Kinetic Modeling of Grain Growth in Polycrystalline Silicon Films Doped with Phosphorus or Boron

1988 ◽  
Vol 135 (9) ◽  
pp. 2312-2319 ◽  
Author(s):  
H. ‐J. Kim ◽  
C. V. Thompson
1984 ◽  
Vol 35 ◽  
Author(s):  
S.J. Krause ◽  
S.R. Wilson ◽  
W.M. Paulson ◽  
R.B. Gregory

ABSTRACTPolycrystalline silicon films of 300 nm thickness were deposited on oxidized wafer surfaces, implanted with As, and annealed on a Varian IA 200 rapid thermal annealer. Transmission electron microscopy was used to study through-thickness and cross sectional views of grain size and morphology of as-deposited and of transient annealed films. A bimoda] distribution of grain sizes was present in as-deposited polycrystalline silicon films. The first population was due to columnar growth of some grains to a final average diameter of 20 rm. The second population of small equiaxed grains of 5 nm average diameter were formed early in the deposition process. During transient annealing grains in the first population grew rapidly up to 280-nm equiaxed grains. After this the growth rate decreased due to the grain size reaching the thickness of the film. Grains in the second population grew rapidly up to a size of 150 nm, after which the growth rate was lowered due to grains impinging upon one another. The grain growth processes for both populations have been described with a modified model for interfacially driven grain growth. This model accounts for diffusion and grain growth which occur with rapidly rising and falling temperatures during short annealing times characteristic of transient annealing processes.


1981 ◽  
Vol 39 (8) ◽  
pp. 645-647 ◽  
Author(s):  
Kenji Shibata ◽  
Tomoyasu Inoue ◽  
Tadahiro Takigawa ◽  
Shintaro Yoshii

1987 ◽  
Vol 106 ◽  
Author(s):  
C. V. Thompson

ABSTRACTExperimental observations of recrystallization, normal grain growth and secondary grain growth in silicon films are reviewed. Normal grain growth leads to grain sizes which are approximately equal to the film thickness. Secondary grain growth can lead to larger grains with restricted crystallographic textures. These procesess are affected by the as-deposited or as-crystallized grain structures and orientations. The rate of grain growth has been shown to be higher in phosphorous or arsenic doped films. Ion bombardment, oxidation, and interactions with silicides also lead to increased grain growth rates. Grain growth enhancement has been related to increased point defect concentrations or dopant redistribution.


1984 ◽  
Vol 45 (7) ◽  
pp. 778-780 ◽  
Author(s):  
S. J. Krause ◽  
S. R. Wilson ◽  
W. M. Paulson ◽  
R. B. Gregory

1987 ◽  
Vol 106 ◽  
Author(s):  
H.-J. Kim ◽  
C. V. Thompson

ABSTRACTIn previous work it has been shown that doping of silicon with P or As leads to enhanced rates of grain growth while doping with B has little effect, except in compensation of the effect of P or As. Here we report a detailed study of the effects of P doping on normal grain growth in silicon films. We also outline a kinetic model for grain growth which is consistent with the various observed effects of dopants. This model is based on the assumption that dopants primarily affect grain boundary mobilities and that grain boundary motion occurs through parallel diffusive and non-diffusive processes. It is further assumed that the rate of the diffusive process is proportional to the vacancy concentration which is a known function of the electron concentration.


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