Oxygen atom transfer reactions to metal carbonyls. Kinetics and mechanism of CO substitution reaction of Cr(CO)6 in the presence of C6H5IO

1988 ◽  
Vol 7 (2) ◽  
pp. 531-534 ◽  
Author(s):  
Jiankun. Shen ◽  
Yianlong. Shi ◽  
Yici. Gao ◽  
Qizhen. Shi ◽  
Fred. Basolo
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.


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