Gas-phase studies in inductively coupled fluorocarbon plasmas

2001 ◽  
Vol 19 (6) ◽  
pp. 2946 ◽  
Author(s):  
M. Schaepkens ◽  
I. Martini ◽  
E. A. Sanjuan ◽  
X. Li ◽  
G. S. Oehrlein ◽  
...  
2009 ◽  
Vol 517 (14) ◽  
pp. 3942-3946 ◽  
Author(s):  
Sungwoo Lee ◽  
Jihyung Woo ◽  
Donggeun Jung ◽  
Jaeyoung Yang ◽  
Jin-hyo Boo ◽  
...  

1999 ◽  
Vol 17 (1) ◽  
pp. 26-37 ◽  
Author(s):  
M. Schaepkens ◽  
T. E. F. M. Standaert ◽  
N. R. Rueger ◽  
P. G. M. Sebel ◽  
G. S. Oehrlein ◽  
...  

Author(s):  
E. A. Joseph ◽  
B. Zhou ◽  
S. P. Sant ◽  
L. J. Overzet ◽  
M. J. Goeckner

2019 ◽  
Vol 25 (1) ◽  
pp. 44-49 ◽  
Author(s):  
Voislav Blagojevic ◽  
Vitali V Lavrov ◽  
Gregory K Koyanagi ◽  
Diethard K Bohme

The kinetics of ammonia ligation to atomic first and second row transition metal cations were measured in an attempt to assess the role of ligand field effects in gas-phase ion-molecule reaction kinetics. Measurements were performed at 295 ± 2 K in helium bath gas at 0.35 Torr using an inductively coupled plasma/selected-ion flow tube tandem mass spectrometer. The atomic cations were produced at ca. 5500 K in an inductively coupled plasma source and were allowed to decay radiatively and to thermalize by collisions with argon and helium atoms prior to reaction. A strong correlation was observed across the periodic table between the measured rate coefficients for ammonia ligation and measured/calculated bond dissociation energies. A similar strong correlation is seen with the ligand field stabilization energy. So ligand field stabilization energies should provide a useful predictor of relative rates of ligation of atomic metal ions.


1989 ◽  
Vol 43 (6) ◽  
pp. 976-980 ◽  
Author(s):  
John T. Rowan ◽  
R. S. Houk

A double quadrupole arrangement to remove polyatomic ions by collisions with an added target gas has been evaluated. The ions Ar2+, ArO+, and ArN+ were attenuated by factors of 50–400 to count rates of ≤100 counts s−1. Fifty to seventy percent of the analyte ions were retained. Removal of polyatomic ions and retention of analyte ions were favored by low-energy collisions with Xe or CH4 rather than typical target gases like N2 or Ar. Products of ion-molecule reactions between background ions and target gas in the first quadrupole could be observed.


2003 ◽  
Vol 21 (1) ◽  
pp. 251-264 ◽  
Author(s):  
S.-M. Suh ◽  
S. L. Girshick ◽  
U. R. Kortshagen ◽  
M. R. Zachariah

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