Nano Composite Polymer Composition for Water Shutoff Treatment at High Formation Temperature

2021 ◽  
Author(s):  
Alekper Baghir Suleymanov ◽  
Akhmed Doletbiyevich Shovgenov

Abstract Excess water production cause serious technical and economic issues including corrosion, loss of productivity, scaling and etc. Various chemical and mechanical methods have been developed to isolate water source in the formation. Among chemical methods polymer-gel treatment is one of the proven solutions in which gel block is placed into high permeable water channel in order to isolate the water source. Most common polymer that is used for water shut-off treatments is Polyacrylamide (PAM) due to its availability and low cost. However in harsh reservoir conditions stability of gel based on PAM is unsatisfactory. Present study focuses on enhancement of bulk gel composition by addition of nano Silica. The effect of nano Silica on gel properties such as gel stability, strength, gelation time, bound/free water content, residual resistance factor was investigated. The results shows that nano Silica addition into bulk gel shortens the gelation time and strengthens the gel. Addition of nano silica significantly reduces syneresis of the gel and nano silica significantly improves the blocking ability of the gel by strengthening the bulk gel and increasing the adsorption. Furthermore, even after aging at 105 °C for 30 days the RRF for the gel with 1% nano silica is still sufficiently high. This observation is explained by syneresis decrement of bulk gel caused by nano Silica.

Author(s):  
K. Nagarajan ◽  
S. Ramya ◽  
T. Thangamani ◽  
A. Selvaperumal ◽  
T. Arthi

The parameters require for maintaining the crop's health and the integrity of the irrigation system has a relation with quality of irrigation water. In Micro irrigation appropriate filtration is very much important to prevent clogging. Filtration unit is one of the main components in micro irrigation system that too, Primary filter is more important to be installed along with the unit, when the water source is from open reservoir and other water sources. Though it is essential, the primary filter is not being installed by the farmers due to its high cost. Hence this study is an attempt to fabricate low-cost filter and to evaluate its performance with different filter media layer. A low-cost primary filter for drip irrigation system is fabricated. Different filter media layer like silex sand (fine silex, coarse silex), pebbles with different sizes are selected. The results revealed that the removal efficiency of filter using silex sand and pebbles were 71% in terms of turbidity, 78% in terms of total suspended solids removal at flow rate of 12 m3 /hr. This fabricated low-cost filter will be cost effective for small farm applications.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000125-000128
Author(s):  
Ruby Ann M. Camenforte ◽  
Jason Colte ◽  
Richard Sumalinog ◽  
Sylvester Sanchez ◽  
Jaimal Williamson

Abstract Overmolded Flip Chip Quad Flat No-lead (FCQFN) is a low cost flip chip on leadframe package where there is no need for underfill, and is compatible with Pb free or high Pb metallurgy. A robust leadframe design, quality solder joint formation and an excellent molding process are three factors needed to assemble a high performance FCQFN. It combines the best of both wirebonded QFN and wafer chip scale devices. For example, wafer chip scale has low resistance, but inadequate thermal performance (due to absence of thermal pad), whereas wirebonded QFN has good thermal performance (i.e., heat dissipated through conductive die attach material, through the pad and to the board) but higher resistance. Flip chip QFN combines both positive aspects – that is: low resistance and good thermals. One of the common defects for molded packages across the semiconductor industry is the occurrence of mold voiding as this can potentially affect the performance of a device. This paper will discuss how mold voiding is mitigated by understanding the mold compound behavior on flip chip QFN packages. Taking for example the turbulent mold flow observed on flip chip QFN causing mold voids. Mold compound material itself has a great contribution to mold voids, hence defining the correct attributes of the mold compound is critical. Altering the mold compound property to decrease the mold compound rheology is a key factor. This dynamic interaction between mold compound and flip chip QFN package configuration is the basis for a series of design of experiments using a full factorial matrix. Key investigation points are establishing balance in mold compound chemistry allowing flow between bump pitch, as well as the mold compound rheology, where gelation time has to be properly computed to allow flow across the leadframe. Understanding the flow-ability of mold compound for FCQFN, the speed of flow was optimized to check on its impact on mold voids. Mold airflow optimization is also needed to help fill in tighter bump spacing but vacuum-on time needs to be optimized as well.


Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 381 ◽  
Author(s):  
Bin Xu ◽  
Huiming Zhang ◽  
He Bian

Delayed crosslinking polymer gel systems are widely utilized in deep profile control processes for water production control in oilfields. In this paper, a kind of delayed crosslinking amphiphilic polymer gel system with adjustable gelation time based on competitive inclusion was prepared and its delayed crosslinking gelling properties were studied. The amphiphilic polymer of P(acrylamide (AM)–sodium acrylate (NaA)–N-dodecylacrylamide (DDAM)) was synthesized and it showed much better salt resistance, temperature resistance, and shear resistance performance compared with hydrolyzed polyacrylamide (HPAM). Phenol can be controlled released from the the cavity of β-cyclodextrin (β-CD) ring in the presence of the hydrophobic group used as the competitive inclusion agent in the amphiphilic polymer backbone. Accordingly, the gelation time of the delayed crosslinking amphiphilic polymer gel system is closely related to release rate of the crosslinker from the the cavity of β-CD ring. This study screened an amphiphilic polymer with good salt resistance and temperature resistance performance, which can be used in high temperature and high salinity reservoirs, and provided a feasible way to control the gelation time of the polymer gel system by the competitive inclusion method.


Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 421 ◽  
Author(s):  
Daouda Ndiaye ◽  
Sébastien Coufourier ◽  
Mbaye Diagne Mbaye ◽  
Sylvain Gaillard ◽  
Jean-Luc Renaud

The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions.


2020 ◽  
Vol 8 (1) ◽  
pp. 149-161 ◽  
Author(s):  
H. K. Tchakouté ◽  
D. E. Tchinda Mabah ◽  
C. Henning Rüscher ◽  
E. Kamseu ◽  
F. Andreola ◽  
...  

2014 ◽  
Vol 70 (6) ◽  
pp. 1065-1073 ◽  
Author(s):  
H. R. Mackey ◽  
Y.-S. Zheng ◽  
W.-T. Tang ◽  
J. Dai ◽  
G.-H. Chen

Freshwater toilet flushing consumes 20–35% of typical household water demand. Seawater toilet flushing, as practised by Hong Kong since 1958, provides an alternative water source. To maximise the benefits of this unique dual water supply, urine separation could be combined to allow low-cost struvite production and subsequent urine nitrification – in-sewer denitrification. This paper reports on a laboratory-scale study of seawater urine phosphate recovery (SUPR) and seawater–urine nitrification. A laboratory-scale SUPR reactor was run under three phases with hydraulic retention time between 1.5 and 6 h, achieving 91–96% phosphorus recovery. A urine nitrification sequencing batch reactor (UNSBR) was also run for a period of over 650 days, averaging 90% ammonia removal and loading of up to 750 mg-N/L.d. Careful control of the SUPR phosphate removal was found necessary for operation of the downstream UNSBR, and system integration considerations are discussed.


2001 ◽  
Vol 44 (2-3) ◽  
pp. 181-188 ◽  
Author(s):  
T. Koottatep ◽  
C. Polprasert ◽  
N. T.K. Oanh ◽  
U. Heinss ◽  
A. Montangero ◽  
...  

Constructed wetlands (CWs) have been proven to be an effective low-cost treatment system, which utilizes the interactions of emergent plants and microorganisms in the removal of pollutants. CWs for wastewater treatment are normally designed and operated in horizontal-flow patterns, namely, free-water surface or subsurface flow, while a vertical-flow operation is normally used to treat sludge or septage having high solid contents. In this study, three pilot-scale CW beds, each with a surface area of 25 m2, having 65 cm sand-gravel substrata, supported by ventilated-drainage system and planting with narrow-leave cattails (Typha augustifolia), were fed with septage collected from Bangkok city, Thailand. To operate in a vertical-flow mode, the septage was uniformly distributed on the surface of the CW units. During the first year of operation, the CWs were operated at the solid loading rates (SLR) and application frequencies of, respectively, 80-500 kg total solid (TS)/m2.yr and 1-2 times weekly. It was found that the SLR of 250 kg TS/m2.yr resulted in the highest TS, total chemical oxygen demand (TCOD) and total Kjeldahl nitrogen (TKN) removal of 80, 96 and 92%, respectively. The TS contents of the dewatered septage on the CW beds were increased from 1-2% to 30-60% within an operation cycle. Because of the vertical-flow mode of operation and with the effectiveness of the ventilation pipes, there were high degrees of nitrification occurring in the CW beds. The nitrate (NO3) contents in the CW percolate were 180-250 mg/L, while the raw septage had NO3 contents less than 10 mg/L. Due to rapid flow-through of the percolates, there was little liquid retained in the CW beds, causing the cattail plants to wilt, especially during the dry season. To reduce the wilting effects, the operating strategies in the second year were modified by ponding the percolate in the CW beds for periods of 2 and 6 days prior to discharge. This operating strategy was found beneficial not only for mitigating plant wilting, but also for increasing N removal through enhanced denitrification activities in the CW beds. During these 2 year operations, the dewatered septage was not removed from the CW beds and no adverse effects on the septage dewatering efficiency were observed.


2016 ◽  
Vol 19 (1) ◽  
pp. 75-84
Author(s):  
Rayhan Hossain ◽  
Mohammad Arifur Rahman ◽  
Nargish Jahan Ara ◽  
AM Shafiqul Alam

The adsorption of levafix red (LR) dye from waste water via batch adsorption onto treated jute stick powder was investigated. Studies concerning the factors influencing the adsorption such as adsorbent dosage, pH, contact time and temperature were systematically investigated and discussed. The results revealed that the maximum removal of levafix red was ~91% from water. The kinetics data were analyzed using pseudo-first order and pseudo-second order models. It was best described by the pseudo-second order model. The adsorption equilibrium follows Langmuir isotherm. This result indicates that treated jute stick powder could be employed as low-cost alternatives to commercial activated carbon for the removal of levafix red (LR) from waste water. Rapid industrialization in Bangladesh has resulted in increased water pollution that has higher dye level. Waste water from dyeing and finishing factories is a significant source of environmental pollution. The waste water is typically characterized by high levels of COD (chemical oxygen demand) concentration, high concentration of coloring material, large amount of suspended solids, highly fluctuating pH and high temperature. Dyes may therefore present an ecotoxic hazard and introduces the potential danger of bioaccumulation that may eventually affect man by transport through the food chain. As pharmaceutical industries use lots of water and intake of this type of water might have adverse effects on human health. Therefore, water purification is extremely essential for human and animal health and dye free water may be farther purified for its proper use.Bangladesh Pharmaceutical Journal 19(1): 75-84, 2016


2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Mohammed Moniruzzaman ◽  
John Rock

A fibre Bragg grating sensor is coated with a novel polymer gel in order to investigate its suitability for nondestructive measurement of moisture in materials that can potentially lose their integrity due to moisture ingress. Absorption and desorption of moisture lead to swelling/shrinkage of an azobenzene-based gel, which induces a strain in the Bragg grating resulting in wavelength shifts. The results demonstrated that the amount of wavelength shift is linearly dependent on the amount of water ingress by the gel. The performance of the proposed optical fibre moisture sensor was found to be repeatable with no detectable hysteresis and has the potential to offer a low-cost route for monitoring moisture content.


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