scholarly journals Arsenate and arsenite adsorption in relation with chemical properties of alluvial and loess soils

2017 ◽  
Vol 82 (7-8) ◽  
pp. 943-954 ◽  
Author(s):  
Shah Rukh ◽  
Saleem Akhtar ◽  
Ayaz Mehmood ◽  
Sayed Hassan ◽  
Khalid Khan ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Chemical Properties ◽  
Parent Material ◽  
Alluvial Soils ◽  
Arsenic Adsorption ◽  
Adsorption Parameters ◽  
Sorption Data ◽  
Parent Materials ◽  
Freundlich Isotherms ◽  
Loess Soils

Arsenic is one of the most toxic elements in the soil environment. Understanding of the arsenic adsorption chemistry is essential for evolving the extent of soil and groundwater contaminations. This research was conducted to determine the variation in adsorption behaviour of arsenite and arsenate with depth in different lithology soils. We sampled two parent materials at genetic horizons, and within a parent material, we selected two soils. Besides basic soil characterizations, a laboratory batch experiments were carried out to study the adsorption of arsenate and arsenite. Freundlich adsorption approaches were employed to investigate the adsorption of arsenate and arsenite in the soils. Freundlich isotherms fit arsenate and arsenite sorption data well with r2 values of 0.88?0.98 in most soils. Arsenate and arsenite adsorption varied with the soil properties, especially in clay composition and in the oxides of iron and aluminum. Arsenic adsorption parameters also varied with depth in parent materials, and loess derived soils had greater adsorption capacity as compared to alluvial soils in most of the adsorption parameters. This research concludes that the loess soils had higher arsenic adsorption capacity than the alluvial soils.

scholarly journals Soil diversity and properties in mountainous subtropical areas, in Sierra Sur de Oaxaca, Mexico

2006 ◽  
Vol 86 (1) ◽  
pp. 61-76 ◽  
Author(s):  
N. E. García Calderón ◽  
A. Ibáñez Huerta ◽  
G. Alvarez Arteaga ◽  
P. V. Krasilnikov ◽  
A. Hernández Jiménez
Keyword(s):  
Mass Movement ◽  
Clay Fraction ◽  
Chemical Properties ◽  
Mineralogical Composition ◽  
Parent Material ◽  
Soil Types ◽  
Soil Diversity ◽  
Parent Materials ◽  
Soil Groups ◽  
And Chemical Properties

Agroforestry is a new practice of sustainable soil use in the mountainous Sierra Sur de Oaxaca area of Mexico. Coffee is also a common cash crop grown in the region. The objective of this study was to investigate the pedodiversity in the area. Soil development is very complex, and is influenced by slope parameters and parent materials. Several soil groups are found in the area investigated: Alisols, Umbrisols, and Cambisols. Morphology, chemical properties, and mineralogical composition of the clay fraction of these soils were studied. The soils vary in the extent of weathering, morphology, and chemical properties, which are important to farming in the area. Most of the soils have heterogeneous parent material. The distribution of major soil types of the area is related to mass movement along the slopes, both past and present. The studied soils represent a chronosequence from unleached and unweathered Cambisols to Alisols, characterized by strong clay illuviation and dominance of kaolinite and gibbsite in clay fraction. A mosaic of landslides and gullies of various ages, formed by catastrophic events such as earthquakes and hurricanes, form the pedodiversity of the area studied. Key words: Landslides, chronosequence, pedodiversity, Cambisols, Umbrisols, Alisols

scholarly journals Effects of geological formations and topography on the evolution and diversity of soils

2020 ◽  
Vol 33 (02) ◽  
pp. 476-789
Author(s):  
Hengameh Javadi ◽  
Reza Sokouti ◽  
Ebrahim Pazira ◽  
Mohammad Hassan Massihabbadi
Keyword(s):  
Chemical Properties ◽  
Soil Formation ◽  
Diversity Indices ◽  
Parent Material ◽  
Moisture Regime ◽  
Soil Diversity ◽  
Parent Materials ◽  
Family Level ◽  
The Relationship ◽  
Geological Formations

Different soils with various properties and sometimes with different types of limitations can be formed which is necessary to investigate the conditions of soil formation and evolution for their optimal use. In this study, we studied the relationship between soil, topography in terms of slope and elevation, and parent material with the land morphology and physical and chemical properties of soil, how the soil formed and evolved. From 19 control soil profiles, 57 soil samples were obtained from three layers and some soil characteristics including Acidity, Salinity, Gypsum, Lime, Texture and Organic matter were measured. Using NEWHALL software, the soil temperature and moisture regime was determined. To study the conditions of topography, the digital elevation map and slope was prepared, the characteristics of geological formations were determined and based on the Gower index and Jacquard index, the relationship between soil evolution factors with topography and parent materials were studied. The diversity of soils classification was studied using richness, uniformity of Shannon and Simpson indices. Based on the results obtained from Gower and jacquard similarity indices, the effect of topography and parent materials on soil diversity was proved. Soil diversity indices showed an increasing trend from the soil order level to the soil family. The increase in the Richness index was higher at the soil family level, so that the highest soil diversity observed at the soil family level. Also, soil diversity is mainly affected by intrinsic factors and to some extent by environmental factors. Soil profile development is mostly influenced by slope, parent materials and in some areas by groundwater level.

Adsorption of Cadmium(II) Ion from Aqueous Solution onto a Raw Material of Bamboo Powder and its Surface Modification

2018 ◽  
Vol 879 ◽  
pp. 131-136 ◽  
Author(s):  
Woravith Chansuvarn ◽  
Yuttapoom Pandee ◽  
Ariya Saechim ◽  
Kritsana Habunmee
Keyword(s):  
Adsorption Capacity ◽  
Low Cost ◽  
Freundlich Isotherm ◽  
Raw Material ◽  
Wastewater Sample ◽  
Adsorption Parameters ◽  
Freundlich Isotherms ◽  
Monolayer Adsorption ◽  
Adsorptive Behavior ◽  
Bamboo Powder

This work was focused on evaluating the potential of bamboo powder modified with manganese oxide (MnO-BP) as a low-cost byproduct adsorbent for the adsorption of cadmium(II) ion. A batch method was carried out at room temperature and the optimized conditions. The optimization of adsorption parameters including pH, equilibrium time, dosage and initial Cd(II) concentration was also systematically studied for the removal of cadmium(II) ion. The maximum monolayer adsorption capacity of MnO-BP was estimated as 8.57 mg/g that it more adsorption capacity than untreated-bamboo powder by about 5 times. The Langmuir and the Freundlich isotherms were used to describe the adsorptive mechanism and calculated the maximum monolayer adsorption capacity. It was found that the data from MnO-BP fitted well to the Freundlich isotherm with R2>0.99. It indicated that the adsorptive behavior of MnO-BP to cadmium(II) ion is preferable. In this work, MnO-BP was used for the removal of cadmium(II) ion in wastewater sample. The MnO-BP is a low-cost adsorbent that can be used to remove cadmium(II) effectively.

scholarly journals Morphology and Composition of Two Late Wisconsinan Soils Forming in Till and Lacustrine Deposits, Scarborough Bluffs Area, South-Central Ontario

2007 ◽  
Vol 39 (3) ◽  
pp. 307-314 ◽  
Author(s):  
William C. Mahaney
Keyword(s):  
Chemical Properties ◽  
Parent Material ◽  
Mineral Contents ◽  
Parent Materials ◽  
Lacustrine Deposits ◽  
South Central ◽  
Primary Mineral ◽  
Physical Attributes ◽  
Late Wisconsinan ◽  
Sand And Gravel

ABSTRACT Halton Till and Glacial Lake Iroquois lacustrine sand and gravel deposits are the major surficial materials exposed at the surface of Scarborough Bluffs in South-Central Ontario. Luvisols formed in these deposits have different morphologies, including depth of weathering, complexity of horizonation, and strength of structural grades which result from parent material differences and pedogenesis. Particle size variations between the two paleosols result, in part, from different modes of deposition, and show that variable amounts of clay were produced pedogenically in the two systems. Clay mineral genesis, involving the transformation of illite and illitesmectite to vermiculite, appears to be restricted to the Iroquois sand paleosol, while some chloritization of illite occurs in both profiles. Changes in the primary mineral contents in the two paleosols suggest a similar magnitude of weathering in both systems. Distributions of vermiculite and dithionite-extractable Fe suggest some preweathering effects in the Halton Till paleosol. Morphological, mineralogical and some soil chemical properties are closely related to the physical attributes of the two different parent materials (till vs lacustrine sand and gravel).

Adsorption-desorption behavior of selected pesticides in some Western Australian soils

Soil Research ◽  
1990 ◽  
Vol 28 (2) ◽  
pp. 227 ◽  
Author(s):  
R Singh ◽  
RG Gerritse ◽  
LAG Aylmore
Keyword(s):  
Organic Matter ◽  
Chemical Properties ◽  
Type Equation ◽  
Dilution Method ◽  
Sorption Data ◽  
Freundlich Isotherms ◽  
Physico Chemical ◽  
Pesticide Adsorption ◽  
Adsorption Desorption ◽  
Western Australian

The adsorption-desorption behaviour of four pesticides, in four Western Australian soils differing in their physico-chemical properties, has been studied using a batch technique. Sorption data for Fenamiphos, Linuron and Simazine could be fitted to a Freundlich-type equation, while that for Diquat more closely fitted the Langmuir equation. The value of the exponent in the fitted Freundlich isotherms varied from 0.70 to 1.00 for the various pesticide and soil combinations. Adsorption was found to be better correlated with organic matter than other soil properties, and decreased with increasing pH for all pesticides except Diquat. This study supports the observation of B. T. Bowman that the Freundlich equation in mole fraction form is more useful for comparing relative adsorption. Comparison of the present adsorption data with previous studies showed that the organic matter in these soils behaved differently in terms of pesticide adsorption. In particular, the octanol-water partition approach, for predicting the adsorption of non-ionic organic compounds, gave unsatisfactory predictions of Linuron and Fenamiphos adsorption in these soils. Desorption by a consecutive method showed hysteresis with all pesticide-soil combinations examined. The magnitude of the hysteresis was unaffected by changes in the soil : solution ratio. Using a dilution method, experimental procedures such as centrifugation and shaking have been shown to only slightly affect desorption hysteresis. The suggestion that hysteresis results from organic matter effectively 'locking in' the adsorbed pesticides is supported. The presence of methanol in the desorption solution results in swelling of organic polymers and facilitates the release of the adsorbed pesticides. Consequently, hysteresis was found to be essentially absent from the Linuron isotherm on removal of organic matter from the soil.

Contributions to the Knowledge of Sandy Soils from Oltenia Plain

2020 ◽  
Vol 71 (1) ◽  
pp. 192-200
Author(s):  
Anca-Luiza Stanila ◽  
Catalin Cristian Simota ◽  
Mihail Dumitru
Keyword(s):  
Chemical Properties ◽  
Soil Formation ◽  
Sandy Soils ◽  
Physical Geography ◽  
Parent Material ◽  
Negative Effects ◽  
Small Water ◽  
Wind Characteristic ◽  
The One ◽  
Physical And Chemical

Highlighting the sandy soil of Oltenia Plain calls for a better knowledge of their variability their correlation with major natural factors from each physical geography. Pedogenetic processes specific sandy soils are strongly influenced by nature parent material. This leads, on the one hand, climate aridity of the soil due to strong heating and accumulation of small water reserves, consequences emphasizing the moisture deficit in the development of the vegetation and favoring weak deflation, and on the other hand, an increase in mineralization organic matter. Relief under wind characteristic sandy land, soil formation and distribution has some particularly of flat land with the land formed on the loess. The dune ridges are less evolved soils, profile underdeveloped and poorly supplied with nutrients compared to those on the slopes of the dunes and the interdune, whose physical and chemical properties are more favorable to plant growth.Both Romanati Plain and the Blahnita (Mehedinti) Plain and Bailesti Plain, sand wind shaped covering a finer material, loamy sand and even loess (containing up to 26% clay), also rippled with negative effects in terms of overall drainage. Depending on the pedogenetic physical and geographical factors that have contributed to soil cover, in the researched were identified following classes of soils: protisols, cernisols, cambisols, luvisols, hidrisols and antrosols.Obtaining appropriate agricultural production requires some land improvement works (especially fitting for irrigation) and agropedoameliorative works. Particular attention should be paid to preventing and combating wind erosion.

TiO2-pillared magadiite and its arsenic adsorption capacity

2019 ◽  
Vol 26 (1) ◽  
pp. 311-318
Author(s):  
Sarah Louise S. Atulba ◽  
Jeong Hun Jang ◽  
Man Park
Keyword(s):  
Adsorption Capacity ◽  
Arsenic Adsorption

scholarly journals Preparation and Characterization of Cationized Cellulose for the Removal of Anionic Dyes

2001 ◽  
Vol 19 (3) ◽  
pp. 197-210 ◽  
Author(s):  
A. Hashem ◽  
Reda M. El-Shishtawy
Keyword(s):  
Adsorption Capacity ◽  
Freundlich Isotherm ◽  
Structural Features ◽  
Isotherm Models ◽  
Acid Orange 7 ◽  
Anionic Dyes ◽  
Adsorption Parameters ◽  
Direct Blue ◽  
Equilibrium Data

The factors influencing the cationization of microcrystalline cellulose with 3-chloro-2-hydroxypropyl triethylammonium chloride in the presence of NaOH were investigated. The course of the reaction was followed by estimating the nitrogen content of the cationized product while its structural features were confirmed by IR analysis. The ability of cationized cellulose to adsorb anionic dyes, viz. Acid Orange 7, Direct Blue 75 and Direct Violet 31, was investigated at 25°C and 50°C. The equilibrium data obtained were fitted by the Langmuir and Freundlich isotherm models, allowing the corresponding adsorption parameters to be determined. The results showed that the adsorption capacity was dependent on the adsorbent, temperature, the nature of the dye and (to some extent) on van der Waals and hydrogen bonding. Cationized cellulose exhibited a much better adsorption capacity towards anionic dyes than cellulose.

scholarly journals Experimental and Modeling of Dicamba Adsorption in Aqueous Medium Using MIL-101(Cr) Metal-Organic Framework

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 419
Author(s):  
Hamza Ahmad Isiyaka ◽  
Khairulazhar Jumbri ◽  
Nonni Soraya Sambudi ◽  
Jun Wei Lim ◽  
Bahruddin Saad ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Adsorption Capacity ◽  
Environmental Concern ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Data Matrix ◽  
Adsorption Parameters ◽  
Metal Organic ◽  
Organic Framework

Drift deposition of emerging and carcinogenic contaminant dicamba (3,6-dichloro-2-methoxy benzoic acid) has become a major health and environmental concern. Effective removal of dicamba in aqueous medium becomes imperative. This study investigates the adsorption of a promising adsorbent, MIL-101(Cr) metal-organic framework (MOF), for the removal of dicamba in aqueous solution. The adsorbent was hydrothermally synthesized and characterized using N2 adsorption-desorption isotherms, Brunauer, Emmett and Teller (BET), powdered X-ray diffraction (XRD), Fourier Transformed Infrared (FTIR) and field emission scanning electron microscopy (FESEM). Adsorption models such as kinetics, isotherms and thermodynamics were studied to understand details of the adsorption process. The significance and optimization of the data matrix, as well as the multivariate interaction of the adsorption parameters, were determined using response surface methodology (RSM). RSM and artificial neural network (ANN) were used to predict the adsorption capacity. In each of the experimental adsorption conditions used, the ANN gave a better prediction with minimal error than the RSM model. The MIL-101(Cr) adsorbent was recycled six times to determine the possibility of reuse. The results show that MIL-101(Cr) is a very promising adsorbent, in particular due to the high surface area (1439 m2 g−1), rapid equilibration (~25 min), high adsorption capacity (237.384 mg g−1) and high removal efficiency of 99.432%.

Red soils of different origins from southwest Nigeria: Characteristics, classification, and management considerations

1997 ◽  
Vol 77 (2) ◽  
pp. 295-307 ◽  
Author(s):  
T. A. Okusami ◽  
R. H. Rust ◽  
A. O. Alao
Keyword(s):  
Clay Mineral ◽  
Agricultural Land ◽  
Clay Fraction ◽  
Chemical Properties ◽  
Cropping System ◽  
Clay Content ◽  
Parent Material ◽  
Classification Systems ◽  
Biotite Gneiss ◽  
Variable Charge

Representative profiles of the Owena, Egbeda, Alagba, and Balogun series were studied. The Owena soil is formed in amphibolite whereas Egbeda and Balogun soils are formed in biotite gneiss derived parent materials. The Alagba soil is formed in sandstone parent rock. The main objectives were to characterize the soils and their clay fraction, and to classify and interpret soil properties for agricultural land use. Most soils exhibit 2.5 YR hues in subsurface horizons. A pedon formed in biotite gneiss has the highest dithionite Fe content and Fed/clay ratio. The relationships between clay content and Fed values vary according to parent material origin and, therefore, would have to be interpreted differently for soil weathering processes. Clay coatings were noticeable in some soil horizons of all pedons studied. Soils are generally medium to slightly acid with sandstone-derived soils being the most acid. The clay mineral suite in all soils is dominated by kaolinite with traces of 2:1 and 2:2 clay minerals, goethite, hematite, anatase, maghemite, and rutile. In addition, some soils contain trace amounts of gibbsite. Kandic horizons have been identified in all soils. The low charge properties of the soils reflect the intensely weathered clay mineral suite. The base status is probably influenced by the cropping system and therefore may tend to unnecessarily differentiate highly weathered soils at the order level. The Egbeda and Balogun series were classified as Rhodic Kandiudults, clayey-skeletal, oxidic and Rhodic Kandiudalfs, clayey-skeletal, oxidic, respectively. Others, Owena, and Alagba series, were classified as Typic Kanhaplohumults, clayey, oxidic and Rhodic Kanhaplustults, fine loamy or clayey, oxidic, respectively. In the FAO-Unesco legend, all soils become Rhodic Ferralsols. In addition, the Owena (with its nitic properties) is further classified as niti-rhodic Ferralsol. The two classification systems are at variance for highly weathered (variable charge property) soils and this difference will definitely influence management decisions depending on which system is used at any particular time. Soil attributes favorable for agricultural use include thick sola and favorable structures. Chemical properties suggest minimal fixation of phosphorus. Key words: Dithionite Fe, kandic, oxidic, variable charge, ferralic, exchangeable Al

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