The effect of sodium thiosulfate on cytotoxicity of a diimine Re(i) tricarbonyl complex

Replacing the aqua ligand in fac-[(Re(CO)3(bpy)(H2O)]+ with S2O32− disrupts the cellular uptake of the product in the MD-MB-231 breast cancer cells.

Topological Unraveling the [3+2] Cycloaddition (32CA) Reaction between N-Methylphenylnitrone and Styrene Catalyzed by Chromium Tricarbonyl Complex from Electron Localization Function and Catastrophe Theory.

We have investigated the reaction mechanisms of [3+2] cycloaddition (32CA) between N-methylphenylnitrone and styrene catalyzed by chromium tricarbonyl complex at the MPWB1K/6-311G(d,p) level of approximation. Activation energy analysis reveals that...

Flexible to rigid: IR spectroscopic investigation of a rhenium-tricarbonyl-complex at a buried interface

Immobilized rhenium tricarbonyl complexes were embedded in ALD deposited ZrO2, and investigated by (time resolved) infrared spectroscopy. The initially solvent exposed molecules react on the change of their environment.

Molybdenum tricarbonyl complex functionalised with a molecular triazatriangulene platform on Au(111): surface spectroscopic characterisation

A Mo(0) tricarbonyl unit supported by a tripod ligand was bound to a triazatriangulene platform, and the resulting complex was deposited on a Au(111) surface. The corresponding monolayer was characterized with STM, XPS, NEXAFS and IRRAS.

Substitution reactivity and structural variability induced by tryptamine on the biomimetic rhenium tricarbonyl complex

The biomimetic tryptamine rhenium tricarbonyl complex shows rapid substitution reactivity on the 6th position as well as cytotoxicity and photoluminescence capability induced by the salicylidene bidentate ligand.

Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water

The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions.