A Mass Balance Approach for Thermogravimetric Analysis in Pozzolanic Reactivity R3 Test and Effect of Drying Methods

The reactivity of supplementary cementitious materials (SCMs) is a key issue in the sustainability of cement-based materials. In this study, the effect of drying with isopropanol and acetone as well as the interpretation of thermogravimetric data on the results of an R3 test for evaluation of the SCM pozzolanic reaction were investigated. R3 samples consisting of calcium hydroxide, potassium hydroxide, potassium sulphate, water, and SCM were prepared. Besides silica fume, three different types of calcined clays were investigated as SCMs. These were a relatively pure metakaolin, a quartz-rich metakaolin, and a mixed calcined clay, where the amount of other types of clays was two times higher than the kaolinite content. Thermogravimetric analysis (TGA) was carried out on seven-day-old samples dried with isopropanol and acetone to stop the reaction processes. Additional calorimetric measurement of the R3 samples was carried out for evaluation of the reaction kinetics. Results show that drying with isopropanol is more suitable for analysis of R3 samples compared to acetone. The use of acetone results in increased carbonation and TGA mass losses until 40 (isothermal drying for 30 min) and 105 °C (ramp heating), indicating that parts of the acetone remain in the sample, causing problems in the interpretation of TGA data. A mass balance approach was proposed to calculate calcium hydroxide consumption from TGA data, while also considering the amount of carbonates in the sample and TGA data corrections of original SCMs. With this approach, an improvement of the linear correlation of TGA results and heat release from calorimetric measurement was achieved.

Calibration of Calorimetric Measurement in a Liquid Argon Time Projection Chamber

The liquid argon time projection chamber provides high-resolution event images and excellent calorimetric resolution for studying neutrino physics and searching for beyond-standard-model physics. In this article, we review the main physics processes that affect detector response, including the electronics and field responses, space charge effects, electron attachment to impurities, diffusion, and recombination. We describe methods to measure those effects, which are used to calibrate the detector response and convert the measured raw analog-to-digital converter (ADC) counts into the original energy deposition.

An Optimized Temperature Sensor Calorimetric Power Device Loss Measurement Method

In the optimized design of power converters, loss analysis of power devices is important. Compared with estimation methods, measuring the power device loss directly in the circuit under test is more accurate. The loss measurement method can be divided into two categories: electrical measurement and calorimetric measurement. The accuracy of the electrical measurement result is restricted to the accuracy of the measurement equipment and parasitic parameters, especially for fast switching devices like SiC devices. The results obtained from calorimetric measurement are more convincing. Based on the measurement principle, calorimetric measurement can be divided into four categories: flow density measurement, temperature equivalent measurement, double jacket measurement, and temperature sensor measurement. This paper proposes an optimized temperature sensor measurement method, which has shorter time consumption, a simpler setup, and lower cost. The principles of the optimized method are described and compared with the traditional ways in detail to show its advantages. The loss measurement and error analysis are carried out in a three-level ANPC (active neutral-point-clamped) topology experiment platform based on the SiC&Si hybrid module to prove the accuracy and practicability of this method.