Delayed-Release Suspending Aid Provides Cement-Slurry Stability in High-Temperature, Horizontal Wells

Author(s):  
Gary P. Funkhouser ◽  
Lennox Leotaud ◽  
Jason Bratcher
2021 ◽  
Author(s):  
Rahul Jadhav ◽  
Thomas Pisklak

Abstract To mitigate strength retrogression at temperatures, higher than 230°F, well cement designs typically include strength retrogression control additives (SRCAs). Solid siliceous materials (e.g., silica flour, fume, and sized-sands) are commonly used SRCAs that are incorporated into cements using dry-blending techniques. This study highlights liquid silica compositions as alternative SRCAs to dry-blended silica for high-temperature cementing. Liquid additives can be managed easily, delivered accurately, and offer a reduced on-site footprint, thus making them particularly advantageous for operations offshore and in remote locations. This paper presents a study on the use of liquid silica compositions as SRCAs and their effect on cement slurry properties, such as thickening time, mixability, fluid loss, rheology, and free water. The cement slurry used during the current study was prepared and tested according to API RP 10B-2 (2005). The performance of the liquid silica composition was tested at temperatures up to 400°F. Set cement samples were prepared using the liquid silica composition and silica flour, cured for up to 14 days at different temperatures. In addition, permeability testing was also performed on the samples. This paper presents the findings of this research, including strength and permeability test results on cement blends cured at temperatures of 300, 330, 350, and 400°F. The liquid silica composition, which provided silica to the cement formulation equivalent to 35% BWOC dry silica (48% BWOC liquid SRCA), functioned effectively as an SRCA at temperatures up to 330°F. Signs of strength retrogression were observed at 350°F and were more pronounced at 400°F. A greater concentration of the liquid silica composition may be necessary to prevent strength retrogression at temperatures higher than 330°F. The liquid silica composition also demonstrated mild retardation and a dispersing effect on the slurry. However, it helped enable improved slurry stability and suspension, thus providing improved control over free water without adverse effects on fluid loss and sedimentation. The study results demonstrate that a liquid SRCA can help improve the performance of annular cement designs to provide dependable barriers and effective zonal isolation during high-temperature cementing applications. The improved performance enabled by this liquid silica composition verifies its potential use as an alternative SRCA for high-temperature oil well cementing operations.


Nafta-Gaz ◽  
2021 ◽  
Vol 77 (5) ◽  
pp. 323-331
Author(s):  
Miłosz Kędzierski ◽  
◽  
Marcin Rzepka ◽  

The article presents the results of the influence of carbon nanotubes on the mechanical parameters of cement stones under high temperature and pressure conditions (150°C, 90 MPa). The tests used multi-walled carbon nanotubes (MWCNTs) with an external diameter of 10–20 nm and a length of 10–30 μm. Cement slurries contained 0.1% of CNTs bwoc (by the weight of cement). Laboratory tests of cement slurries were carried out at the Oil and Gas Institute – National Research Institute. The tests were carried out under conditions of increased pressure and temperature at 150°C, 90 MPa. Cement slurries were prepared on the basis of class G drilling cement. Developing recipes were guided by the requirements to be met by cement slurry for the cementing of casing in the conditions of high temperature and reservoir pressures. The densities of tested slurries ranged from 1900 kg/m3 to 2250 kg/m3 (slurries with the addition of hematite). The cement slurries were tested for density, fluidity, rheological parameters, filtration and thickening time. Compressive strength tests and measuring adhesion were carried out after 2, 7, 14 and 28 days. Cement slurry recipes with very good technological parameters were developed and after curing (after 28 days of hydration) had very high values of compressive strength, reaching up to 45 MPa. Cements were characterized by high values of adhesion to pipes reaching up 7 MPa after 28 days. The research showed significant information about possible applications of carbon nanotubes to modify the cement slurry under conditions of high temperature and pressure. The conducted tests confirmed that the addition of even small amounts of CNTs improves the mechanical parameters of the cement stone compared to the base sample without such addition, and also reduces the thickening time of cement slurries and reduces filtration. It is investigated that CNTs addition increases the viscosity and yield point of cement slurry. As a result, slurries with the addition of MWCNTs will more effectively displace the mud from the borehole and significantly affect the quality of cementation.


2018 ◽  
Vol 136 (13) ◽  
pp. 47292 ◽  
Author(s):  
Rui Zhang ◽  
Qiong Han ◽  
Xuyang Zhu ◽  
Youfeng Cai ◽  
Tongqing Zhang

2021 ◽  
pp. 52-62
Author(s):  
V. P. Ovchinnikov ◽  
O. V. Rozhkova ◽  
S. N. Bastrikov ◽  
D. S. Leontiev ◽  
P. V. Ovchinnikov

The article discusses the main technological processes of well construction for the production of high-viscosity hydrocarbons from productive lowporosity reservoirs with high temperature and pressure conditions, which include shale deposits of Bazhenov formation. According to the results of the review and analysis of existing solutions in the development of this deposits, the following measures were justified and proposed: construction of branched multi-hole azimuth horizontal wells, implementation of selective multi-stage hydraulic fracturing in the productive formation; the use of oil-based process fluids when opening the reservoir, the use of plugging materials for isolation of the reservoir, the hardening product of which is represented by thermally stable hydrate phases (hydrobasic hydrosilicates). Вranched wells have a long horizontal end (about 1 000 meters or more). Only a part of the horizontal section works effectively, which is the basis for the development and application of the staged, both in time and along the strike, hydraulic fracturing method. At the level of the invention, a method and apparatus for carrying out multistage selective hydraulic fracturing in wells with horizontal completion have been developed. The article describes a method for implementing multistage selective hydraulic fracturing, comparing this method with the existing ones. Much attention is given to the need to use hydrocarbon-based solutions for the initial opening the reservoir, to use cement slurries from composite materials to separate the reservoir, the hardening product of which is a stone formed by low-basic calcium hydrosilicate.


2016 ◽  
Vol 847 ◽  
pp. 485-489
Author(s):  
Xing Cai Zhang ◽  
Xiao Wei Cheng ◽  
Xiao Yang Guo

With the exploration of oil and gas in depth, shallow wells already can’t satisfy the requirement, therefore to explore and develop deep reservoirs is necessary. In the case of deep wells the loop temperature of bottom can reach to 150°C-200°C, which put forward a higher requirement for the high temperature resistance property of cement slurry. At present, many problems existed in the most of high temperature cement slurry. For example, high temperature resistance is not well, cement thickening time can’t adjust easily, mega-thermal sedimentation stability is unsatisfactory, and ultra-retarding phenomenon appeared for the top prone. After research indoors, we developed the ultra-high temperature slurry system by means of the investigation on cementing additives and select proper materials from high temperature resistant fluid loss additives, retarders, flowable agent at the same time. This system needs a lots of properties, such as, adjustable slurry thickening time below 200°C, great slurry sedimentation stability, API loss can be controlled at the range of 0-50ml, insensitive to temperature and density, could be used in low-density and conventional density cement etc. This system be used successfully in the well that loop temperature of bottom reaches to 185°C and get a good effect finally.


2020 ◽  
Vol 993 ◽  
pp. 1341-1350
Author(s):  
Xiu Jian Xia ◽  
Yong Jin Yu ◽  
Jian Zhou Jin ◽  
Shuo Qiong Liu ◽  
Ming Xu ◽  
...  

The conventional oil-well cement dispersant has the characteristics of poor dispersion at high temperature, poor compatibility with other additives, and environmental pollution during the production process. In this article, with ultra-early strong polyether monomer, acrylic acid, 2-acrylamine-2-methylpropyl sulfonic acid, sodium methacrylate as copolymer monomers, an environmentally friendly polycarboxylic acid dispersant, DRPC-1L, was prepared by the aqueous solution free-radical polymerization. The chemical composition and thermal stability of the synthetic copolymer were characterized by FTIR and TGA techniques. The evaluation results show that DRPC-1L has a wide temperature range (30~210 °C), good salt-resistance and dispersing effect. It can significantly improve the rheological performance of cement slurry, and it is well matched with oil-well cement additives such as fluid loss agent, retarder and so on. Moreover, it is beneficial to the mechanical strength development of set cement, especially the early compressive strength. It can also inhibit the abnormal gelation phenomenon of cement slurry, flash set, that occurs during high temperature thickening experiments, which plays an important role in enhancing the comprehensive performance of cement slurry. Consequently, the novel polycarboxylic acid dispersant has good application prospects in deep and ultra-deep wells cementing.


2013 ◽  
Vol 744 ◽  
pp. 53-57 ◽  
Author(s):  
Lian Xin Gao ◽  
Kun Zhong Sun ◽  
Yi Zhang

The application of API threaded connections for casing and tubing is limited due to their imperfect sealing ability and weak connecting strength. To overcome these prominent drawbacks of API threaded connections, new WSP series of premium threaded connections are developed by Wuxi Seamless Oil Pipe Corporation for HTHP(High temperature, High pressure) wells, deep wells, steam injection wells, highly deviated and long horizontal wells, etc. Characteristics and application ranges of eight kinds of these high performance premium threaded connections are compared and analyzed thoroughly in this paper. The comparison results are not only a good reference for technicians to design new connections, but a technical proof for users to choose the proper connections in different applications.


Author(s):  
Khalil Rehman Memon ◽  
Aftab Ahmed Mahesar ◽  
Shahzad Ali Baladi ◽  
Muhannad Talib Sukar

The experimental study was conducted on rheological properties in laboratory to measure the integrity of cement slurry. Three samples were used and analyzed at different parameters to check the elasticity of cement slurry. Additives with various concentrations, i.e. silica fume % BWOC (Present by Weight on Cement) (15, 17, 19 and 21), dispersant % Wt (Percent Weight) (0.21, 0.26 and 0.31) and additional 1; % Wt of fluid losscontrol were used to improve the performance of the cement slurry at the temperature of 123oC. The results have shown that increase in the concentration of dispersants that have caused to decrease in the Plastic Viscosity (PV), Yield Point (YP) and GS (Gel Strength). The rheological properties of cement were improved with the addition of fluid loss control additive in 21 % BWOC (Present by Weight on Cement) silica fume increase the water quantity in cement slurry that improve its durability and to reduce the strength retrogression in High Temperature High Pressure (HTHP) environment. Results were achieved through HTHP OFITE Viscometer (Model 1100).


2016 ◽  
Vol 847 ◽  
pp. 497-504
Author(s):  
Xiu Jian Xia ◽  
Jin Tang Guo ◽  
Shuo Qiong Liu ◽  
Jian Zhou Jin ◽  
Yong Jin Yu ◽  
...  

On account of that the domestic polymer fluid loss additive exists some severe problems, such as, inferior thermal resistance, poor salt tolerance, strong shear-and thermal thinning behavior, a novel polymer/silica nanocomposite PADMO-V@NS is used as ultra-high temperature fluid loss control additive for cementing. In the present study PADMO-V@NS was prepared through an in situ free radical copolymerization of 2-acrylamico-2-methylpropane sulfonic acid (AMPS), N,N-dimethylacryl amide (DMAM), maleic anhydride (MA), octadecyl dimethylallyl ammonium chloride (ODAAC) and triethoxyvinylsilane (VTS) modified nanosilica. The linear hydrophobic associated copolymer was regarded as the shell and the modified nanosilica as the core. The microstructure, compositions and thermal resistance of PADMO-V@NS were investigated through FTIR and TGA techniques. The results showed that the copolymer modified with nanosilica particles possessed more excellent thermal stability than that of PADMO, and the most rapid decomposing temperature of PADMO-V@NS was highly up to 396.9°C. The application performance of PADMO-V@NS in cement slurry exhibited that it had excellent fluid loss control capacity, good high temperature resistance, strong salt tolerance and mild shear-/ thermal thinning performance, and could be used in 220°C and saturated brine circumstances. Moreover, comparing to PADMO, the compressive strength of set cement containing the copolymer increased over 20 % at 80°C, atmosphere pressure and curing time of 1 day due to the reaction of residual silanol groups with Ca (OH)2. The laboratory research results indicated that the multi-functional fluid loss additive composed of hydrophobic associated polymer/silica nanocomposite had bestowed on the cement slurry systems good comprehensive properties, and may have extensive applications in deep & ultra-deep oil/gas wells cementing.


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