Oxygen-atom-transfer reactions to metal carbonyls. Kinetics and mechanism of CO substitution of M(CO)5 (M = Fe, Ru, Os) in the presence of trimethylamine oxide

1989 ◽  
Vol 8 (9) ◽  
pp. 2144-2147 ◽  
Author(s):  
Jiankun. Shen ◽  
Yici. Gao ◽  
Qizhen. Shi ◽  
Fred. Basolo
Keyword(s):  
Oxygen Atom ◽  
Kinetics And Mechanism ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Metal Carbonyls ◽  
Oxygen Atom Transfer ◽  
Co Substitution ◽  
Trimethylamine Oxide ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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