Oxygen Atom Transfer Reactions to Metal Carbonyls: Kinetics and Mechanism of CO Substitution Reactions of M2(CO)9L (M = Re, L = PPh3, PMePh2, PMe2Ph, C5H5N, or M = Mn, L = C5H5N) in the Presence of (CH3)3NO

2004 ◽  
Vol 34 (7) ◽  
pp. 1181-1190 ◽  
Author(s):  
Li Peng ◽  
Yi‐Ci Gao
Keyword(s):  
Oxygen Atom ◽  
Kinetics And Mechanism ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Metal Carbonyls ◽  
Oxygen Atom Transfer ◽  
Substitution Reactions ◽  
Co Substitution ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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