scholarly journals ZnSnS3: Structure Prediction, Ferroelectricity, and Solar Cell Applications

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Radi A. Jishi ◽  
Marcus A. Lucas

The rapid growth of the solar energy industry is driving a strong demand for high performance, efficient photoelectric materials. In particular, ferroelectrics composed of earth-abundant elements may be useful in solar cell applications due to their large internal polarization. Unfortunately, wide band gaps prevent many such materials from absorbing light in the visible to mid-infrared range. Here, we address the band gap issue by investigating the effects of substituting sulfur for oxygen in the perovskite structure ZnSnO3. Using evolutionary methods, we identify the stable and metastable structures of ZnSnS3and compare them to those previously characterized for ZnSnO3. Our results suggest that the most stable structure of ZnSnS3is the monoclinic structure, followed by the metastable ilmenite and lithium niobate structures. The latter structure is highly polarized, possessing a significantly reduced band gap of 1.28 eV. These desirable characteristics make it a prime candidate for solar cell applications.

2015 ◽  
Vol 1741 ◽  
Author(s):  
Koichi Matsushima ◽  
Ryota Shimizu ◽  
Tomoaki Ide ◽  
Daisuke Yamashita ◽  
Hyunwoong Seo ◽  
...  

ABSTRACTWe succeeded in photovoltaic power generation of p-i-n solar cells utilizing epitaxial ZnInON film with a wide band gap of 3.1 eV as the intrinsic layer, suitable for a top cell of tandem solar cells. The solar cell shows a high open circuit voltage (Voc) of 1.68 V under solar simulator light irradiation of 3.2 mW/cm2. The solar cell performance becomes worse under 100 mW/cm2, which is mainly attributed to the leakage current caused by crystal defects and grain boundaries. X-ray diffraction analysis reveals that the ZnInON film has rather large tilt and twist angles and a high dislocation density of 7.62×1010 cm-2. Such low crystallinity is a bottleneck for high performance of the solar cells. Our results demonstrate a potential of epitaxial ZnInON films as an intrinsic layer of wide band gap p-i-n solar cells with a high Voc.


Author(s):  
Bojun Peng ◽  
Liang Xu ◽  
Jian Zeng ◽  
Xiaopeng Qi ◽  
Youwen Yang ◽  
...  

The development of non-precious, high-performance and environmentally friendly wide band gap semiconductor composite photocatalysts is highly desirable. Here we report two-dimensional (2D) GaN/SiC-based multilayer van der Waals heterostructures for hydrogen...


Author(s):  
Weihuang Wang ◽  
Zixiu Cao ◽  
Huanhuan Wang ◽  
Jingshan Luo ◽  
Yi Zhang

Sb2Se3, as an alternative potential photovoltaic material, has attracted a lot of attention in recent years owing to its excellent photoelectrical properties. The eco-friendly TiO2 with wide band gap is...


2015 ◽  
Vol 27 (12) ◽  
pp. 4184-4187 ◽  
Author(s):  
Jannic Wolf ◽  
Federico Cruciani ◽  
Abdulrahman El Labban ◽  
Pierre M. Beaujuge

2011 ◽  
Vol 98 (9) ◽  
pp. 093502 ◽  
Author(s):  
Marina S. Leite ◽  
Robyn L. Woo ◽  
William D. Hong ◽  
Daniel C. Law ◽  
Harry A. Atwater
Keyword(s):  
Band Gap ◽  

2012 ◽  
Vol 132 (2-3) ◽  
pp. 559-562 ◽  
Author(s):  
Omar S. Martínez ◽  
Aduljay Remolina Millán ◽  
L. Huerta ◽  
G. Santana ◽  
N.R. Mathews ◽  
...  

2021 ◽  
Author(s):  
Pragati Kumar ◽  
Tania Kalsi

Development of high-performance and highly selective NIR photodetectors (PDs) using wide band gap semiconductors is a significant field of research in the present scenario. Herein, cost effective and easy to...


Author(s):  
Yong Zhao ◽  
Yu Lu ◽  
Yonghai Li ◽  
Xiao Kang ◽  
Xichang Bao ◽  
...  

Most polymer donors developed so far for high-performance non-fullerene OSCs are designed in planar molecular geometries containing BDT units. In this work, two D−A conjugated polymers with wide band gap,...


Sign in / Sign up

Export Citation Format

Share Document