High Reliability Underfill for Flip-Chip Application

1996 ◽  
Vol 445 ◽  
Author(s):  
K. Sumita ◽  
K. Kumagae ◽  
K. Dobashi ◽  
T. Shiobara ◽  
M. Kuroda

AbstractA new underfill was developed for a flip chip application with a large VLSI die. The new underfill is resistant to hydrolysis, exhibits a significantly lower moisture saturation level than widely used carboxylic anhydride cured underfills, demonstrates superb penetration capability between such a large die and an organic substrate without void formation, and delivers excellent adhesion characteristics and reliability performance during temperature cycling test and PCT (pressure cooker test).The new underfill utilizes amine catalyzed ring opening polymerization of epoxides, forms ether linkages during cure rather than ester linkages which anhydride cured underfills form, and strongly resists to hydrolysis. The underfill is less sensitive to moisture contamination and provides improved floor life as well as storage life in contrast to anhydride cured underfills as well. Unique low stress performance and penetration capability of the underfill are attributed to the use of proprietary silicone modified epoxy resin as well as highly loaded filler of optimized size, shape and size distribution in reference to the gap between a die and an organic substrate.An optimum cure schedule and a desirable viscosity range have also been identified for the new underfill to minimize filler segregation. Proper preheating of a die‐substrate has effectively reduced void formation while facilitating the removal of volatile from an organic substrate.

Author(s):  
Gnyaneshwar Ramakrishna ◽  
Donghyun Kim ◽  
Mudasir Ahamad ◽  
Lavanya Gopalakrishnan ◽  
Mason Hu ◽  
...  

Large Flip Chip BGA (FCBGA) packages are needed in high pin out applications (>1800), e.g., ASIC's and are typically used in high reliability and robustness applications. Hence understanding the package reliability and robustness becomes one of paramount importance for efficient product design. There are various aspects to the package that need to be understood, to ensure an effective design. The focus of this paper is to understand the BGA reliability of the package with particular reference to comparison of the surface finish, vis-a`-vis, between Electroless Nickel Immersion Gold (ENIG) and Solder On Pad (SOP) on the substrate side of the package, which are the typical solutions for large plastic FC-BGA packages. Tests, which include board level temperature cycling, monotonic bend and shock testing have been conducted to compare the two surface finish options. The results of these tests demonstrate that the mechanical strength of the interface exceeds by a factor of two for the SOP surface finish, while BGA design parameters play a key role in ensuring comparative temperature cycle reliability in comparison with ENIG packages.


Author(s):  
Gino Hung ◽  
Ho-Yi Tsai ◽  
Chun An Huang ◽  
Steve Chiu ◽  
C. S. Hsiao

A high reliability and high thermal performance molding flip chip ball grid arrays structure which was improved from Terminator FCBGA®. (The structure are shown as Fig. 1) It has many advantages, like better coplanarity, high through put (multi pes for each shut of molding process), low stress, and high thermal performance. In conventional flip chip structure, underfill dispenses and cure processes are a bottleneck due to low through put (dispensing unit by unit). For the high performance demand, large package/die size with more integrated functions needs to meet reliability criteria. Low k dielectric material, lead free bump especially and the package coplanarity are also challenges for package development. Besides, thermal performance is also a key concern with high power device. From simulation and reliability data, this new structure can provide strong bump protection and reach high reliability performance and can be applied for low-K chip and all kind of bump composition such as tin-lead, high lead, and lead free. Comparing to original Terminator FCBGA®, this structure has better thermal performance because the thermal adhesive was added between die and heat spreader instead of epoxy molding compound (EMC). The thermal adhesive has much better thermal conductivity than EMC. Furthermore, this paper also describes the process and reliability validation result.


Author(s):  
Xing QIU ◽  
Jeffery Lo ◽  
Yuanjie CHENG ◽  
Shi-Wei Ricky Lee ◽  
Yong Jhe TSENG ◽  
...  

Abstract Cu pillar micro-bumps with polymer cores have been demonstrated to effectively reduce thermomechanical stress and improve joint reliability. Fabricating polymer cores by a printing approach was proposed to overcome the limitations in conventional fabrication process. Cylindrical polymer cores with diameter of 20 µm and height of 30 µm were successfully printed. Surface metallization was subsequently applied on the printed polymer cores and Cu pillar micro-bumps with printed polymer cores with diameter of 35 µm and height of 35 µm were eventually achieved. To study the reliability performance of the interconnect joints made of Cu pillar micro-bumps with printed polymer cores, flip-chip bonding technology was successfully introduced and the interconnect joints between a designed BT substrate and a silicon chip were formed. The interconnect joints made of conventional Cu pillars with identical dimensions were prepared for comparison. The reliability performance of the joints was investigated under temperature cycling condition and drop condition, respectively. Printed polymer cores increased the characteristic life by 32% in a temperature cycling test (0°C-100°C), while the drop test showed that printed polymer cores increased the characteristic life by 4 times due to the extra compliance provided by the printed polymer cores. It can be concluded that Cu pillar micro-bumps with printed polymer cores can effectively reduce stress and improve joint reliability.


2013 ◽  
Vol 2013 (DPC) ◽  
pp. 001870-001893
Author(s):  
Rajesh Katkar ◽  
Zhijun Zhao ◽  
Ron Zhang ◽  
Rey Co ◽  
Laura Mirkarimi

Existing Package-on-Package (PoP) solutions are rapidly approaching the logic memory bandwidth capacity in the multi-core mobile processor packages. Package on Package stack using the conventional solder balls has a serious pitch limitation below 400um. The through mold via interconnects may reduce the pitch to 300um; however, this technology is believed to reach a limitation below 300 um. Other approaches including the use of PCB interposers between the Logic and the memory face similar challenges; however, they are cumbersome in the assembly process and expensive. Although Through Silicon Via stacking is expected to achieve the ultimate high bandwidth required to support multi-core mobile processors, the technology must overcome the challenges in process, infrastructure, supply chain and cost. Bond Via Array (BVA) technology addresses all of these issues while enabling high bandwidth PoP stacking of more than 1000 high aspect ratio interconnects at less than 200um within the standard package footprint. BVA is a cost effective, ultra-fine pitch, high density PoP stacking solution that will assist in driving high logic-memory bandwidth applications with standard assembly equipment and processes. This is achieved by encapsulating the logic package after forming free-standing wire bonds along the periphery of its flip chip substrate. The wire protrusions formed above the mold cap at the top of the package are then connected to the BGA at the bottom of the memory package during a standard reflow operation. In this work, the initial evaluation test vehicle with 432 PoP interconnects at 240um pitch within a standard 14 x 14mm package foot print is demonstrated. The important technological challenges we overcame to fabricate the first prototypes will be discussed. The reliability performance describing the temperature cycling, high temperature storage, autoclave and drop testing will be discussed. Finite element analysis modeling used to optimize the package structure will be presented.


2011 ◽  
Vol 2011 (1) ◽  
pp. 000997-001006 ◽  
Author(s):  
Kei Murayama ◽  
Taiji Sakai ◽  
Nobuaki Imaizumi ◽  
Mitsutoshi Higashi

The bonding technique for high density Flip Chip(F.C.) packages requires a low temperature and a low stress process to achieve high reliability of the micro joining. Sn-Bi solder has been noted as a low temperature bonding material. Electromigration behavior of Sn-57wt%Bi flip chip interconnection with Cu post bumps was investigated. The flip chip bumps used for this experiments consisted of Cu post formed with plating and Sn-57wt%Bi solder. Two types of under bump metal(UBM) of organic substrate were studied, that is, electroless Ni(6μm)/Au(0.5μm) on Cu pad and Cu pad. Electron flow to induce the electro-migration was from organic substrate side (Cu pad) to chip side (Cu post) with current density of 40000A/cm2 at 125 degree C. At both types of the UBM, Bi migrated and accumulated to the anode side (Cu post) and Sn migrated to the cathode side (substrate pad). Each interconnect resistance has increased to about 25% and 46% within 100 hours, respectively. However, after more than 3000 hours, they were stabilized. With Ni/Au UBM pad, Cu3Sn/Cu6Sn5 intermetallic compounds (IMCs) were formed at the Cu bump side. And under the Bi layer Cu6Sn5/Ni-Sn compounds were formed. But we didn’t observe the failure like cracks or voids at the Ni layer. With Cu pad, only Cu3Sn IMC at the Cu bump side and under the Bi layer Cu6Sn5/Cu3Sn compounds were formed after 4000 hours. Although the voids were observed at Cu3Sn/Cu interface, good electrical connection was obtained.


2017 ◽  
Vol 2017 (1) ◽  
pp. 000754-000760 ◽  
Author(s):  
Adrien Morard ◽  
Jean-Christophe Riou ◽  
Gabriel Pares

Abstract The first part of this work is dedicated to the study of “system in package” (SiP) solutions based on different substrates, namely organic or silicon. Generally speaking a SIP is composed by several active and passive components stacked on an interposer. Benchmarks done by Safran have demonstrated that in terms of substrate, embedded die technology leads to several advantages compared to 3D TSV or TGV based packaging approaches. The benefits leaded by this substrate is the possibility to embed some Surface Mount Technologies, bare chips or integrated passives devices (IPD) banks directly above or below the stacked active components. This way, top and bottom surface of the substrate can be used to integrate several heterogeneous dies side by side while using low profile flip-chip assemblies on the C4 side. Finally, in this kind of 3D architecture, this embedded technology enable a gain of integration, without using costly TSV connections. Substrates of high quality allow a reduction of interconnection pitches leading to very aggressive integration. Secondly, a 3D stack with 3 levels of components, as described above, means to, at least, 2 or 3 REACH compliant sequential assembly processes, depending on the needs. In order to consider all the solutions for an optimized integration and a high reliability, this work focused on the study of a simple SIP, which includes the top die assembled by flip-chip. For the flip chip hybridization, copper-pillars technologies are studied in the case of both organic and silicon interposers. The aim of this study is to understand in depth both processes and to obtain information on the reliability aspect after thermal cycling stress of the flip chip assembly. Thirdly, we built many silicon test chips with different characteristics with a dedicated daisy chain test vehicle. The different parameters are: chips' thicknesses (50 to 200 μm), chips' sizes (2 to 8 mm), bump structures (diameter), and the pitches of the interconnection (from 50 to 250 μm) and the number of interconnection rows. Designs were chosen in order to fit real operational configurations. Moreover, these configurations are interesting to build a comprehensive model in order to understand the failure mechanisms. These chips are then stacked by flip-chip on the silicon and on the organic substrate. We are also designing the two configurations of substrates. Only the production of the organics part is outsourced. Fourth, with all these configurations we will be able to fit the thermo-cycling test results with thermos-mechanical simulations done by finite elements. 3D models will take into account the different geometries in order to understand and quantify the various key parameters. The analysis will mainly focus on 3D interconnections. Design rules based on the results will be derivate. The aim is to obtain dimensional criteria based on stress versus deformation responses. Information obtained will be exploited for designing the future functional SIP. Fifth, in order to assess the electrical behaviors of this 3D architecture, signal integrity aspect will be considered as well. As for the design, the migration from an existing 2D electrical design to a 3D architecture design will be studied keeping the signal transmission without any degradation. The ultimate aim of this work is to define mechanical and electrical design rules that can then be used in functional SiP modules.


2002 ◽  
Vol 124 (3) ◽  
pp. 240-245 ◽  
Author(s):  
Johan Liu ◽  
Zonghe Lai

A reliability study on anisotropically conductive adhesive joints on a Flip-Chip/FR-4 assembly has been carried out. In the study, nine types of anisotropic conductive adhesive (ACA) and one nonconductive film (NCF) were used. In total, nearly one-thousand single joints were subjected to reliability tests in terms of temperature cycling between −40°C and 125°C with a dwell time of 15 minutes and a ramp rate of 110°C/min. The test chip used for this extensive reliability test had a pitch of 100 μm. Therefore, this work was particularly focused on evaluation on the reliability of ultra fine pitch flip-chip interconnections using anisotropically conductive adhesives on a low-cost substrate. The reliability was characterized by single contact resistance measurement using the four-probe method during temperature cycling testing up to 3000 cycles. The Mean Time To Failure (MTTF) (defined as 50% failure of all tested joints) are 650, 2500, and 3500 cycles when the failure definition is defined as 20% increase, larger than 50 mΩ and larger than 100 mΩ, respectively, using the in-situ electrical resistance measurement technique. Using the discontinuous (manual) measurement at room temperature by taking out the sample from the cycling chamber, the MTTF for the same joint system is around 2500 cycles in the case that the failure criteria is defined as 20% of the resistance increase, far better than the results from the in-situ measurement. The results show clearly that in optimized conditions, high reliability flip-chip anisotropically conductive adhesive joints on low-cost substrate can be achieved.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000029-000036 ◽  
Author(s):  
Adrien Morard ◽  
Jean-Christophe Riou ◽  
Gabriel Pares

Abstract In the aeronautical field, the electronic integration roadmaps show that the weight and the volume dedicated to on-board electronics must be reduced by a factor of 4 to 10 compared to the existing ones for the most recurrent functions in the next years. This work is an opening to new technological solutions to increase our ability to save space while improving the overall reliability of the system. The first part of this work is dedicated to the study of “system in package” (SiP) solutions based on different substrates, namely organic or silicon. Generally speaking a SIP is composed by several active and passive components stacked on an interposer. Benchmarks done by our laboratory have demonstrated that in terms of substrate, embedded die technology leads to several advantages compared to 3D TSV or TGV based packaging approaches. The benefits provided by this substrate is the possibility to embed some surface mount technologies (SMT), some bare chips or some integrated passives devices (IPD) banks directly above or below the stacked active components. This way, top and bottom surface of the substrate can be used to integrate several heterogeneous dies side by side while using low profile flip-chip assemblies on the C4 side. Finally, in this kind of 3D architecture, this embedded technology enable a gain of integration, without using costly TSV connections. Substrates of high quality allow a reduction of I/Os interconnection pitches leading to very aggressive integration down to 50μm. Secondly, a 3D stack with 3 levels of components, as described above, leads to 2 or 3 REACH compliant sequential assembly processes, depending of the needs. In order to consider all the solutions for an optimized overall integration with high reliability, this work focuse on the study one simple SIP which includes the top die assembled by flip-chip. For the flip chip hybridization on organic interposers copper pillars technologies will be studied. The objective is to understand in depth the processes and to obtain information on the reliability aspect after thermal cycling stress of the flip chip assembly. Thirdly, we built many silicon test chips with different characteristics with a dedicated daisy chain test vehicle. The different parameters are: chip's thicknesses (50 to 200 μm), chip's sizes (2 to 8 mm), bump structures (diameter), the pitches of the interconnection (from 50 to 250 μm) and the number of interconnection rows. Designs were chosen in order to fit real operational configurations. Moreover, these configurations are interesting to build a comprehensive model in order to understand the failure mechanisms. These chips are then stacked by flip chip on the silicon and on the organic substrate. We are also designing the both configurations of substrates. Only the production of the organics part is outsourced. Fourth, for all assemblies thermos-cycling test results will be evaluated with thermo mechanical simulations done by finite elements. 3D models will take into account the different geometries in order to understand and quantify the various key parameters. The analysis will mainly focus on 3D interconnections. Design rules based on the results will be derivated. The aim is to obtain dimensional criteria based on stress versus deformation responses. Lastly intermetallic formation will be evaluated using EBSD analysis to obtain better understanding of copper pillar failures for this specific bumps size. Issued information's will be exploited for designing the future functional SIP. The ultimate goal of this work is finally to define mechanical design rules that can then be used in functional SiP modules.


2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>


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