Optical Characterization of the Visible Photoluminescence from Porous Silicon

1991 ◽  
Vol 256 ◽  
Author(s):  
H. D. Fuchs ◽  
M. S. Brandt ◽  
M. Stutzmann ◽  
J. Weber

ABSTRACTThe visible photoluminescence of electrochemically etched silicon wafers is studied by cw- and pulsed-laser excitation. Raman data and infrared transmission measurements on the same samples prove the presence of oxygen and hydrogen in different bonding configurations in the luminescent layers. Identical optical properties are found for chemically synthesized siloxene (Si6O3H6) and its derivates. We present evidence that the origin of the strong room temperature luminescence in “porous” silicon can be traced to siloxene derivates present in the samples.

2010 ◽  
Vol 75 ◽  
pp. 202-207
Author(s):  
Victor Ríos ◽  
Elvia Díaz-Valdés ◽  
Jorge Ricardo Aguilar ◽  
T.G. Kryshtab ◽  
Ciro Falcony

Bi-Pb-Sr-Ca-Cu-O (BPSCCO) and Bi-Pb-Sb-Sr-Ca-Cu-O (BPSSCCO) thin films were grown on MgO single crystal substrates by pulsed laser deposition. The deposition was carried out at room temperature during 90 minutes. A Nd:YAG excimer laser ( = 355 nm) with a 2 J/pulse energy density operated at 30 Hz was used. The distance between the target and substrate was kept constant at 4,5 cm. Nominal composition of the targets was Bi1,6Pb0,4Sr2Ca2Cu3O and Bi1,6Pb0,4Sb0,1Sr2Ca2Cu3OSuperconducting targets were prepared following a state solid reaction. As-grown films were annealed at different conditions. As-grown and annealed films were characterized by XRD, FTIR, and SEM. The films were prepared applying an experimental design. The relationship among deposition parameters and their effect on the formation of superconducting Bi-system crystalline phases was studied.


2008 ◽  
Vol 202 (22-23) ◽  
pp. 5467-5470 ◽  
Author(s):  
Norihiro Sakai ◽  
Yoshihiro Umeda ◽  
Fumiaki Mitsugi ◽  
Tomoaki Ikegami

1991 ◽  
Vol 235 ◽  
Author(s):  
J. A. Knapp

ABSTRACTA new UHV system for pulsed laser deposition of materials is described, together with results from preliminary experiments for depositions of BN on Si. The system is designed to allow for in-situ diagnostics of the ablation plasma, as well as UHV preparation and characterization of clean sample substrates. The room temperature depositions of BN result in amorphous, B-rich films, whose particle content is a strong function of laser wavelength.


2017 ◽  
Vol 24 (5) ◽  
pp. 1139-1144 ◽  
Author(s):  
Mansour Aouassa ◽  
Imen Jadli ◽  
Mohammad Ali Zrir ◽  
Hassen Maaref ◽  
Ridha Mghaieth ◽  
...  

2010 ◽  
Vol 663-665 ◽  
pp. 393-396
Author(s):  
Fu Ru Zhong ◽  
Xiao Yi Lv ◽  
Zhen Hong Jia

We have investigated the morphology and photoluminescence (PL) of Zinc Oxide (ZnO) and Zinc sulphide (ZnS) compound grown on porous silicon at room temperature. Under different excitation wavelengths (320 nm, 340nm, 370 nm), the photoluminescence (PL) spectra of PS-ZnS-ZnO composites were different, and at 550nm there is a strong photoluminescence peak. Energy dispersive spectroscopy (EDS) has been carried out to evaluate the existing of ZnO/ZnS compound. In addition, the scanning electron microscopy (SEM) observation shows that the morphology of the PS-ZnS-ZnO composites was well grown on porous silicon.


1991 ◽  
Vol 236 ◽  
Author(s):  
J. A. Knapp

AbstractA new UHV system for pulsed laser deposition of materials is described, together with results from preliminary experiments for depositions of BN on Si. The system is designed to allow for in-situ diagnostics of the ablation plasma, as well as UHV preparation and characterization of clean sample substrates. The room temperature depositions of BN result in amorphous, B-rich films, whose particle content is a strong function of laser wavelength.


2018 ◽  
Vol 39 (2) ◽  
pp. 161-166
Author(s):  
Mi-Ae Park ◽  
Jin Soo Kim ◽  
Soo Gyeong Cho ◽  
Honglae Sohn

2013 ◽  
Vol 28 (S1) ◽  
pp. S7-S11
Author(s):  
Y. Zhang ◽  
Y.H. An ◽  
Y. Xing ◽  
D.Y. Dong ◽  
S.L. Wang ◽  
...  

The c-oriented La1.8Sr0.2CuO4 and La1.9Sr0.1CuO4 bilayer films were deposited on (001) SrTiO3 single-crystal substrates by using the pulsed laser deposition technique. The effects of deposition parameters on the quality of thin films were investigated. The crystal structures and surface morphologies were characterized by means of XRD and SEM, and the results showed that an as-prepared film deposited with the optimized parameters has high quality. Then La1.8Sr0.2CuO4/La1.9Sr0.1CuO4 bilayers structure was prepared using the optimized parameters for each corresponding layer, and the electrical transport properties were measured. Interesting rectifying properties were observed at both room and low temperatures, and the rectifying ratio at low temperature was found to be much higher than that at room temperature.


2017 ◽  
Vol 73 (11) ◽  
pp. 1616-1621 ◽  
Author(s):  
David K. Geiger ◽  
Matthew R. DeStefano ◽  
Robert A. Lewis

Copper(II) complexes of benzimidazole are known to exhibit biological activity that makes them of interest for chemotherapeutic and other pharmaceutical uses. The complex bis(acetato-κO){5,6-dimethyl-2-(pyridin-2-yl)-1-[(pyridin-2-yl)methyl]-1H-benzimidazole-κ2N2,N3}copper(II), has been prepared. The absorption spectrum has features attributed to intraligand and ligand-field transitions and the complex exhibits ligand-centered room-temperature luminescence in solution. The acetonitrile monosolvate, [Cu(C2H3O2)2(C20H18N4)]·C2H3N (1), and the ethanol hemisolvate, [Cu(C2H3O2)2(C20H18N4)]·0.5C2H6O (2), have been structurally characterized. Compound2has two copper(II) complexes in the asymmetric unit. In both1and2, distorted square-planar N2O2coordination geometries are observed and the Cu—N(Im) bond distance is slightly shorter than the Cu—N(py) bond distance. Intermolecular π–π interactions are found in1and2. A weak C—H...π interaction is observed in1.


1994 ◽  
Vol 50 (23) ◽  
pp. 17093-17096 ◽  
Author(s):  
S. M. Prokes ◽  
W. E. Carlos ◽  
O. J. Glembocki

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