Silver deposits associated with the Proterozoic rocks of the Thunder Bay District, Ontario

1986 ◽  
Vol 23 (10) ◽  
pp. 1576-1591 ◽  
Author(s):  
J. M. Franklin ◽  
S. A. Kissin ◽  
M. C. Smyk ◽  
S. D. Scott

The silver deposits to the immediate north and west of Lake Superior are divided into three groups. The Mainland veins, the largest group, occur along a zone of normal faults near the western margin of the Proterozoic rocks of the Southern Province. The most economically productive deposits, the Island group, arc in or very near a northeast-trending swarm of gabbro dykes lying immediately offshore the northwestern shore of Lake Superior. The third group occurs near the western margin of the Port Coldwell alkalic complex; these veins are in a shear zone that cuts both Archean metasedimentary rocks and a Proterozoic diabase dyke. The Mainland deposits occur in the Rove shale, immediately below the contact with Logan diabase sills. The veins locally extend upwards into the sills, but the silver-bearing portions, consisting of acanthite and native silver associated with base-metal sulphides, fluorite, barite, quartz, and calcite, are largely bounded by locally silicified shale. The Island veins, typified by the Silver Islet mine, are in fractures perpendicular to the gabbro-dyke host rocks. These veins contain both native silver and acanthite, associated with a Ni–Co sulpharsenide suite and the same mineral assemblage as the Mainland deposits. The veins near Coldwell are rich in sphalerite and galena.Lead-isotope data indicate that the Mainland and Island veins are genetically related and that the Mainland veins formed from an inhomogeneous fluid. Two-stage calculations indicate an early Proterozoic source rock, possibly the Rove shale. The Island veins are more isotopically homogeneous, and their metals may have been derived partially from the gabbro. The Coldwell veins contain lead that is less radiogenic than that of the other two groups and is possibly derived from the adjacent Archean rocks. All three groups of deposits have isotopic compositions that are much less uranogenic and more thorogenic than the nearby Pb–Zn–Ba veins of the Dorion area. Preliminary fluid-inclusion data from the Mainland veins indicate that deposition occurred from a fluid whose temperature varied from approximately 200 °C to more than 400 °C; deposition occurred during boiling induced by adiabatic expansion of the fluid at relatively shallow crustal depths. The Mainland veins developed in the shale (rather than the diabase), as its high fissility, and hence permeability, made it susceptible to intense fracturing by the expanding fluid. Both the Mainland and Island groups were deposited in structures formed dominantly by listric normal faulting during late stages of intracontinental rifting. Heat was supplied by abundant mafic intrusions that formed coincident with rifting. The ore fluid was probably formed as a result of metamorphic dewatering, with metals released to the fluid because of silicate and sulphide recrystallization.

1986 ◽  
Vol 23 (10) ◽  
pp. 1463-1469 ◽  
Author(s):  
A. Changkakoti ◽  
R. D. Morton ◽  
J. Gray ◽  
C. J. Yonge

The native-silver-bearing deposits of the Great Bear Lake region occur within two separate domains, namely the Echo Bay sector and the Camsell River sector. In all these deposits, native silver occurs in veins, associated with a wide range of Ni-, Co-, and Fe- arsenides, Cu-, Fe-, Ni-, and Co-sulfides, and pitchblende in gangues of quartz, calcite, dolomite, siderite, rhodochrosite, and fluorite. The host rocks of the veins are for the most part Aphebian volcano-sedimentary roof pendants within the Great Bear batholithic complex. The carbonates (calcite, dolomite, siderite, and rhodochrosite) show a wide range of δ18O (6.8 to 22.5‰, SMOW) and δ13C (−2.7 to −13.3‰, PDB) values. A single analysis of quartz gave a δ18O value of 16.54‰ (SMOW). The δD of water in fluid inclusions in quartz, dolomite, and calcite shows a range from −62.2 to −98.5‰ (SMOW). The δD of present-day meteoric waters from the region shows a range of −146.5 to −165.2‰ (SMOW). The δ18O of the hydrothermal fluids (0.47 to 9.12‰, SMOW) was calculated from the δ18O values of the quartz, calcite, and dolomite belonging to different paragenetic sequences. The δ13C of carbon (−2.8 to −8.6‰, PDB) in the hydrothermal fluid was calculated from the δ13C values of the calcites. The oxygen, carbon, and hydrogen isotopic values indicate that in the early stages of mineralization, magmatic water and carbon from a magmatic source were predominant. During the late stages of mineralization, the influence of meteoric water became more pronounced.


1986 ◽  
Vol 23 (10) ◽  
pp. 1470-1479 ◽  
Author(s):  
A. Changkakoti ◽  
R. D. Morton

The Great Bear Lake silver deposits in the Northwest Territories of Canada occur within two separate domains, namely the Echo Bay sector and the Camsell River sector. In these deposits, native silver occurs in veins, associated with a wide range of Ni-, Co-, and Fe-arsenides, sulphides, and pitchblende in gangues of quartz, calcite, dolomite, rhodochrosite, and fluorite. The host rocks of the veins are for the most part Aphebian volcano-sedimentary roof pendants within the Great Bear batholithic complex. Native silver, nickeline (niccolite), maucherite, safflorite, rammelsbergite, pararammelsbergite, loellingite, skutterudite, cobaltite, gersdorffite, and arsenopyrite were analyzed on the electron microprobe to determine any local or regional chemical variations. Mercury and antimony were found to occur in significant quantities in the majority of the native-silver samples. The silver samples from the Camsell River sector were found to be generally more enriched in mercury than those of the Echo Bay sector. Nickeline, cobaltite, and gersdorffite were found to be enriched in arsenic in the ores of the Camsell River sector, versus those of the Echo Bay sector. Such variations are probably related to differing magmatic sources for the hydrothermal fluids or even to precursor metallo-organic associations and are not due to different rocks hosting the silver-bearing veins.


Author(s):  
Mikael Vasilopoulos ◽  
Ferenc Molnár ◽  
Hugh O’Brien ◽  
Yann Lahaye ◽  
Marie Lefèbvre ◽  
...  

AbstractThe Juomasuo Au–Co deposit, currently classified as an orogenic gold deposit with atypical metal association, is located in the Paleoproterozoic Kuusamo belt in northeastern Finland. The volcano-sedimentary sequence that hosts the deposit was intensely altered, deformed, and metamorphosed to greenschist facies during the 1.93–1.76 Ga Svecofennian orogeny. In this study, we investigate the temporal relationship between Co and Au deposition and the relationship of metal enrichment with protolith composition and alteration mineralogy by utilizing lithogeochemical data and petrographic observations. We also investigate the nature of fluids involved in deposit formation based on sulfide trace element and sulfur isotope LA-ICP-MS data together with tourmaline mineral chemistry and boron isotopes. Classification of original protoliths was made on the basis of geochemically immobile elements; recognized lithologies are metasedimentary rocks, mafic, intermediate-composition, and felsic metavolcanic rocks, and an ultramafic sill. The composition of the host rocks does not control the type or intensity of mineralization. Sulfur isotope values (δ34S − 2.6 to + 7.1‰) and trace element data obtained for pyrite, chalcopyrite, and pyrrhotite indicate that the two geochemically distinct Au–Co and Co ore types formed from fluids of different compositions and origins. A reduced, metamorphic fluid was responsible for deposition of the pyrrhotite-dominant, Co-rich ore, whereas a relatively oxidized fluid deposited the pyrite-dominant Au–Co ore. The main alteration and mineralization stages at Juomasuo are as follows: (1) widespread albitization that predates both types of mineralization; (2) stage 1, Co-rich mineralization associated with chlorite (± biotite ± amphibole) alteration; (3) stage 2, Au–Co mineralization related to sericitization. Crystal-chemical compositions for tourmaline suggest the involvement of evaporite-related fluids in formation of the deposit; boron isotope data also allow for this conclusion. Results of our research indicate that the metal association in the Juomasuo Au–Co deposit was formed by spatially coincident and multiple hydrothermal processes.


1983 ◽  
Vol 20 (9) ◽  
pp. 1389-1408 ◽  
Author(s):  
Philippe Erdmer ◽  
Herwart Helmstaedt

Eclogite occurring in central Yukon, at Faro and near Last Peak, as lenses interleaved with muscovite–quartz blastomylonite has the chemical and field characteristics of group C rocks. From sigmoidal inclusion trails in garnet, from geothermometry and geobarometry, and from mineral parageneses, the eclogite is inferred to have a crustal protolith and to have followed a hysteretic, subduction-cycle P–T trajectory. Transformation of basic igneous rock into schist was followed by eclogite metamorphism during which pressure was at least 1000 MPa and temperature was between 600 and 700 °C. Uplifting involved passage through the stability field of glaucophane; the eclogite and its host rocks were then subjected to greenschist fades metamorphism and deformation, with temperature at approximately 400 °C. The rocks were emplaced as thrust sheets against or onto the western North American cratonal margin. The tectonic boundary ranges from nearly vertical, where it is outlined by a zone of steeply dipping mélange, to nearly horizontal beneath klippen of cataclastic rocks that lie on North American miogeoclinal strata. Together with occurrences of eclogite on strike, in Yukon, near Fairbanks (Alaska), and near Pinchi Lake (British Columbia), eclogite at Faro and near Last Peak implies that the Yukon Cataclastic Complex is a deeply eroded collision mélange that borders over 1000 km of the ancient continental margin.


2019 ◽  
Vol 112 (2) ◽  
pp. 166-181
Author(s):  
Jonas Hardege ◽  
Lukas Plan ◽  
Gerhard Winkler ◽  
Bernhard Grasemann ◽  
Ivo Baroň

AbstractEisensteinhöhle is a 2 km long crevice cave that is significantly overprinted by hydrothermal karst processes. It was opened during quarrying in the Fischauer Vorberge, at the western margin of the Vienna Basin. This pull-apart basin cuts the eastern foothills of the Alps and is formed by a major NE-SW striking, sinistral transform fault. The western margin consists of NNE-SSW striking normal faults creating paths for thermal water to rise from the central basin. The deepest part of the cave, 73 m below the entrance, hosts a pond with 14.6 ±0.2 °C warm water that occasionally acts as a spring. The water level and temperature fluctuate and at a certain level, water visibly discharges into a nearby narrow fissure. As sporadic observations of the water level since 1992 gave no obvious connection to precipitation events, the connection to an aquifer and the origin of the water remained unknown. A pumping test, conducted on 13/7/2016, yielded a volume of the spring/pool of about 2.8 m3 that is fed by a very small inlet at the sandy bottom. At the time of the pumping test, the discharge was only 4.5 l/h but during previous overflow events, discharge values of up to 289 l/h were recorded.Water temperature and hydrochemistry hint towards a mixture of an old thermal component and a young meteoric component. During continuous monitoring of water level and temperature from October 2015 until November 2018, the water level was almost stable with few periods of high level (almost at overflow) that lasted for about 3 to 4 weeks each. The water temperature increased during most high stands and is positively correlated with the water level. Correlation of the high-resolution data on water level and temperature fluctuations with precipitation measurements at the nearest meteorological stations show a relation of water level to certain rainfall events and the sporadically taken long time records show a correlation with annual precipitation sums. Long-term observations also indicate a connection to groundwater levels in the Vienna Basin with a delay of about 8 weeks in Bad Fischau. In July 2017, the water level dropped suddenly and then recovered simultaneously in the time of several weak earthquakes in the vicinity. The data suggest that the spring in Eisensteinhöhle is influenced by precipitation. For one seismic event, there is a correlation with unusual water level changes at Eisensteinhöhle, but the rareness of earthquakes demands for a longer time series to confirm this observation.


Author(s):  
Richard D. Stewart ◽  
Terry LaVoie ◽  
Nathan Shutes

The feasibility of reestablishing roll on–roll off (RO–RO) service linking Thunder Bay, Ontario, and the Twin Ports of Duluth, Minnesota, and Superior, Wisconsin, was examined. An analysis of similar services both on the Great Lakes and overseas was undertaken. Previous operations on the same route on Lake Superior and short sea service in the Baltic region were analyzed, and the attributes of an appropriate vessel type, such as ice strengthened scantlings and adequate speeds, were determined. A route schedule for a typical vessel was developed. A profile of a suitable vessel was prepared, and the market availability of the vessels was assessed. Issues in terminal design and operation were applied to potential docks in the ports of call to determine the adequacy of shoreside facilities. Cost factors for vessel operations and terminal operations were determined, and a spreadsheet model was developed for future application. Potential revenue streams from vessel and terminal operations were also explored. Revenue generators included day passengers as well as trailers and containers. The feasibility of linking the RO–RO service to a larger intermodal system serving Canada and the United States was also assessed.


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