The Influence of Interfaces on the Gap State Distribution of Undoped a-Si:H

1990 ◽  
Vol 192 ◽  
Author(s):  
G. Schumm ◽  
G. H. Bauer

ABSTRACTModulated primary photocurrent (MPC) studies on pin structures show spatial variations of the gap state distribution across the i-layer that can be correlated with Fermi level shifts by band bending towards interfaces. These results as well as reverse bias annealing effects are explained in terms of the defect pool model. It is demonstrated that MPC measurements are basically identical to TOF measurements with clear advantages in the post-transit time regime.

2003 ◽  
Vol 762 ◽  
Author(s):  
M. Schmidt ◽  
A. Schoepke ◽  
O. Milch ◽  
Th. Lussky ◽  
W. Fuhs

AbstractWe report on a detailed study on gap-state distribution in thin amorphous silicon layers (a-Si:H) with film thicknesses between 5 nm and 20 nm on c-Si wafers performed by UV excited photoelectron spectroscopy (UV-PES). We measured how the work function, the gap state density, the position of the Fermi-level and the Urbach-energy depend on the layer thickness and the doping level of the ultra thin a-Si:H(n) layers. It was found, that for phosphorous doping the position of the Fermi level saturates at EF–EV=1.47 eV. This is achieved at a gas phase concentration of 10000 ppm PH3 in the SiH4/H2 mixture which was used for the PECVD deposition process. The variation of the doping level from 0 to 20000 ppm PH3 addition results in an increase of the Urbach energy from 65 meV to 101 meV and in an increase of the gap state density at midgap (EV-Ei= 0.86eV) from 3·1018 to 2·1019 cm-3eV-1.


2021 ◽  
Vol 118 (5) ◽  
pp. 052101
Author(s):  
Youjung Kim ◽  
Hyeongmin Cho ◽  
Kookrin Char

Nanoscale ◽  
2020 ◽  
Vol 12 (16) ◽  
pp. 8883-8889 ◽  
Author(s):  
Ronen Dagan ◽  
Yonatan Vaknin ◽  
Yossi Rosenwaks

Gap states and Fermi level pinning play an important role in all semiconductor devices, but even more in transition metal dichalcogenide-based devices due to their high surface to volume ratio and the absence of intralayer dangling bonds.


1992 ◽  
Vol 259 ◽  
Author(s):  
Chikashi Yamada ◽  
Takahiro Kimura ◽  
Peter Fuqua

ABSTRACTA passivation processes using Na2S and photochemical washing of GaAs (100) surfaces was studied in real time by a second-harmonic generation (SHG) technique. The intensities of surface-specific SHG signals were compared with those of photoluminescence (PL) signals. We found a remarkable similarity between the SHG and PL intensity changes during these processes. A band-bending model due to Fermi-level pinning at the surface has been applied in order to account for both the SHG and the PL intensity changes.


2014 ◽  
Vol 92 (7/8) ◽  
pp. 619-622
Author(s):  
N. Qamhieh ◽  
S.T. Mahmoud ◽  
A.I. Ayesh

Steady-state photoconductivity measurements in the temperature range 100–300 K on amorphous Ge2Sb2Te5 thin film prepared by dc sputtering are analyzed. The dark conductivity is thermally activated with a single activation energy that allocates the position of the Fermi level approximately in the middle of the energy gap relative to the valance band edge. The temperature dependence of the photoconductivity ensures the presence of a maximum normally observed in chalcogenides with low- and high-temperature slopes, which predict the location of discrete sets of localized states (recombination levels) in the gap. The presence of these defect states close to the valence and conduction band edges leaves the quasi Fermi level shifts in a continuous distribution of gap states at high temperatures, as evidenced from the γ values of the lux–ampere characteristics.


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