The mechanical Properties of CVD Diamond Films, and Diamond Coated Fibres and Wires

1995 ◽  
Vol 383 ◽  
Author(s):  
E D Nicholson ◽  
J E Field ◽  
P G Partridge ◽  
M N R Ashfold
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
Microwave Plasma ◽  
Young's Modulus ◽  
Protective Coatings ◽  
Small Diameter ◽  
Cvd Diamond ◽  
Film Stress ◽  
Free Standing ◽  
Film Property

ABSTRACTTwo areas of thin film property measurement are addressed. The first is that of flat films, either on a substrate or free-standing. The film properties only are of interest. Therefore, when the film remains attached to a substrate during testing, an appropriate analysis is used to subtract the effect of the substrate. The films under test are prospective protective coatings and ‘window’ materials for infrared applications, namely CVD diamond (Hot filament Assisted, HFACVD and Microwave plasma assisted, MPACVD) and Germanium carbide (Ge:C). The mechanical properties under investigation are the Young's modulus and the internal film stress.In the second case the substrates are small diameter fibres and wires coated with CVD diamond. The mechanical properties measured were composite, containing contributions from both the substrate and the film. These coated fibres and wires, have possible applications as reinforcement phases in the production of composites. They are silicon carbide (SiC) and Tungsten (W) of diameters varying between 10 and 125μm. A technique has been developed to measure the Young's modulus of individual coated fibres.

The Structure and the Mechanical Properties of a Newly Fabricated Cellulose-Nanofiber/Polyvinyl-Alcohol Composite

2014 ◽  
Vol 1621 ◽  
pp. 149-154
Author(s):  
Yukako Oishi ◽  
Atsushi Hotta
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Cellulose Nanofibers ◽  
Small Diameter ◽  
Short Fiber ◽  
Cellulose Nanofiber ◽  
Process Conditions ◽  
Aspect Ratios

ABSTRACTCellulose nanofibers (Cel-F) were extracted by a simple and harmless Star Burst (SB) method, which produced aqueous cellulose-nanofiber solution just by running original cellulose beads under a high pressure of water in the synthetic SB chamber. By optimizing the SB process conditions, the cellulose nanofibers with high aspect ratios and the small diameter of ∼23 nm were obtained, which was confirmed by transmission electron microscopy (TEM). From the structural analysis of the Cel-F/PVA composite by the scanning electron microscopy (SEM), it was found that the Cel-F were homogeneously dispersed in the PVA matrix. Considering the high molecular compatibility of the cellulose and PVA due to the hydrogen bonding, a good adhesive interface could be expected for the Cel-F and the PVA matrix. The influences of the morphological change in Cel-F on the mechanical properties of the composites were analysed. The Young’s modulus rapidly increased from 2.2 GPa to 2.9 GPa up to 40 SB treatments (represented by the unit Pass), whereas the Young’s modulus remained virtually constant above 40 Pass. Due to the uniform dispersibility of the Cel-F, the Young’s modulus of the 100 Pass composite at the concentration of 5 wt% increased up to 3.2 GPa. The experimental results corresponded well with the general theory of the composites with dispersed short-fiber fillers, which clearly indicated that the potential of the cellulose nanofibers as reinforcement materials for hydrophilic polymers was sufficiently confirmed.

Characterization of metal-containing amorphous hydrogenated carbon films

1992 ◽  
Vol 7 (3) ◽  
pp. 667-676 ◽  
Author(s):  
M. Wang ◽  
K. Schmidt ◽  
K. Reichelt ◽  
H. Dimigen ◽  
H. Hübsch
Keyword(s):  
Mechanical Properties ◽  
Critical Load ◽  
Young’S Modulus ◽  
Metal Concentration ◽  
Young's Modulus ◽  
Protective Coatings ◽  
Mass Density ◽  
Carbon Films ◽  
Elastic Recoil ◽  
Amorphous Hydrogenated Carbon

Metal-containing amorphous hydrogenated carbon (Me–C: H) films were prepared on silicon substrates. Two kinds of metals (Ti, Ta) were incorporated in the process of reactive rf diode— (13.56 MHz) and DC-magnetron sputtering, respectively. Elastic recoil detection (ERD) and Rutherford backscattering (RBS) of MeV He+ ions were used to determine the hydrogen content and mass density of Me–C: H films. The mechanical properties, i.e., microhardness, Young's modulus, and adhesion, were measured with the help of a nanoindenter and scratch tester. Results show that (1) the mechanical properties of Me–C: H films depend mainly on metal concentrations. At a certain metal concentration, optimal hardness, Young's modulus, and critical load were obtained; (2) the M–C: H films with an optimal metal concentration possess similar hardness, Young's modulus, and higher critical load compared with the corresponding values of diamond-like carbon (a–C: H) films, due to the improvement of the toughness of the films by the incorporation of metals. Therefore, Me–C: H films show high promise of being wear-resistant protective coatings.

Hardness and Young's modulus of amorphous a-SiC thin films determined by nanoindentation and bulge tests

1994 ◽  
Vol 9 (1) ◽  
pp. 96-103 ◽  
Author(s):  
M.A. El Khakani ◽  
M. Chaker ◽  
A. Jean ◽  
S. Boily ◽  
J.C. Kieffer ◽  
...  
Keyword(s):  
Thin Films ◽  
Mechanical Properties ◽  
Silicon Carbide ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Chemical Vapor ◽  
Free Standing ◽  
Film Composition ◽  
Sputtering Deposition ◽  
Sic Films

Due to its interesting mechanical properties, silicon carbide is an excellent material for many applications. In this paper, we report on the mechanical properties of amorphous hydrogenated or hydrogen-free silicon carbide thin films deposited by using different deposition techniques, namely plasma enhanced chemical vapor deposition (PECVD), laser ablation deposition (LAD), and triode sputtering deposition (TSD). a-SixC1−x: H PECVD, a-SiC LAD, and a-SiC TSD thin films and corresponding free-standing membranes were mechanically investigated by using nanoindentation and bulge techniques, respectively. Hardness (H), Young's modulus (E), and Poisson's ratio (v) of the studied silicon carbide thin films were determined. It is shown that for hydrogenated a-SixC1−x: H PECVD films, both hardness and Young's modulus are dependent on the film composition. The nearly stoichiometric a-SiC: H films present higher H and E values than the Si-rich a-SixC1−x: H films. For hydrogen-free a-SiC films, the hardness and Young's modulus were as high as about 30 GPa and 240 GPa, respectively. Hydrogen-free a-SiC films present both hardness and Young's modulus values higher by about 50% than those of hydrogenated a-SiC: H PECVD films. By using the FTIR absorption spectroscopy, we estimated the Si-C bond densities (NSiC) from the Si-C stretching absorption band (centered around 780 cm−1), and were thus able to correlate the observed mechanical behavior of a-SiC films to their microstructure. We indeed point out a constant-plus-linear variation of the hardness and Young's modulus upon the Si-C bond density, over the NSiC investigated range [(4–18) × 1022 bond · cm−3], regardless of the film composition or the deposition technique.

Adhesion and Young's Modulus of CVD Diamond Thin Films Grown Over Various Substrates

1995 ◽  
Vol 383 ◽  
Author(s):  
R. Ramesham ◽  
R. F. Askew ◽  
M. F. Rose
Keyword(s):  
Thin Films ◽  
Young’S Modulus ◽  
Microwave Plasma ◽  
Young's Modulus ◽  
Diamond Films ◽  
Cvd Diamond ◽  
Gas Mixture ◽  
Cantilever Beams ◽  
Plasma Cvd ◽  
Microwave Plasma Cvd

ABSTRACTDiamond films were deposited by microwave plasma CVD using H2 and CH4 gas mixture over various substrate materials such as Si, Pd, Be, Cu, Mo, AIN, SiO2, Si3N4, Al2O3, Sapphire, Quartz, Ni-base alloys, single crystal Ni, boron nitride, and Ti. We have used a Z-axis pull stud test to determine adhesion strength of diamond film to some of the substrates. Our observations on the adhesion of diamond films to the above substrates are reported. A method will be described to evaluate Young's modulus of CVD diamond films using fabricated diamond cantilever beams.

Mechanical Properties of Photosensitive Polyimide Film by Nanoindentation and Microtensile Test

2005 ◽  
Vol 297-300 ◽  
pp. 237-243 ◽  
Author(s):  
Shin Hur ◽  
Sung In Hong ◽  
Dong Kil Shin
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Polyimide Film ◽  
Nanoindentation Test ◽  
Strain Rates ◽  
Polyimide Films ◽  
Free Standing ◽  
Micro Fabrication ◽  
Microtensile Test

A free-standing photosensitive polyimide film with thickness of 10µm is fabricated with the different curing temperatures using a micro fabrication process. The microtensile specimens of a strip type are made to facilitate a tensile testing. The Young’s modulus and yield strength of photosensitive polyimide film are measured with various strain rates from 10-4 /s to 10-3 /s by using a microtensile test. Also, the hardness and Young’s modulus of polyimide films are obtained from nanoindentation test. Finally, the mechanical properties measured from microtensile test are compared with those from nanoindentation test.

Study on Tensile Strength of Resin Mortar

1986 ◽  
Vol 108 (2) ◽  
pp. 163-166
Author(s):  
Takenori Morimitsu ◽  
Tetsuro Yabuta ◽  
Takeshi Tsujimura ◽  
Kotaro Yamaguchi
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Small Diameter ◽  
Spring Model ◽  
Shield Tunneling ◽  
Breaking Elongation ◽  
Tunneling Method ◽  
The Relationship

A new resin mortar has been developed to facilitate a small-diameter shield tunneling method. The breaking elongation, Young’s modulus and tensile strength of the resin mortar are measured and studied. This paper clarifies the relationship between the mechanical properties of the resin mortar and the ones of its constituent materials, using a three-spring model. The mechanical properties of the resin mortar predicted from the model proposed in this paper agree with the measured values.

Mechanical properties of FeAlSi powders prepared by mechanical alloying from different initial feedstock materials

2019 ◽  
Vol 107 (2) ◽  
pp. 207 ◽  
Author(s):  
Jaroslav Čech ◽  
Petr Haušild ◽  
Miroslav Karlík ◽  
Veronika Kadlecová ◽  
Jiří Čapek ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Alloying ◽  
Young’S Modulus ◽  
Milling Time ◽  
Young's Modulus ◽  
Element Model ◽  
X Ray Diffraction ◽  
X Ray ◽  
Powder Particles ◽  
Complete Homogenization

FeAl20Si20 (wt.%) powders prepared by mechanical alloying from different initial feedstock materials (Fe, Al, Si, FeAl27) were investigated in this study. Scanning electron microscopy, X-ray diffraction and nanoindentation techniques were used to analyze microstructure, phase composition and mechanical properties (hardness and Young’s modulus). Finite element model was developed to account for the decrease in measured values of mechanical properties of powder particles with increasing penetration depth caused by surrounding soft resin used for embedding powder particles. Progressive homogenization of the powders’ microstructure and an increase of hardness and Young’s modulus with milling time were observed and the time for complete homogenization was estimated.

scholarly journals First principles computation of composition dependent elastic constants of omega in titanium alloys: implications on mechanical behavior

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
R. Salloom ◽  
S. A. Mantri ◽  
R. Banerjee ◽  
S. G. Srinivasan
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
First Principles ◽  
Young's Modulus ◽  
Group Vi ◽  
Group V ◽  
Β Phase ◽  
Ti Alloys ◽  
Ω Phase ◽  
Stabilizer Concentration

AbstractFor decades the poor mechanical properties of Ti alloys were attributed to the intrinsic brittleness of the hexagonal ω-phase that has fewer than 5-independent slip systems. We contradict this conventional wisdom by coupling first-principles and cluster expansion calculations with experiments. We show that the elastic properties of the ω-phase can be systematically varied as a function of its composition to enhance both the ductility and strength of the Ti-alloy. Studies with five prototypical β-stabilizer solutes (Nb, Ta, V, Mo, and W) show that increasing β-stabilizer concentration destabilizes the ω-phase, in agreement with experiments. The Young’s modulus of ω-phase also decreased at larger concentration of β-stabilizers. Within the region of ω-phase stability, addition of Nb, Ta, and V (Group-V elements) decreased Young’s modulus more steeply compared to Mo and W (Group-VI elements) additions. The higher values of Young’s modulus of Ti–W and Ti–Mo binaries is related to the stronger stabilization of ω-phase due to the higher number of valence electrons. Density of states (DOS) calculations also revealed a stronger covalent bonding in the ω-phase compared to a metallic bonding in β-phase, and indicate that alloying is a promising route to enhance the ω-phase’s ductility. Overall, the mechanical properties of ω-phase predicted by our calculations agree well with the available experiments. Importantly, our study reveals that ω precipitates are not intrinsically embrittling and detrimental, and that we can create Ti-alloys with both good ductility and strength by tailoring ω precipitates' composition instead of completely eliminating them.

scholarly journals Tailoring a Low Young Modulus for a Beta Titanium Alloy by Combining Severe Plastic Deformation with Solution Treatment

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3467
Author(s):  
Anna Nocivin ◽  
Doina Raducanu ◽  
Bogdan Vasile ◽  
Corneliu Trisca-Rusu ◽  
Elisabeta Mirela Cojocaru ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Plastic Deformation ◽  
Severe Plastic Deformation ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Solution Treatment ◽  
Young Modulus ◽  
Orthopedic Implants ◽  
Beta Titanium Alloy

The present paper analyzed the microstructural characteristics and the mechanical properties of a Ti–Nb–Zr–Fe–O alloy of β-Ti type obtained by combining severe plastic deformation (SPD), for which the total reduction was of etot = 90%, with two variants of super-transus solution treatment (ST). The objective was to obtain a low Young’s modulus with sufficient high strength in purpose to use the alloy as a biomaterial for orthopedic implants. The microstructure analysis was conducted through X-ray diffraction (XRD), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy (HRTEM) investigations. The analyzed mechanical properties reveal promising values for yield strength (YS) and ultimate tensile strength (UTS) of about 770 and 1100 MPa, respectively, with a low value of Young’s modulus of about 48–49 GPa. The conclusion is that satisfactory mechanical properties for this type of alloy can be obtained if considering a proper combination of SPD + ST parameters and a suitable content of β-stabilizing alloying elements, especially the Zr/Nb ratio.

scholarly journals Phase Formation, Microstructure and Mechanical Properties of Mg67Ag33 as Potential Biomaterial

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 461
Author(s):  
Konrad Kosiba ◽  
Konda Gokuldoss Prashanth ◽  
Sergio Scudino
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Equilibrium Phase ◽  
Antibacterial Properties ◽  
Equilibrium Phase Diagram ◽  
Compressive Yield Strength ◽  
X Ray ◽  
Fine Grained ◽  
Equilibrium Phases

The phase and microstructure formation as well as mechanical properties of the rapidly solidified Mg67Ag33 (at. %) alloy were investigated. Owing to kinetic constraints effective during rapid cooling, the formation of equilibrium phases is suppressed. Instead, the microstructure is mainly composed of oversaturated hexagonal closest packed Mg-based dendrites surrounded by a mixture of phases, as probed by X-ray diffraction, electron microscopy and energy dispersive X-ray spectroscopy. A possible non-equilibrium phase diagram is suggested. Mainly because of the fine-grained dendritic and interdendritic microstructure, the material shows appreciable mechanical properties, such as a compressive yield strength and Young’s modulus of 245 ± 5 MPa and 63 ± 2 GPa, respectively. Due to this low Young’s modulus, the Mg67Ag33 alloy has potential for usage as biomaterial and challenges ahead, such as biomechanical compatibility, biodegradability and antibacterial properties are outlined.

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