scholarly journals The Structure of the Cyclodextrin Complex. XXI. Crystal Structures of Heptakis(2,6-di-O-methyl)-β-cyclodextrin Complexes withp-Iodophenol andp-Nitrophenol

1988 ◽  
Vol 61 (6) ◽  
pp. 1939-1944 ◽  
Author(s):  
Kazuaki Harata
1997 ◽  
Vol 75 (1) ◽  
pp. 52-55 ◽  
Author(s):  
Frank Hacket ◽  
Jose-Miguel Coteron ◽  
Hans-Jörg Schneider ◽  
Vladimir P. Kazachenko

Equilibrium constants of complexes between β-cyclodextrin and glucose, galactose, or mannose have been determined by fluorometric competition titrations in water to be as low as K = 1 – 0.5 M−1, in sharp contrast to recently published values for glucose around K = 400 M–1. The pentoses ribose, xylose, and arabinose show association constants between 6.3 and 1.5 M−1, in agreement with published values. Preliminary computer-aided molecular modelling studies suggest that the small values observed for the hexoses are not due to steric hindrance of an intracavity inclusion but to a smaller number of intermolecular hydrogen bonds and to some strain as a result of cyclodextrin deformation. Calorimetric measurements of the glucose–β-cyclodextrin complex show, again in contradiction with the literature, an endothermic reaction, or a free enthalpy value close to zero. Key words: cyclodextrin complexes, sugar complexation, glucose complexation, calorimetry, computer-aided molecular modelling.


RSC Advances ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 3450-3458 ◽  
Author(s):  
Joo Hyung Lee ◽  
Sang Ho Park ◽  
Seong Hun Kim

Bio-polyurethane nanofibers containing triclosan–cyclodextrin complexes to enhance antibacterial properties were prepared using an electrospinning method.


1999 ◽  
Vol 320 (3-4) ◽  
pp. 261-266 ◽  
Author(s):  
Shin Muraoka ◽  
Osamu Matsuzaka ◽  
Shigehiro Kamitori ◽  
Kenji Okuyama

2012 ◽  
Vol 188 ◽  
pp. 70-75 ◽  
Author(s):  
Monica Cretan Stamate ◽  
Carmen Gafitanu ◽  
Ciprian Stamate ◽  
Eliza Gafitanu

Since, anti-inflamatory drugs have a high demand due to increased incidence of pain associated with different pathology; the objectives of this paper are the synthesis, the physicochemical characterization and analysis of the tribological properties for the ketoprofen-cyclodextrin complexes. The analysis of solubility for these complexes was carried out using MathCAD software. Tribological factors were evaluated by the wear resistance of cylindrical tablets containing ketoprofen-cyclodextrin complex, methocel and magnesium stearate. The tablets with ketoprofen-cyclodextrin complexes provide good solubility and wear resistance and these are ideal for preparation of extended release systems like implantable tablets or for orally administration tablets.


Sign in / Sign up

Export Citation Format

Share Document