Structural Damping Enhancement of Nanocomposites With Engineered Vapor Grown Carbon Nanofiber Paper

Author(s):  
Jihua Gou ◽  
Haichang Gu ◽  
Gangbing Song

Due to their nanometer size and low density, the surface area to mass ratio of carbon nanotubes and carbon nanofibers is extremely large. In addition, the large aspect ratio and high elastic modulus of carbon nanotubes and carbon nanofibers allow for large differences in strain between the constituents in the nanocomposites, which could enhance the interfacial energy dissipation ability. While there are many reported benefits of carbon nanotubes and carbon nanofibers in the nanocomposites, the potential of carbon nanotubes and carbon nanofibers to enhance the structural damping properties of nanocomposites has not been fully explored. This paper presents a novel process to manufacture multifunctional and cost-effective hybrid nanocomposites through integrating engineered carbon nanofiber paper into traditional fiber reinforced composites to improve the structural damping properties. The vacuum-assisted resin transfer molding (VARTM) process was employed to fabricate the nanocomposites by using engineered carbon nanofiber papers as inter-layers or surface layers of traditional composite laminates. To characterize the structural damping properties, the influence of frequency dependence was analyzed through the experiments conducted using the nanocomposite beams. It was found that there is up to 200–700% increase of the damping ratios at higher frequencies. It was found that the connectivities between carbon nanofibers and short glass fibers within the carbon nanofiber paper were responsible for the significant energy dissipation in the nanocomposites during structural vibration applications.

Aerospace ◽  
2006 ◽  
Author(s):  
J. Gou ◽  
S. Sumerlin ◽  
H. C. Gu ◽  
G. Song

This paper presents a novel process to manufacture multifunctional and cost-effective hybrid nanocomposites through integrating engineered carbon nanofiber paper into traditional fiber reinforced composites to improve structural damping properties. In this study, carbon nanofibers are vapor grown carbon fibers, which are grown catalytically from gaseous hydrocarbons using metallic catalyst particles. Vapor grown carbon nanofibers are much less costly than single-walled and multi-walled carbon nanotubes. Carbon nanofibers were preformed as a nanopaper which had a porous structure with highly entangled carbon nanofibers and short glass fibers. The vacuum-assisted resin transfer molding (VARTM) process was used to fabricate the nanocomposites by using engineered carbon nanofiber paper as inter-layer or surface layer of traditional composite laminates. To characterize the structural damping properties, the influence of frequency dependence was analyzed through the experiments conducted using the nanocomposite beams. It was found that there is up to 200-700% increase of the damping ratios at higher frequencies. In addition, experiments were also performed to study the interface characteristics between the carbon nanofiber paper and the laminate ply. The study showed a complete penetration of the resin through the carbon nanofiber paper. It was found that the connectivities between carbon nanofibers and short glass fibers within the carbon nanofiber paper were responsible for the significant energy dissipation in the hybrid nanocomposites during the structural vibration applications. The research results confirm the possible advantage of using engineered carbon nanofiber for damping augmentation.


2006 ◽  
Vol 2006 ◽  
pp. 1-7 ◽  
Author(s):  
Jihua Gou ◽  
Scott O'Braint ◽  
Haichang Gu ◽  
Gangbing Song

Vacuum-assisted resin transfer molding (VARTM) process was used to fabricate the nanocomposites through integrating carbon nanofiber paper into traditional glass fiber reinforced composites. The carbon nanofiber paper had a porous structure with highly entangled carbon nanofibers and short glass fibers. In this study, the carbon nanofiber paper was employed as an interlayer and surface layer of composite laminates to enhance the damping properties. Experiments conducted using the nanocomposite beam indicated up to 200–700% increase of the damping ratios at higher frequencies. The scanning electron microscopy (SEM) characterization of the carbon nanofiber paper and the nanocomposites was also conducted to investigate the impregnation of carbon nanofiber paper by the resin during the VARTM process and the mechanics of damping augmentation. The study showed a complete penetration of the resin through the carbon nanofiber paper. The connectivities between carbon nanofibers and short glass fibers within the carbon nanofiber paper were responsible for the significant energy dissipation in the nanocomposites during the damping tests.


Author(s):  
F. Liang ◽  
Y. Tang ◽  
J. Gou ◽  
H. C. Gu ◽  
G. Song

Polymer matrix composites with reinforcement of carbon nanofibers and carbon nanotubes in the form of paper sheet have shown significant vibration damping improvement compared to pure matrix materials. The large specific area (1000 m2/g) and aspect ratio (>1000) of carbon nanotubes and nanofibers promote significant interfacial friction between carbon nanotubes/nanofibers and a polymer matrix, which causes much higher energy dissipation in the polymer matrix. In this study, a unique concept of manufacturing nanocomposites with carbon nanotube/nanofiber based nanopaper sheets for vibration damping applications has been explored. The new approach includes making carbon nanopaper sheet by the filtration of well-dispersed carbon nanotubes and carbon nanofibers under controlled processing conditions. Subsequently, carbon nanopaper sheets are integrated into composite laminates as surface layer using the vacuum assistant resin transfer molding (VARTM) process. To compare the damping property of laminates constituted by different fibers, three kinds of fibers, including glass fiber, basalt fiber, and carbon fiber are used. For the comparative study, the vibration damping ratios of samples with and without carbon nanopaper sheets are determined. To identify the damping characteristics of each specimen, the Frequency Response Function (FRF) was estimated by a pair of piezoceramic patches: one as an actuator to excite the specimen and the other as a sensor to detect the induced vibrations. From the FRF, the damping ratio of the specimen at each modal frequency of interest was calculated. The experimental results clearly show a significant improvement of vibration damping properties of the nanocomposites plates. This research demonstrates vibration damping enhancement of a polymer matrix via incorporation of carbon nanopaper sheets and provided basic understanding of the damping characteristics for the optimal design and fabrication of high performance damping composites, which have the potential to be used as structural components for different applications.


Author(s):  
Aashish Rohatgi ◽  
William R. Pogue ◽  
Jared N. Baucom ◽  
James P. Thomas

Carbon nanofibers, such as single walled carbon nanotubes (SWNT), multiwalled carbon nanotubes (MWNT) and vapor-grown carbon nanofibers (VGCF or VGCNF) are routinely compounded with polymers to create thermally and electrically conductive polymer nanocomposites. Our group is interested in combining the conduction with structural functionality by reinforcing a high-performance thermotropic liquid crystal polymer (LCP) matrix with vapor-grown carbon nanofibers and single walled carbon nanotubes. High strength and stiffness can be achieved in LCPs through the alignment of molecular domains during high-shear mixing and extrusion. Further strength and stiffness enhancements are potentially possible if the carbon nanofibers could also be aligned, perhaps, with the assistance of the aligned domains of the LCP matrix. However, the geometrical structure of VGCF is quite different and the diameter is one to two orders of magnitude larger than that of SWNT. Therefore, the processing conditions and the interactions between the LCP domains and the nanofibers are expected to lead to different dispersion and alignment characteristics of VGCF and SWNT within the LCP matrix. In this work, twin-screw and Maxwell-type mixer-extruders were used to produce neat LCP filaments and LCP-nanofiber composite filaments with various concentrations of VGCF and SWNT. The dispersion and orientation of the VGCF and SWNT reinforcements were determined by X-ray diffraction and electron microscopy. The filaments were loaded in quasi-static uniaxial tension until fracture to determine the tensile modulus, strength and strain-to-failure. The mechanical properties showed a strong dependence on the filament diameter, nanofiber concentration and processing parameters. A significant increase in mechanical performance was observed with decreasing filament diameter irrespective of the carbon nanofiber concentration. Fracture surfaces examined under electron microscopy revealed hierarchical features at multiple length scales. At the macroscopic scale, a skin-core configuration was observed in the filament cross-section with the skin possessing a greater degree of LCP molecular alignment and nanofiber alignment than the core. The mechanical and electrical properties of the LCP, LCP-VGCF and LCP-SWNT nanocomposite filaments will be described and related to processing parameters, the type of carbon nanofibers (VGCF or SWNT) and the resulting composite microstructure.


Author(s):  
J. Gou ◽  
H. C. Gu ◽  
G. Song

Carbon nanotubes and carbon nanofibers have been used as nanofillers for high performance damping composite materials in recent years. The large specific area (1000 m2/g) and aspect ratio (>1000) of carbon nanotubes and nanofibers promote significant interfacial friction between carbon nanotubes/nanofibers and the polymer matrix. The high stiffness and strength of carbon nanotubes and nanofibers enlarge the differences in the strains of individual constituents of the composites, which causes much higher energy dissipation in the polymer matrix. However, adding small amount of carbon nanotubes and nanofibers will significant increase the viscosity of polymer resin, which makes the dispersion and resin flow through the porous fiber mats extremely difficult. In addition, the fiber mats will filter carbon nanotubes and nanofibers during liquid molding process such as Resin Transfer Molding (RTM) and Vacuum-Assisted Resin Transfer Molding (VARTM). A unique concept of manufacturing nanocomposites with carbon nanotube/nanofiber based nanopaper sheets for structural damping applications has recently been explored. This approach involves making carbon nanopaper sheet by the filtration of well-dispersed carbon nanotubes and carbon nanofibers under controlled processing conditions. Subsequently, carbon nanopaper sheets are integrated into composite laminates using Vacuum Assisted Resin Transfer Molding (VARTM) process. In this study, several nanocomposite plates were fabricated with carbon nanopaper sheet as surface layer. For the comparative study, the regular composite plates without carbon nanopaper sheet were also fabricated. To identify the damping characteristics of each specimen, the Frequency Response Function (FRF) was estimated by a pair of piezoceramic patches: one as an actuator to excite the specimen and the other as a sensor to detect the induced vibrations. From the FRF, the damping ratio of the specimen at each modal frequency of interests was calculated. The experimental results clearly show a significant improvement of damping properties of nanocomposites plates. This research demonstrates structural damping enhancement via carbon nanopaper sheets and provided basic understanding of the damping characteristics for the optimal design and fabrication of high performance damping composites, which have the potential to be used as structural components for many applications.


2003 ◽  
Vol 774 ◽  
Author(s):  
Janice L. McKenzie ◽  
Michael C. Waid ◽  
Riyi Shi ◽  
Thomas J. Webster

AbstractSince the cytocompatibility of carbon nanofibers with respect to neural applications remains largely uninvestigated, the objective of the present in vitro study was to determine cytocompatibility properties of formulations containing carbon nanofibers. Carbon fiber substrates were prepared from four different types of carbon fibers, two with nanoscale diameters (nanophase, or less than or equal to 100 nm) and two with conventional diameters (or greater than 200 nm). Within these two categories, both a high and a low surface energy fiber were investigated and tested. Astrocytes (glial scar tissue-forming cells) and pheochromocytoma cells (PC-12; neuronal-like cells) were seeded separately onto the substrates. Results provided the first evidence that astrocytes preferentially adhered on the carbon fiber that had the largest diameter and the lowest surface energy. PC-12 cells exhibited the most neurites on the carbon fiber with nanodimensions and low surface energy. These results may indicate that PC-12 cells prefer nanoscale carbon fibers while astrocytes prefer conventional scale fibers. A composite was formed from poly-carbonate urethane and the 60 nm carbon fiber. Composite substrates were thus formed using different weight percentages of this fiber in the polymer matrix. Increased astrocyte adherence and PC-12 neurite density corresponded to decreasing amounts of the carbon nanofibers in the poly-carbonate urethane matrices. Controlling carbon fiber diameter may be an approach for increasing implant contact with neurons and decreasing scar tissue formation.


2003 ◽  
Vol 774 ◽  
Author(s):  
Janice L. McKenzie ◽  
Michael C. Waid ◽  
Riyi Shi ◽  
Thomas J. Webster

AbstractCarbon nanofibers possess excellent conductivity properties, which may be beneficial in the design of more effective neural prostheses, however, limited evidence on their cytocompatibility properties exists. The objective of the present in vitro study was to determine cytocompatibility and material properties of formulations containing carbon nanofibers to predict the gliotic scar tissue response. Poly-carbonate urethane was combined with carbon nanofibers in varying weight percentages to provide a supportive matrix with beneficial bulk electrical and mechanical properties. The substrates were tested for mechanical properties and conductivity. Astrocytes (glial scar tissue-forming cells) were seeded onto the substrates for adhesion. Results provided the first evidence that astrocytes preferentially adhered to the composite material that contained the lowest weight percentage of carbon nanofibers. Positive interactions with neurons, and, at the same time, limited astrocyte functions leading to decreased gliotic scar tissue formation are essential for increased neuronal implant efficacy.


2020 ◽  
Vol 9 (1) ◽  
pp. 1170-1182
Author(s):  
Muhammad Razlan Zakaria ◽  
Hazizan Md Akil ◽  
Mohd Firdaus Omar ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Aslina Anjang Ab Rahman ◽  
...  

AbstractThe electrospray deposition method was used to deposit carbon nanotubes (CNT) onto the surfaces of woven carbon fiber (CF) to produce woven hybrid carbon fiber–carbon nanotubes (CF–CNT). Extreme high-resolution field emission scanning electron microscopy (XHR-FESEM), X-ray diffraction (XRD), Raman spectroscopy and Fourier transform infrared spectroscopy (FT-IR) were used to analyze the woven hybrid CF–CNT. The results demonstrated that CNT was successfully and homogenously distributed on the woven CF surface. Woven hybrid CF–CNT epoxy composite laminates were then prepared and compared with woven CF epoxy composite laminates in terms of their flexural and dielectric properties. The results indicated that the flexural strength, flexural modulus and dielectric constant of the woven hybrid CF–CNT epoxy composite laminates were improved up to 19, 27 and 25%, respectively, compared with the woven CF epoxy composite laminates.


2021 ◽  
Vol 11 (2) ◽  
pp. 605
Author(s):  
Antonio Agresta ◽  
Nicola Cavalagli ◽  
Chiara Biscarini ◽  
Filippo Ubertini

The present work aims at understanding and modelling some key aspects of the sloshing phenomenon, related to the motion of water inside a container and its effects on the substructure. In particular, the attention is focused on the effects of bottom shapes (flat, sloped and circular) and water depth ratio on the natural sloshing frequencies and damping properties of the inner fluid. To this aim, a series of experimental tests has been carried out on tanks characterised by different bottom shapes installed over a sliding table equipped with a shear load cell for the measurement of the dynamic base shear force. The results are useful for optimising the geometric characteristics of the tank and the fluid mass in order to obtain enhanced energy dissipation performances by exploiting fluid–structure interaction effects.


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