scholarly journals Calcium oxychloride formation in pastes containing supplementary cementitious materials: Thoughts on the role of cement and supplementary cementitious materials reactivity

2016 ◽  
Vol 1 ◽  
pp. 24 ◽  
Author(s):  
Prannoy Suraneni ◽  
Vahid Jafari Azad ◽  
Burkan O. Isgor ◽  
William Jason Weiss
Keyword(s):  
Calcium Hydroxide ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Concrete Pavements ◽  
Scanning Calorimetry ◽  
Supplementary Cementitious Material ◽  
Deicing Salts ◽  
Constituent Material ◽  
Local Saturation

Over the last decade many concrete pavements in North America have begun to show excessive damage at the joints. This damage appears to be due to two primary causes: classic freeze-thaw damage due to local saturation caused by the pooling of water at the joints, and formation of an expansive phase known as calcium oxychloride due to a reaction between chloride-based deicing salts and calcium hydroxide in concrete. This letter explores the formation of calcium oxychloride in cementitious matrices based on constituent materials and mixture compositions. Low temperature differential scanning calorimetry and thermogravimetric analysis were used to quantify the amount of calcium oxychloride and calcium hydroxide, respectively. Thermodynamic modeling was used to predict calcium hydroxide contents from the constituent material compositions. It is shown that calcium oxychloride contents are well correlated with calcium hydroxide contents in cementitious pastes. Supplementary cementitious materials, such as fly ash and slag, can reduce calcium oxychloride formation by reducing the amount of calcium hydroxide. Complexities in the determination of reactivity of supplementary cementitious materials based on their replacement level and different water-to-cement ratios are discussed. Although it is clear that supplementary cementitious materials are beneficial in reducing calcium oxychloride formation, additional analysis tools are needed to more accurately quantify the specific mechanisms (such as dilution, pozzolanic or hydraulic reaction, changes in cement hydration) that result in the beneficial aspects of each supplementary cementitious material.

scholarly journals Calcium oxychloride formation in pastes containing supplementary cementitious materials: Thoughts on the role of cement and supplementary cementitious materials reactivity

2016 ◽  
Vol 1 ◽  
pp. 24 ◽  
Author(s):  
Prannoy Suraneni ◽  
Vahid Jafari Azad ◽  
Burkan O. Isgor ◽  
William Jason Weiss
Keyword(s):  
Calcium Hydroxide ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Concrete Pavements ◽  
Scanning Calorimetry ◽  
Supplementary Cementitious Material ◽  
Deicing Salts ◽  
Constituent Material ◽  
Local Saturation

Over the last decade many concrete pavements in North America have begun to show excessive damage at the joints. This damage appears to be due to two primary causes: classic freeze-thaw damage due to local saturation caused by the pooling of water at the joints, and formation of an expansive phase known as calcium oxychloride due to a reaction between chloride-based deicing salts and calcium hydroxide in concrete. This letter explores the formation of calcium oxychloride in cementitious matrices based on constituent materials and mixture compositions. Low temperature differential scanning calorimetry and thermogravimetric analysis were used to quantify the amount of calcium oxychloride and calcium hydroxide, respectively. Thermodynamic modeling was used to predict calcium hydroxide contents from the constituent material compositions. It is shown that calcium oxychloride contents are well correlated with calcium hydroxide contents in cementitious pastes. Supplementary cementitious materials, such as fly ash and slag, can reduce calcium oxychloride formation by reducing the amount of calcium hydroxide. Complexities in the determination of reactivity of supplementary cementitious materials based on their replacement level and different water-to-cement ratios are discussed. Although it is clear that supplementary cementitious materials are beneficial in reducing calcium oxychloride formation, additional analysis tools are needed to more accurately quantify the specific mechanisms (such as dilution, pozzolanic or hydraulic reaction, changes in cement hydration) that result in the beneficial aspects of each supplementary cementitious material.

Use of Fly Ash to Minimize Deicing Salt Damage in Concrete Pavements

2017 ◽  
Vol 2629 (1) ◽  
pp. 24-32 ◽  
Author(s):  
Prannoy Suraneni ◽  
Vahid J. Azad ◽  
O. Burkan Isgor ◽  
W. Jason Weiss
Keyword(s):  
Fly Ash ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Concrete Pavements ◽  
Scanning Calorimetry ◽  
Deicing Salt ◽  
Performance Specification ◽  
Hydrated Cement Paste ◽  
Deicing Salts ◽  
Damage In Concrete

Premature damage has been observed at the joints in numerous concrete pavements where calcium chloride and magnesium chloride deicing salts have been used. This damage results from a reaction between the deicing salt and the calcium hydroxide (CH) in the hydrated cement paste. This reaction leads to the formation of an expansive product known as calcium oxychloride (CAOXY). The use of supplementary cementitious materials as a replacement for cement has been proposed to reduce the CH that is available in the mixture to react with the deicing salts. Reducing the CH can reduce the amount of CAOXY that forms. In this study, mixtures representative of paving concrete were made with cements and fly ashes from across the country. CH amounts were determined by using thermogravimetric analysis, and CAOXY amounts were determined by using low-temperature differential scanning calorimetry. Various replacement levels of fly ash were used to demonstrate that the main parameter that influences the amounts of CH and CAOXY that form is the replacement level of fly ash. This paper proposes that a prescriptive specification requiring 35% cement replacement by volume with fly ash would reduce the damage caused by CAOXY formation and further proposes a performance specification to limit the CAOXY formation to below 15 g/100 g paste.

scholarly journals Use of Treated Non-Ferrous Metallurgical Slags as Supplementary Cementitious Materials in Cementitious Mixtures

2021 ◽  
Vol 11 (9) ◽  
pp. 4028
Author(s):  
Asghar Gholizadeh Vayghan ◽  
Liesbeth Horckmans ◽  
Ruben Snellings ◽  
Arne Peys ◽  
Priscilla Teck ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
Strength Development ◽  
Supplementary Cementitious Material ◽  
Performance Requirements ◽  
Metallurgical Slags ◽  
Leaching Behaviour ◽  
Kinetics Of

This research investigated the possibility of using metallurgical slags from the copper and lead industries as partial replacement for cement. The studied slags were fayalitic, having a mainly ferro-silicate composition with minor contents of Al2O3 and CaO. The slags were treated at 1200–1300 °C (to reduce the heavy metal content) and then granulated in water to promote the formation of reactive phases. A full hydration study was carried out to assess the kinetics of reactions, the phases formed during hydration, the reactivity of the slags and their strength activity as supplementary cementitious material (SCM). The batch-leaching behaviour of cementitious mixtures incorporating treated slags was also investigated. The results showed that all three slags have satisfactory leaching behaviour and similar performance in terms of reactivity and contribution to the strength development. All slags were found to have mediocre reactivity and contribution to strength, especially at early ages. Nonetheless, they passed the minimum mechanical performance requirements and were found to qualify for use in cement.

Use of Algerian Natural Mineral Deposit as Supplementary Cementitious Materials

2018 ◽  
Vol 34 ◽  
pp. 48-58 ◽  
Author(s):  
Karima Arroudj ◽  
Saida Dorbani ◽  
Mohamed Nadjib Oudjit ◽  
Arezki Tagnit-Hamou
Keyword(s):  
Mechanical Strength ◽  
Calcium Hydroxide ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Pozzolanic Reaction ◽  
Heat Of Hydration ◽  
Cement Industry ◽  
Supplementary Cementitious Materials ◽  
Natural Mineral ◽  
Different Ages

Much of the current research on concrete engineering has been focused on including siliceous additions as supplementary cementitious materials (SCMs). Silica reacts with Calcium hydroxide release during cement hydration, and produces more C-S-H. The latter contributes to increase compactness, mechanical strengths and sustainability of concrete. This paper explores the hydration characteristics of cement paste based on various natural mineral additions, that are very abundant in Algeria and present a high silica content (ground natural pozzolana “PZ” and ground dune sand “DS”). For this purpose, several analyses were carried out on modified cement pastes and mortars. TheseSCMswere introduced by replacement levels of 15, 20 and 25 by weight of cement. We first, studied the effect of these SCMs on the heat of hydration and mechanical strength of mortars at different ages. The evolution of hydration of modified paste was studied, by using Thermal analysis (TG/TDA) at different ages, to analyze the Calcium Hydroxide (CH) content of the modified pastes. It is shown that the CH content of the mixes including SCMs is lower than that of the plain cement paste, indicating that silica reacts with the cement paste through a pozzolanic reaction. Increased pozzolanic activity results in higher amounts of Calcium Silicate Hydrate in the paste, which in turn results in higher compressive strength for modified cement mortars. Due to its crystalline morphology, the ground DS particles present a partial pozzolanic effect, compared to PZ which is semi-crystalline. Modified mortars by 20% DS can be the optimal composition. It presents satisfactory results: good mechanical strength and low heat of hydration. It can lead to an economic and sustainable concrete. Ground DS is very abounded in Africa and free of any impurities and can be a good alternativeSCMsin cement industry.

scholarly journals Reducing Damage Due to Chemical Reactions in Concrete Exposed to Sodium Chloride: Quantification of a Deleterious Chemical Phase Change Formation

2019 ◽  
Vol 271 ◽  
pp. 07004 ◽  
Author(s):  
Fadi Althoey ◽  
Yaghoob Farnam
Keyword(s):  
Fly Ash ◽  
Sodium Chloride ◽  
Phase Change ◽  
Dilution Effect ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Scanning Calorimetry ◽  
Chemical Phase ◽  
Potential Formation ◽  
Negative Effect

It has been shown that sodium chloride can react with the tricalcium aluminate (C3A) and its hydrates, leading to a formation of a deleterious chemical phase change during thermal cycling. It is believed that this chemical phase change is implicated in the premature deterioration of concrete pavements in the cold regions. This work examines the potential formation of the deleterious chemical phase change in several cementitious pastes made using different types of portland cement and supplementary cementitious materials (SCMs). The amount of the chemical phase change was quantified using a low-temperature differential scanning calorimetry. The results indicated that the formation of the chemical phase change can be reduced by using cements with low C3A content. The addition of SCMs showed different effects on the chemical phase change formation. Slag and Class F fly ash could reduce the amount of the chemical phase change due to only the dilution effect whereas silica fume could significantly reduce the amount of the chemical phase change due to the dilution effect as well as pozzolanic reactions. Adversely, the addition of Class C fly ash showed a negative effect through increasing the formation of the chemical phase change.

Improving the Durability of High Early Strength (HES) Concrete Patching Materials for Concrete Pavements

2020 ◽  
Vol 2674 (8) ◽  
pp. 12-23
Author(s):  
Cameron Wilson ◽  
W. Jason Weiss
Keyword(s):  
Cement Content ◽  
Autogenous Shrinkage ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Strength Development ◽  
Concrete Pavements ◽  
Shrinkage Cracking ◽  
Concrete Mixtures ◽  
Water To Cement Ratio ◽  
Early Strength

High early strength (HES) concrete patching materials are increasingly used to repair damaged pavements. The use of HES concrete enables the repaired pavement to be opened to traffic shortly after the repair has been installed; for example, opening pavements to traffic 4–6 h after the concrete is placed is becoming more common. HES concrete mixtures are typically designed with a low water-to-cement ratio and a high cement content; they contain accelerating admixtures and limited supplementary cementitious materials. As a result, these HES patches may be susceptible to self-desiccation, causing autogenous shrinkage and early age cracking. Self-desiccation can lead to reduced hydration, limited strength gain, and overestimation of strength development in maturity-based predictions. The objectives of this study are threefold. First, the paper will illustrate how self-desiccation can lead to the premature cessation of hydration and increased potential for shrinkage cracking. Second, the paper will illustrate how maturity-based predictions can be modified to account for self-desiccation. Third, internal curing is discussed as a way to mitigate self-desiccation and shrinkage ultimately improving the performance of HES concrete patching materials.

scholarly journals The Relationship between Cementitious Composition and Properties of Ultrahigh Strength Concrete

2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Dehui Wang ◽  
Zhiwen Zhang
Keyword(s):  
Fly Ash ◽  
Calcium Hydroxide ◽  
Silica Fume ◽  
Design Method ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Strength Concrete ◽  
Ultrahigh Strength ◽  
Acceleration Period ◽  
The Relationship

It is well known that supplementary cementitious materials (SCMs) have obvious effects on the properties of concrete. In order to understand the relationship between cementitious materials and properties of ultrahigh strength concrete (UHSC), the cementitious compositions of UHSC were designed by the simple-centroid design method. The effects of cementitious compositions on the properties of UHSC were investigated. It was found that the incorporation of silica fume (SF) improved the flowability and strength of UHSC, but it decreased the time of acceleration period, calcium hydroxide (CH) content, and porosity of UHSC at a certain content. The incorporation of fly ash (FA) increased the flowability, time of acceleration period, and porosity of UHSC, but it decreased the strength and CH content of UHSC. The relationships between cement, silica fume, and fly ash and the properties of UHSC were calculated based on the simple-centroid design method.

scholarly journals A Mass Balance Approach for Thermogravimetric Analysis in Pozzolanic Reactivity R3 Test and Effect of Drying Methods

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5859
Author(s):  
Kira Weise ◽  
Neven Ukrainczyk ◽  
Eduardus Koenders
Keyword(s):  
Thermogravimetric Analysis ◽  
Mass Balance ◽  
Calcium Hydroxide ◽  
Cementitious Materials ◽  
Pozzolanic Reaction ◽  
Supplementary Cementitious Materials ◽  
Drying Methods ◽  
Calorimetric Measurement ◽  
Balance Approach ◽  
Mass Balance Approach

The reactivity of supplementary cementitious materials (SCMs) is a key issue in the sustainability of cement-based materials. In this study, the effect of drying with isopropanol and acetone as well as the interpretation of thermogravimetric data on the results of an R3 test for evaluation of the SCM pozzolanic reaction were investigated. R3 samples consisting of calcium hydroxide, potassium hydroxide, potassium sulphate, water, and SCM were prepared. Besides silica fume, three different types of calcined clays were investigated as SCMs. These were a relatively pure metakaolin, a quartz-rich metakaolin, and a mixed calcined clay, where the amount of other types of clays was two times higher than the kaolinite content. Thermogravimetric analysis (TGA) was carried out on seven-day-old samples dried with isopropanol and acetone to stop the reaction processes. Additional calorimetric measurement of the R3 samples was carried out for evaluation of the reaction kinetics. Results show that drying with isopropanol is more suitable for analysis of R3 samples compared to acetone. The use of acetone results in increased carbonation and TGA mass losses until 40 (isothermal drying for 30 min) and 105 °C (ramp heating), indicating that parts of the acetone remain in the sample, causing problems in the interpretation of TGA data. A mass balance approach was proposed to calculate calcium hydroxide consumption from TGA data, while also considering the amount of carbonates in the sample and TGA data corrections of original SCMs. With this approach, an improvement of the linear correlation of TGA results and heat release from calorimetric measurement was achieved.

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