Structural, Optical, and Electrical Properties of Amorphous Hydrogenated Carbon Nitride

1987 ◽  
Vol 95 ◽  
Author(s):  
He-Xiang Han ◽  
Bernard J. Feldman

AbstractAmorphous hydrogenated carbon nitride thin films have been grown by plasma decomposition of a feedstock of CH4 and N2. In the films with higher nitrogen concentration, the infrared absorption spectra are dominated by NH2 modes and give strong evidence of a polymeric structure. The optical absorption and photoluminescence spectra show that nitrogen incorporation decreases the bandgap and increases the structural order of these thin films. The undoped material is an insulator with resistivities up to 1015Q cm, but when doped with iron, it becomes a p-type degenerate semiconductor.

Author(s):  
Daniel A. Fentahun ◽  
Alekha Tyagi ◽  
Sugandha Singh ◽  
Prerna Sinha ◽  
Amodini Mishra ◽  
...  

2005 ◽  
Vol 492 (1-2) ◽  
pp. 203-206 ◽  
Author(s):  
Zhi Yan ◽  
Zhi Tang Song ◽  
Wei Li Liu ◽  
Qing Wan ◽  
Fu Min Zhang ◽  
...  

2010 ◽  
Vol 636-637 ◽  
pp. 423-429 ◽  
Author(s):  
M. Fathallah ◽  
N. Alassimi ◽  
N. Alzayed ◽  
R. Gharbi

Optical and electrical properties amorphous carbon nitride (a-CN) has been investigated on films deposited by reactive R.F. sputtering source with a graphite target. The amorphous carbon nitride samples were prepared under a gas mixture of nitrogen (N2) and /or Argon (Ar).The optical transitions are governed by the  and * electronic state distributions, related to sp2- and sp1-hybridized C and N atoms. Specific lonepair electronic states arise from groups (CN) with sp1-hybridized C atoms, which may form C≡N triple bonds or —N=C=N— longer chains. Photoluminescence spectra show a maximum around 650 nm. Two conduction regimes at high and low temperature are found in a-CN samples. The corresponding activation energies decrease with the increase of target voltage.


1999 ◽  
Vol 607 ◽  
Author(s):  
V. Valdna

AbstractThe photoluminescence spectra, defect composition and optoelectronic properties of chlorine doped CdTe monocrystals, thick layers and thin films are investigated. It is supposed that the complex defect (VCd-2ClTe) is a neutral defect that causes high resistivity of Cl doped CdTe. This complex can dissociate into two charged defects (VCd-ClTe) and ClTe at 300 K. Acentre (VCd-ClTe) is a stable defect that is responsible for p-type conductivity of Cl doped CdTe. Depending on the C1 concentration high resistivity, high photoconductivity or high p-type conductivity can be formed in CdTe that is only chlorine doped.


2009 ◽  
Vol 60-61 ◽  
pp. 105-109 ◽  
Author(s):  
Yong Li Yang ◽  
Shu Ying Cheng ◽  
Song Lin Lai

Silver-doping in SnS films can improve the semiconducting properties of SnS films. Based on our previous research, SnS:Ag thin films were deposited on ITO coated glass by pulse electro-deposition in order to study their structural, optical and electrical properties. SnS:Ag thin films were characterized with X-ray diffraction (XRD) , Scanning Electron Microscope (SEM) and some other methods. The primary composition of the films is SnS, but maybe there is a little quantity of SnS2, Ag8SnS6 and other compounds. The doped films exhibit good crystallization with big grain size. They have an optical gap of 1.66~1.89eV and a high absorption coefficient (α>5×104cm-1). Hall measurement has shown that all the samples are of p-type conduction with low resistivity of the order of 10-3Ω•cm, and the carrier concentration increases to 1019cm-3 after Ag-doping. In conclusion, the semiconducting properties of the SnS films have been improved by silver-doping. Thus, SnS:Ag thin films can be used as solar cells absorbers.


2009 ◽  
Vol 79-82 ◽  
pp. 787-790
Author(s):  
Ti Ning ◽  
Feng Ji ◽  
Jin Ma ◽  
Zhen Guo Song ◽  
Xu An Pei ◽  
...  

Copper-tin-oxide thin films have been prepared on quartz substrates by the magnetron sputtering method. The structural,optical and electrical properties were investigated. The prepared samples were amorphous, CuSnO3 single crystalline grains with perovskite structure were observed after annealing temperature was above 530°C. The optical and electrical properties had great dependence with reactive gas pressure and annealing temperature. Thermal probe reveals p type conductivity of some samples. Keywords: Magnetron sputtering, CuSnO3, Perovskite structure


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