Hand-pump subsurface arsenic removal: the effect of groundwater conditions and intermittent operation

2013 ◽  
Vol 14 (1) ◽  
pp. 119-126 ◽  
Author(s):  
S. C. Borges Freitas ◽  
D. van Halem ◽  
M. M. Rahman ◽  
J. Q. J. C. Verberk ◽  
A. B. M. Badruzzaman ◽  
...  
Keyword(s):  
Adsorption Process ◽  
Arsenic Removal ◽  
Multiple Injection ◽  
Arsenic Adsorption ◽  
Rural Bangladesh ◽  
Hand Pump ◽  
Oxidized Iron ◽  
Intermittent Operation ◽  
Tube Well ◽  
Provide Drinking Water

Hand-pump subsurface arsenic removal (SAR) has been investigated in rural Bangladesh with different groundwater conditions and intermittent operation modes. Multiple injection-abstraction cycles were performed after injection of 1 m3 of aerated water. From these experiments it can be concluded that hand-pump SAR, in the traditional injection-abstraction design, does not provide drinking water below the WHO arsenic guideline of 10 μg/L. Results show that arsenic removal was not enhanced by: (i) injection of O2-rich water, (ii) higher Fe:As ratios in the groundwater, or by (iii) multiple injection-abstraction cycles, i.e. at location 1, the breakthrough occurred at abstraction-injection ratios of Va/Vi = 2, for cycle 23. It is proposed that dissolved organic carbon (DOC), bicarbonate and phosphate have a significant effect on the arsenic adsorption process. However, iron removal was very efficient and abstraction-injection ratios increased within successive cycles, with Va/Vi > 8 for cycle 23. Furthermore, intermittent operation reduced arsenic concentrations after stop and restart, suggesting insufficient contact time between soluble arsenic and oxidized iron surfaces around the tube well.

As(III) Removal by Dynamic Adsorption onto Amberlite XAD7 Functionalized with Crown Ether and Doped with Fe(III) Ions

2019 ◽  
Vol 70 (7) ◽  
pp. 2330-2334
Author(s):  
Mihaela Ciopec ◽  
Adina Negrea ◽  
Narcis Duteanu ◽  
Corneliu Mircea Davidescu ◽  
Iosif Hulka ◽  
...  
Keyword(s):  
Adsorption Process ◽  
Arsenic Removal ◽  
Arsenic Concentration ◽  
Fixed Bed ◽  
World Health ◽  
Arsenic Content ◽  
Arsenic Adsorption ◽  
Stage Of Development ◽  
Wide Range ◽  
Health Organization

Arsenic content in groundwater�s present a wide range of concentration, ranging from hundreds of micrograms to thousands of micrograms of arsenic per litter, while the maximum permitted arsenic concentration established by World Health Organization (WHO) is 10 mg L-1. According to the WHO all people, regardless of their stage of development and their social economic condition, have the right to have access to adequate drinking water. The most efficient and economic technique used for arsenic removal is represented by adsorption. In order to make this remediation technique more affordable and environmentally friendly is important to new materials with advance adsorbent properties. Novelty of present paper is represented by the usage of a new adsorbent material obtained by physical - chemical modification of Amberlite XAD polymers using crown ethers followed by iron doping, due to well-known affinity of arsenic for iron ions. Present paper aims to test the obtained modified Amberlite polymer for arsenic removal from real groundwater by using adsorption in a fixed bed column, establishing in this way a mechanism for the adsorption process. During experimental work was studied the influence of competing ions from real water into the arsenic adsorption process.

Subsurface iron and arsenic removal: low-cost technology for community-based water supply in Bangladesh

2010 ◽  
Vol 62 (11) ◽  
pp. 2702-2709 ◽  
Author(s):  
D. van Halem ◽  
S. G. J. Heijman ◽  
R. Johnston ◽  
I. M. Huq ◽  
S. K. Ghosh ◽  
...  
Keyword(s):  
Arsenic Removal ◽  
Low Cost ◽  
Iron Hydroxide ◽  
Oxidation Zone ◽  
Small Scale ◽  
Arsenic Adsorption ◽  
Community Based ◽  
Competing Anions ◽  
Tube Well

The principle of subsurface or in situ iron and arsenic removal is that aerated water is periodically injected into an anoxic aquifer through a tube well, displacing groundwater containing Fe(II). An oxidation zone is created around the tube well where Fe(II) is oxidised. The freshly formed iron hydroxide surfaces provide new sorption sites for soluble Fe(II) and arsenic. The system's efficiency is determined based on the ratio between abstracted volume with reduced iron/arsenic concentrations (V) and the injected volume (Vi). In the field study presented in this paper, the small-scale application of this technology was investigated in rural Bangladesh. It was found that at small injection volumes (<1 m3) iron removal was successful and became more effective with every successive cycle. For arsenic, however, the system did not prove to be very effective yet. Arsenic retardation was only limited and breakthrough of 10 μg/L (WHO guideline) was observed before V/Vi=1, which corresponds to arrival of groundwater at the well. Possible explanations for insufficient arsenic adsorption are the short contact times within the oxidation zone, and the presence of competing anions, like phosphate.

Subsurface iron and arsenic removal for shallow tube well drinking water supply in rural Bangladesh

2010 ◽  
Vol 44 (19) ◽  
pp. 5761-5769 ◽  
Author(s):  
D. van Halem ◽  
S. Olivero ◽  
W.W.J.M. de Vet ◽  
J.Q.J.C. Verberk ◽  
G.L. Amy ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Supply ◽  
Arsenic Removal ◽  
Drinking Water Supply ◽  
Rural Bangladesh ◽  
Tube Well

scholarly journals Understanding social acceptability of arsenic-safe technologies in rural Bangladesh: a user-oriented analysis

Water Policy ◽  
2015 ◽  
Vol 18 (2) ◽  
pp. 318-334 ◽  
Author(s):  
Debasish Kumar Kundu ◽  
Aarti Gupta ◽  
Arthur P. J. Mol ◽  
Mahbuba Nasreen
Keyword(s):  
Drinking Water ◽  
Social Acceptance ◽  
Arsenic Removal ◽  
Future Research ◽  
Social Acceptability ◽  
Safe Drinking Water ◽  
Rural Bangladesh ◽  
The Social ◽  
Tube Well ◽  
Dug Well

Contamination of shallow tube well drinking water by naturally occurring arsenic is a severe societal and human health challenge in Bangladesh. Multiple technological interventions seeking to ameliorate the problem face hurdles in securing social acceptance, i.e. the willingness of users to receive and use a technology. While most papers focus on expert understanding of social acceptability, this paper analyzes how users themselves understand the factors shaping the social acceptability of safe drinking water options in rural Bangladesh. We then deploy such understanding to comparatively assess which factors users see as most important in securing social acceptance for three safe drinking water options in rural Bangladesh: the arsenic removal household (Sono) filter; the deep tube well; and an improved dug well. We draw on focus groups and semi-structured interviews with technology users in six villages across three districts to analyze how users assess the social acceptability of specific arsenic-safe technologies. Our findings highlight that factors such as availability, affordability and compatibility with existing water use practices, as understood by users, are key to securing users' acceptance of a specific arsenic-safe option. In concluding, we point to a future research agenda to analyze user-oriented social acceptability of arsenic-safe technologies in developing country contexts.

ARSENIC ADSORPTION FROM WATER USING GRAPHENE-BASED MATERIALS AS ADSORBENTS: A CRITICAL REVIEW

2016 ◽  
Vol 24 (01) ◽  
pp. 1730001 ◽  
Author(s):  
XUETONG YANG ◽  
LING XIA ◽  
SHAOXIAN SONG
Keyword(s):  
Adsorption Capacity ◽  
Adsorption Process ◽  
Arsenic Removal ◽  
Surface Complexation ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Large Specific Surface Area ◽  
Arsenic Adsorption ◽  
Adsorption Mechanisms ◽  
Adsorption Performance

Adsorption is widely applied to remove arsenic from water. This paper reviewed and compared the recent progresses on the arsenic removal by adsorption using two-dimensional and three-dimensional graphene-based materials as adsorbents. Functional graphene sheet achieved the largest As(III) adsorption capacity of 138.79[Formula: see text]mg/g, while Mg-Al LDH/GO2 showed the largest As(V) adsorption capacity of 183.11[Formula: see text]mg/g. Parameters including pH, temperature, co-existing ions and loaded metal or metal oxide affected the adsorption process. The adsorption mechanisms of graphene-based materials for As(III) and As(V) could be explained by surface complexation and the electrostatic attraction, respectively. Future works are suggested to focus on regenerating of two-dimensional graphene-based adsorbents and developing the three-dimensional with large specific surface area and better adsorption performance.

Four years of development and field-testing of IHE arsenic removal family filter in rural Bangladesh

2008 ◽  
Vol 58 (1) ◽  
pp. 53-58 ◽  
Author(s):  
B. Petrusevski ◽  
S. Sharma ◽  
W. G. van der Meer ◽  
F. Kruis ◽  
M. Khan ◽  
...  
Keyword(s):  
Arsenic Removal ◽  
Local Population ◽  
Iron Concentration ◽  
Arsenic Concentration ◽  
Field Testing ◽  
Arsenic Adsorption ◽  
Arsenic Level ◽  
Rural Bangladesh ◽  
Removal Capacity ◽  
Guideline Value

UNESCO-IHE has been developing an arsenic removal family filter with a capacity of 100 L/day based on arsenic adsorption onto iron oxide coated sand, a by-product of iron removal plants. The longer term and field conditions performance of the third generation of eleven family filters prototypes were tested in rural Bangladesh for 30 months. All filters achieved initially highly effective arsenic removal irrespective of arsenic concentration and groundwater composition. Arsenic level in filtrate reached 10 μg/l after 50 days of operation at one testing site and after 18 months of continuous operation at other 3 testing sites. Arsenic level at other 7 sites remained below the WHO guideline value till the end of study. Positive correlation was found between arsenic removal capacity of the filter and iron concentration in groundwater. In addition to arsenic, iron present in groundwater at all testing sites was also removed highly effectively. Manganese removal with IHE family filter was effective only when treating groundwater with low ammonia. A simple polishing sand filter, after IHE family filter, resulted in consistent and effective removal of manganese. IHE family filters were easy to operate and were well accepted by the local population.

scholarly journals Failing arsenic mitigation technology in rural Bangladesh: explaining stagnation in niche formation of the Sono filter

Water Policy ◽  
2016 ◽  
Vol 18 (6) ◽  
pp. 1490-1507 ◽  
Author(s):  
Debasish Kumar Kundu ◽  
Arthur P. J. Mol ◽  
Aarti Gupta
Keyword(s):  
Drinking Water ◽  
Management Approach ◽  
Rural Bangladesh ◽  
Hand Pump ◽  
Radical Innovations ◽  
Explanatory Factors ◽  
Strategic Niche Management ◽  
Niche Formation ◽  
Tube Well

Arsenic contamination of shallow hand pump tube well drinking water in Bangladesh has created opportunities for radical innovations to emerge. One such innovation is the household Sono filter, designed to remove arsenic from water supplies. Applying a strategic niche management approach, and based on interviews, focus groups and a workshop, this article explains the Sono filter's failure to establish itself as a successful niche technology. Three explanatory factors are identified: lack of a strong social network (of technology producers, donors, users, and government actors) around it; diverging expectations regarding its potential to be a long-term solution; and lack of second-order learning amongst key actors. Beyond these three factors that help to explain the lack of successful niche formation, this paper clearly shows that the overwhelming dependency on fund-driven projects also deters successful niche formation in the context of the developing world.

scholarly journals Evaluation of Fe-Mg Binary Oxide for As (III) Adsorption—Synthesis, Characterization and Kinetic Modelling

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 805
Author(s):  
Saif Ullah Khan ◽  
Rumman Zaidi ◽  
Feroz Shaik ◽  
Izharul Haq Farooqi ◽  
Ameer Azam ◽  
...  
Keyword(s):  
Arsenic Removal ◽  
Kinetic Modelling ◽  
Arsenic Concentration ◽  
Experimental Studies ◽  
Precipitation Method ◽  
Arsenic Adsorption ◽  
Adsorbent Dosage ◽  
X Ray ◽  
Co Precipitation ◽  
Contaminated Waters

Nanotechnology has received much attention in treating contaminated waters. In the present study, a facile co-precipitation method was employed to synthesize a novel iron and magnesium based binary metal oxide using a stoichiometrically fixed amount of FeNO3.9H2O and MgNO3.6H2O in a proportion of molar concentration 1:1 and was later evaluated in removing As (III) from contaminated waters. Characterization of the prepared nanomaterial was done using X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy Dispersive X-Ray Analysis (EDAX) and ultraviolet–visible spectrophotometry (UV-VIS). Experimental studies on batch scale were carried out, examining the effect of varying initial concentrations of metal, adsorbent dosage, application time and initial pH on removal efficiency. Arsenic removal increased on increasing adsorbent dosage (0.1–1 g/L) but trend reversed on increasing initial arsenic concentration attaining qmax of 263.20 mg/g. Adsorption was quite efficient in pH range 4–8. Freundlich fitted better for adsorption isotherm along with following Pseudo-2nd order kinetics. The reusability and effect of co-existing ions on arsenic adsorption, namely SO42−, CO32− and PO43− were also explored with reusability in 1st and 2nd cycles attained adsorptive removal up to 77% and 64% respectively. The prepared nano-adsorbent showed promising results in terms of high arsenic uptake (qmax of 263.20 mg/g) along with facile and cost-effective synthesis. Thus, the co-precipitation technique used in this work is a simple one step procedure without any use of any precursor as compared to most of the other procedures used for synthesis.

Reactive transport modeling of subsurface arsenic removal systems in rural Bangladesh

2015 ◽  
Vol 537 ◽  
pp. 277-293 ◽  
Author(s):  
M.M. Rahman ◽  
M. Bakker ◽  
C.H.L. Patty ◽  
Z. Hassan ◽  
W.F.M. Röling ◽  
...  
Keyword(s):  
Reactive Transport ◽  
Arsenic Removal ◽  
Transport Modeling ◽  
Reactive Transport Modeling ◽  
Rural Bangladesh

Pilot-Scale Performance of Iron and Arsenic Removal from Contaminated Groundwater

2005 ◽  
Vol 40 (1) ◽  
pp. 82-90 ◽  
Author(s):  
Biswaranjan Manna ◽  
Uday Chand Ghosh
Keyword(s):  
Arsenic Removal ◽  
Cost Effective ◽  
Pilot Scale ◽  
Cost Evaluation ◽  
Contaminated Groundwater ◽  
Arsenic Content ◽  
Hand Pump ◽  
Excess Iron ◽  
Tube Wells ◽  
Performance Results

Abstract Pilot-scale performance in reducing excess iron and arsenic from contaminated groundwater has been systematically reported. Here, a double column unit, the first packed with β-MnO2 and the second with crystalline FeOOH (goethite variety), with filters attached to the outlet of hand-pump tube-wells has been used in the field. Results showed that the filters generate 10,000 to 15,000 BV and 19,000 to 35,000 BV water with iron ≤ 0.3 mg/L and arsenic ≤10 µg/L from groundwater having influent iron and arsenic levels of 3.75 to 7.25 mg/L and 70 to 220 µg/L, respectively. The downflow rate of effluent water was 237.6 to 305.5 L/m2-min. The performance results were achieved with a single charging of the iron and arsenic removal media. Toxicity characteristic leaching procedure (TCLP) tests of the waste (arsenic content: 2.4 g/kg) showed that it is not hazardous to the environment and does not pose any risk to users. Cost evaluation showed $US0.50 to 0.70 per 1000 gallons of treated water and, hence, the technology is cost-effective for countries such as India and Bangladesh.

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