Transference Numbers for Sodium and Potassium Chlorides in Anhydrous Methanol at 25°C

1951 ◽  
Vol 19 (6) ◽  
pp. 749-751 ◽  
Author(s):  
J. A. Davies ◽  
R. L. Kay ◽  
A. R. Gordon
1977 ◽  
Vol 30 (3) ◽  
pp. 535 ◽  
Author(s):  
RC Paul ◽  
R Sharma ◽  
T Puri ◽  
R Kapoor

Conductances of some 1 : 1 electrolytes have been measured in the concentration range (5-100) x 10-3 mol l-1 in anhydrous formic acid at 25�. The conductance data have been analysed by Fuoss-Shedlovsky equations. Transference numbers of sodium and potassium formates have been measured in this solvent at 25� by a modified Hittorf's method in the concentration range (3-80) x mol l-1. Ionic mobilities, effective ionic radii and solvation numbers of various ions in solution have been calculated. Solvation of cations decreases with the increase in the crystal radii of the ions.


1973 ◽  
Vol 2 (1) ◽  
pp. 23-35 ◽  
Author(s):  
George A. Vidulich ◽  
Glenn P. Cunningham ◽  
Robert L. Kay

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