scholarly journals Suppressing Effect of Chelating Agent on the Degradation and Discoloration of Fabric Dyed with Metal Complex Dye during Bleaching Process with Hydrogen Peroxide

1995 ◽  
Vol 51 (1) ◽  
pp. 39-43 ◽  
Author(s):  
Yuko Imabayashi
1982 ◽  
Vol 152 (1) ◽  
pp. 81-88
Author(s):  
E H Berglin ◽  
M B Edlund ◽  
G K Nyberg ◽  
J Carlsson

Under anaerobic conditions an exponentially growing culture of Escherichia coli K-12 was exposed to hydrogen peroxide in the presence of various compounds. Hydrogen peroxide (0.1 mM) together with 0.1 mM L-cysteine or L-cystine killed the organisms more rapidly than 10 mM hydrogen peroxide alone. The exposure of E. coli to hydrogen peroxide in the presence of L-cysteine inhibited some of the catalase. This inhibition, however, could not fully explain the 100-fold increase in hydrogen peroxide sensitivity of the organism in the presence of L-cysteine. Of other compounds tested only some thiols potentiated the bactericidal effect of hydrogen peroxide. These thiols were effective, however, only at concentrations significantly higher than 0.1 mM. The effect of L-cysteine and L-cystine could be annihilated by the metal ion chelating agent 2,2'-bipyridyl. DNA breakage in E. coli K-12 was demonstrated under conditions where the organisms were killed by hydrogen peroxide.


ISRN Textiles ◽  
2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
T. Harizi ◽  
S. Dhouib ◽  
S. Msahli ◽  
F. Sakli

Successful bleaching of pigmented fibres was, generally, evaluated by a maximum whiteness, a minimum yellowness, and less damage to the bleached fibers. A review of the literature reveals that many studies on pigmented fibre bleaching are concerned with improving the whiteness and mechanical properties of bleached fibres. In this study, we investigate the effects of the hydrogen peroxide concentration, bleaching time, and clarification bath on the bleaching efficiency of Tunisian dromedary hair. It was showed that 30 min bleaching time gives better result in term of whiteness. However, an increased bleaching time gives an excessive damage to the bleached fibers. Further, the damage incurred by the dromedary hair was more important than that for wool, as is shown by the tenacity results. We found that oxalic acid, which is used for rinsing dromedary hair (after bleaching), provides improved results in term of whiteness obtained with bleaching. Certainly, oxalic acid made it possible to remove the maximum of iron remaining on fibre after bleaching. Bleaching methods demonstrate the excessive damage incurred by the fibre when using hydrogen peroxide particularly with raise concentration. This damage leads to adverse effects on the tenacity fibre.


2019 ◽  
Author(s):  
Ab Dulmalik Khaliq ◽  
Achmad Chafidz ◽  
Faisal Rasjid Maddun ◽  
Hafizh Rafi Herimawan ◽  
Ghalib Muhammad Yusuf ◽  
...  

2011 ◽  
Vol 233-235 ◽  
pp. 1328-1331 ◽  
Author(s):  
Qiang Zhao ◽  
De Zhi Sun ◽  
Ming Yang Zhang ◽  
Su Min Kang

The Mg(OH)2-based peroxide bleaching process of Nigra poplar CTMP pulp was confirmed. The optimal bleaching condition were as follows: 4% H2O2,1% Mg(OH)2, 15% pulp consistency, the reaction temperature was 80°C and the suitable reaction time was 2 hours. The Mg(OH)2-based bleaching process shows significant benefits over sodium hydroxide process. In contrast, magnesium hydroxide bleaching generates higher pulp yield and lower effluent COD at the same chemical dosage. The study shows peroxide bleaching of CTMP pulp with magnesium hydroxide as alkali source is to be an option for the high-yield pulp bleaching.


2011 ◽  
Vol 233-235 ◽  
pp. 934-937
Author(s):  
Xiang Xia Liu ◽  
Yong Tang Jia ◽  
Jian Feng Di ◽  
Jia Jie Lu

This paper discussed the bleaching process with chlorine dioxide on cotton fabric. Tests of the whiteness, capillary effect, and strength were made and the best bleaching process with chlorine dioxide was determined. Studies showed that compared with the conventional bleaching process of hydrogen peroxide, the whiteness and strength of cotton fabric treated with chlorine dioxide were higher and the capillary values was similar. Chlorine dioxide can find its good application because of its good properties and low pollution.


2011 ◽  
Vol 347-353 ◽  
pp. 2245-2248
Author(s):  
Jing Jian Zhu ◽  
Long Lu ◽  
Jian Xin Chen

In this paper, the effects of operating parameters such as UV light wavelength, initial pH, reaction temperature and hydrogen peroxide concentration on decolorization of metal complex dyes (Neutral Bordeaux GRL, Neutral Pink BL and Neutral Blue BNL) by UV/H2O2process were studied in detail. The results showed that the decolorization rate constants were obviously enhanced with the increase of UV intensity. In UV (254nm)/H2O2system, 94.4% decolorization of Neutral Bordeaux GRL, 99.2% decolorization of Neutral Pink BL and 65.4% decolorization of Neutral Blue BNL were achieved after 60 min reaction. The results also indicated that both suitable amount of H2O2and initial pH were needed for effective decolorization of different metal complex dyes. The reaction activation energy of Neutral Bordeaux GRL, Neutral Pink BL and Neutral Blue BNL were 3.43, 14.4 and 23.39 KJ mol-1, respectively.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Edith A. Enemose ◽  
Jerome S. Nworu ◽  
Onunkwo Innocent ◽  
Wisdom E. Morka

Abstract As part of the current research for more effective antimalarial drug, Cu (II) complex of sulphamethazine with 1,10 phenanthroline was synthesized. The novel complex was characterized by Elemental analysis, FT-IR and electronic spectroscopy. The novel complex is insoluble in water, which is an indication of covalent and non- electrolyte character. The elemental analysis result of the complex correspond with the proposed formula [Cu(SUF)(phen)(SCN)2]. The electronic spectrum of sulfamethazine and 1, 10- phen showed absorption bands at 212 nm (47169 cm−1) and 306 nm (32679 cm–1). These bands were assigned to the n – δ* and π – δ* transitions. The infrared bands were seen at 3443 – 3344 cm −1which were attributed to the presence of v(NH2), v(NH) and v (OH) vibrations experience bathochromic shift in the metal complex. The parent ligands acted as a bidentate chelating agent showing coordination through the pyridine nitrogen and the nitrogen of the NH moiety in this case.


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