak centered at 1,073 nm (1.156 eV) to the Nd concentration.


Author(s):  
A. A. Ionin ◽  
D. V. Mokrousova ◽  
L. V. Seleznev ◽  
D. V. Sinitsyn ◽  
E. S. Sunchugasheva
Keyword(s):  

Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 2054
Author(s):  
Hongsub Jee ◽  
Guanying Chen ◽  
Paras N. Prasad ◽  
Tymish Y. Ohulchanskyy ◽  
Jaehyeong Lee

In this paper, we report an approach to polymerization of a nanocomposite containing UV-polymerizable organic material and inorganic, NaYbF4:Tm3+ core-based nanoparticles (NPs), which are optimized for upconversion of near infrared (NIR) to ultraviolet (UV) and blue light. Our approach is compatible with numerous existing UV-polymerizable compositions and the NaYF4: Yb, Tm3+ core-based NPs are much more stable against harsh conditions than NIR organic photo-initiators proposed earlier. The use of a core-shell design for the NPs can provide a suitable method for binding with organic constituents of the nanocomposite, while maintaining efficient NIR-to-UV/blue conversion in the NaYbF4 core. The prepared photopolymerized transparent polymer nanocomposites display upconversion photoluminescence in UV, visible and NIR ranges. We also demonstrate a successful fabrication of polymerized nanocomposite structure with millimeter/submillimeter size uniformly patterned by 980 nm irradiation of inexpensive laser diode through a photomask.


2019 ◽  
Vol 210 ◽  
pp. 189-201 ◽  
Author(s):  
Jianxu Hu ◽  
Yuanpeng Zhang ◽  
Bin Lu ◽  
Haiping Xia ◽  
Huanqing Ye ◽  
...  

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